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| 研究生： |
曾思瑜 Tseng, Ssu-Yu |
|---|---|
| 論文名稱： |
含釕化合物修飾碳管探討：光控磁性AFM探針製備研究 Ruthenium Complex Modified Photomagnetic Carbon Nanotube：Applications and Characterizations. |
| 指導教授： |
王忠茂
Wang, Chong-Mou |
| 學位類別： |
碩士 Master |
| 系所名稱： |
化學系 Department of Chemistry |
| 論文出版年： | 2016 |
| 畢業學年度： | 104 |
| 語文別： | 中文 |
| 論文頁數： | 61 |
| 中文關鍵詞： | 2,2’-二吡啶-5-胺基菲繞啉釕化合物 、多壁奈米碳管 、磁性原子力顯微術 、光磁轉換 |
| 英文關鍵詞： | Ru(bpy)2(NH2-phen)2+, multi-walled carbon nanotube, photomagnetic |
| DOI URL： | https://doi.org/10.6345/NTNU202204294 |
| 論文種類： | 學術論文 |
| 相關次數： | 點閱：126 下載：2 |
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我們以Ru(bpy)2Cl2和NH2-phen合成Ru(bpy)2(NH2-phen)2+，再以偶氮還原修飾法將此錯合物鍵結於多壁奈米碳管和HOPG表面，成為Ru@CNT、Ru@HOPG。經由磁性分析，我們發現在室溫下2,2’-二吡啶-5-胺基菲繞啉釕化合物、Ru@CNT與Ru@HOPG受到473-nm雷射光照射時，會顯現光磁性。我們進而以之製備具有光磁轉換功能的磁性原子力顯微術(MFM)掃瞄探針，以分析磁性物質表面。有鑒於市售MFM探針易被氧化，不易保存，於磁性物質分析上存在困擾，故若以2,2’-二吡啶-5-胺基菲繞啉釕化合物製備MFM探針，將可有效避免除此一困擾。
We synthesized Ru(bpy)2(NH2-phen)2+ by reacting Ru(bpy)2Cl2 with 1,10-phenanthrolin-5-amine (NH2-phen), and then attached the resulting product on multi-walled carbon nanotube and highly oriented pyrolytic graphite (HOPG) through diazotization/denitrogenation processes. We found that Ru(bpy)2(NH2-phen)2+ and the resulting Ru@CNT and Ru@HOPG exhibited magnetism as exposed to the 473-nm light at room temperature. In view of the fact that most metal-coated magnetic-mode AFM (MFM) tips are prone to oxidation in the air, we then devoted efforts to modifying Ru(bpy)2(NH2-phen)2+ on commercial silicon-based tips to fabricate photomagnetic AFM tips. The resultant tips show application potential in MFM imaging.
(1)M. Majumder, N. Chopra, B. J. Hinds, J. Am. Chem. Soc. 2005, 127, 9062.
(2)B. Corry, J. Phys. Chem. B, 2008, 112, 1427.
(3)A. Vlandas, T. Kurkina, A. Ahmad, K. Kern, K. Balasubramanian, Anal. Chem. 2010, 82, 6090.
(4)J. Zhao, A. Buldum, J. Han, J. P. Lu, Phys. Rev. Lett. 2000, 85, 1706.
(5)L. Jiang, H. Gu, X. Xu, X. Yan, J. Mol. Catal. A: Chem. 2009, 310, 144.
(6)W. Z. Li, C. H. Liang, W. J. Zhou, J. S. Qiu, Z. H. Zhou, G. Q. Sun, Q. Xin, J. Phys. Chem. B, 2003, 107, 6292.
(7)Y. Zhao, L. Z. Fan, D. M. Gao, J. L. Ren, B. Hong, Electrochim. Acta 2014, 145, 159.
(8)L. Kong, J. Wang, T. Luo, F. Meng, X. Chen, M. Li, J. Liu, Analyst, 2010, 135, 368.
(9)A. Battigelli, C. Ménard-Moyon, T. Da Ros, M. Prato, A. Bianco, Adv. Drug Delivery Rev. 2013, 65, 1899.
(10)D. Pantarotto, J. P. Briand, M. Prato, A. Bianco, Chem. Commun. 2004, 1, 16.
(11)C. D. Ellis, L. D. Margerum, R. W. Murray, T. J. Meyer, Inorg. Chem. 1983, 22, 1283.
(12)L. G. Bachas, L. Cullen, R. S. Hutchins, D. L. Scott, J. Chem. Soc. Dalton Trans. 1997, 1571.
(13)J. S. Pinter, K. L. Brown, P. A. DeYoung, G. F. Peaslee, Talanta, 2007, 71, 1219.
(14)H. Ozawa, M. Haga, K. Sakai, J. Am. Chem. Soc. 2006, 128, 4926.
(15)O. A. Zadvornyy, J. E. Lucon, R. Gerlach, N. A. Zorin, T. Douglas, T. E. Elgren, J. W. Peters, J. Inorg. Biochem. 2012, 106, 151.
(16)Y. Tao, Z. J. Lin, X. M. Chen, X. L. Huang, M. Oyama, X. Chen, X. R. Wang, Sens. Actuators B: Chem. 2008, 129, 758.
(17)X. M. Chen, G. H. Wu, J. M. Chen, Y. Q. Jiang, G. N. Chen, M. Oyama, X. Chen, X. R. Wang, Biosens. Bioelectron. 2010, 26, 872.
(18)Y. Yu, M. Zhou, H. Cui, J. Mater. Chem. 2011, 21, 12622.
(19)G. Binnig, H. Rohrer, Ch. Gerber, E. Weibel, Phys. Rev. Lett. 1982, 57.
(20)G. Binnig, C. F. Quate, Ch. Gerber, Phys. Rev. Lett. 1986, 56, 930.
(21)黃英碩，科儀新知，2005，4。
(22)H. Heinzelmann, D. W. Pohl, Appl. Phys. A, 1994, 59, 89.
(23)A. Majumdar, Annu. Rev. Mater. Sci. 1999, 29, 505.
(24)D. Rugar, H. J. Mamin, P. Guethner, S. E. Lambert, J. E. Stern, I. McFadyen, T. Yogi, J. Appl. Phys. 1990, 68, 1169.
(25)P. Gayathri, A. S. Kumar, S. Kamaraj, J. Phys. Chem. C, 2015, 119, 7791.
