簡易檢索 / 詳目顯示

研究生: 林合康
Lin, Ho-Kang
論文名稱: 純鈦與Ti-6Al-4V合金同質摩擦攪拌銲接之機械性質與抗腐蝕特性研究
Mechanical properties and corrosion resistance of pure titanium and Ti-6Al-4V alloy by similar friction stir welding
指導教授: 程金保
Cheng, Chin-Pao
口試委員: 程金保
Cheng, Chin-Pao
王星豪
Wang, Shing-Hoa
黃智威
Huang, Chih-Wei
口試日期: 2023/07/28
學位類別: 碩士
Master
系所名稱: 機電工程學系
Department of Mechatronic Engineering
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 100
中文關鍵詞: 摩擦攪拌銲接圓球形凸銷費德曼組織機械性質抗腐蝕性
英文關鍵詞: friction stir welding, spherical tool pin, Widmanstatten, mechanical properties, corrosion resistance
研究方法: 實驗設計法
DOI URL: http://doi.org/10.6345/NTNU202301470
論文種類: 學術論文
相關次數: 點閱:99下載:2
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本研究使用摩擦攪拌銲接(FSW)技術對Gr. 2 CP-Ti及Ti-6Al-4V進行同質對接,使用碳化鎢圓球形凸銷攪拌棒作為銲接工具,銲接過程攪拌棒傾斜角分別使用3°及1°,且下壓深度分別為1.9 mm及1.8 mm,探討不同主軸轉速、進給速度對於銲接件機械性質及抗腐蝕能力的影響,利用金相組織觀察、抗拉試驗、微硬度試驗等作為機械性質分析。在抗腐蝕分析中使用3.5 wt %氯化鈉水溶液模擬海水中使用狀態進行各參數銲道及熱影響區抗腐蝕性質比較,另外將摩擦攪拌銲接實驗數據與惰氣鎢極電弧銲(GTAW)進行銲後性質比較。
    實驗結果在使用圓球形凸銷攪拌棒時,可以增加材料的塑性流動方向,且在成功的銲接參數下,拉伸斷裂位置都出現在母材,在CP-Ti摩擦攪拌銲接的主軸轉速600 rpm、進給速度80 mm/min有最佳銲接性質,抗拉強度為395 MPa,為母材的 94.8 %,而Ti-6Al-4V最佳銲接性質在主軸轉速900 rpm、進給速度40 mm/min時,抗拉強度為1059 MPa,為母材的99.3 %。從純鈦的銲接攪拌區可觀察到明顯的晶粒細化現象,且微硬度直達180 HV,Ti-6Al-4V合金的攪拌區則為針狀的費德曼組織,且攪拌區也有明顯的硬度提升,相較於GTAW,FSW在純鈦接合中有較佳的延伸率,而在Ti-6Al-4V接合中FSW有較優異的機械性質表現。在CP-Ti、Ti-6Al-4V銲後抗腐蝕性研究中,兩種接合法之銲道受組織改變影響,抗腐蝕性均低於母材, FSW的攪拌區及熱影響區相較於GTAW銲道,FSW在抗腐蝕能力中有明顯提升,其中Ti-6Al-4V經FSW在主軸轉速1000 rpm、進給速度40 mm/min 的銲道表面及攪拌區底部未相變態之晶粒細化組織,使抗腐蝕性大幅提升,且優於母材。

    This study employed friction stir welding (FSW) technique to perform similar joining of Gr. 2 commercially pure titanium and Ti-6Al-4V alloy. Tungsten carbide spherical tool pin was used as the welding tool. The tilt angles of the tool pin during the welding process were set at three degrees and one degree, with plunging depths of 1.9 mm and 1.8 mm, respectively. The effects of different spindle speeds and feed rates on the mechanical properties and corrosion resistance of the welds were investigated. Analysis of mechanical properties included metallographic observation, tensile testing, and microhardness testing. Corrosion resistance analysis involves comparing the weld and heat-affected zone under various parameters using a 3.5 wt% sodium chloride solution to simulate seawater corrosion. Additionally, the FSW experimental data was compared with the post-weld properties of gas tungsten arc welding (GTAW).
    The experimental results showed that using a spherical tool pin could enhance the material's plastic flow direction. Under successful welding parameters, the tensile fractures occurred in the base material. For pure titanium friction stir welding, the best welding properties were achieved at a spindle speed of 600 rpm and a feed rate of 80 mm/min, with a tensile strength of 395 MPa, which was 94.8% of the base material. As for Ti-6Al-4V, the optimum welding properties were achieved at a spindle speed of 900 rpm and a feed rate of 40 mm/min, with a tensile strength of 1059 MPa, which was 99.3% of the base material. Significant grain refinement was observed in the friction stir zone of pure titanium, with a microhardness reaching 180 HV. The stir zone of Ti-6Al-4V exhibited needle-like Widmanstatten microstructure, along with a noticeable increase in hardness. Compared to GTAW, FSW demonstrated superior tensile elongation in pure titanium joints, while FSW shows better mechanical properties in Ti-6Al-4V joints. In terms of corrosion resistance, the stir zone and heat-affected zone of FSW exhibited better performance than GTAW welds, indicating improved corrosion resistance in FSW. In the study of post-weld corrosion resistance for CP-Ti and Ti-6Al-4V, the welds formed by two different joining methods were found to have been affected by microstructural changes, resulting in diminished corrosion resistance compared to the base materials. Notably, the friction stir welding (FSW) technique exhibited a pronounced enhancement in corrosion resistance when compared to gas tungsten arc welding (GTAW). Specifically, Ti-6Al-4V that underwent FSW at a spindle speed of 1000 rpm and a feed rate of 40 mm/min showed a substantial increase in corrosion resistance. This improvement was attributed to a refined grain structure on the surface of the weld and at the base of the stir zone, without undergoing phase transformation. The resulting corrosion resistance of these FSW-treated welds surpassed that of the base material. These findings underscored the potential of FSW to significantly enhance corrosion resistance, particularly under specific welding conditions, offering promising implications for improving the longevity of welded joints.

    第一章 前言 1 1.1 研究背景 1 1.2 研究動機與目的 3 第二章 文獻探討 5 2.1 鈦金屬特性 5 2.1.1 鈦金屬簡介 5 2.1.2 鈦金屬機械性質與物理特性 8 2.2 摩擦攪拌銲接製程 10 2.2.1 摩擦攪拌銲接簡介 10 2.2.2 摩擦攪拌銲接原理 11 2.2.3 銲道組織特徵 14 2.3 鈦的銲接 16 2.4 鈦的摩擦攪拌銲接 20 第三章 實驗方法與步驟 28 3.1 實驗流程 28 3.2 實驗材料 29 3.3 銲接製程與參數 30 3.4 銲接設備 32 3.5 切割設備 34 3.6 銲接特性分析 35 3.6.1 金相顯微組織觀察 35 3.6.2 拉伸試驗 36 3.6.3 微硬度試驗 37 3.6.4 X光繞射儀 38 3.6.5 電化學腐蝕測試 39 第四章 結果與討論 41 4.1 圓球形凸銷FSW純鈦接合 41 4.1.1 圓球形攪拌頭製備及形貌 41 4.1.2 圓球形攪拌頭純鈦對接形貌 43 4.1.3 純鈦FSW銲道金相微觀組織觀察 46 4.1.4 純鈦FSW銲後微硬度分析 48 4.1.5 純鈦FSW拉伸試驗分析 50 4.1.6 純鈦摩擦攪拌銲接之拉伸破壞特性 53 4.2 圓球形凸銷FSW接合Ti-6Al-4V 55 4.2.1 Ti-6Al-4V 經FSW對接銲道表面及斷面形貌 56 4.2.2 Ti-6Al-4V經FSW銲後攪拌凸銷磨耗形貌 59 4.2.3 Ti-6Al-4V FSW銲道金相組織觀察 61 4.2.4 Ti-6Al-4V FSW銲後微硬度試驗 66 4.2.5 Ti-6Al-4V FSW拉伸試驗分析 68 4.2.6 Ti-6Al-4V摩擦攪拌銲接之拉伸破壞特性 73 4.3 GTAW接合純鈦與Ti-6Al-4V之接合性質分析 75 4.3.1 GTAW銲道金相觀察與顯微硬度分析 75 4.3.2 Ti-6Al-4V銲道 X光繞射儀測量 80 4.3.3 GTAW拉伸試驗分析及斷面SEM觀察 81 4.4 銲接對純鈦及Ti-6Al-4V之抗腐蝕性分析 85 4.4.1 純鈦在FSW與GTAW之抗腐蝕分析 85 4.4.2 Ti-6Al-4V在FSW與GTAW之抗腐蝕分析 88 第五章 結論 92 參考文獻 94

    [1] H. Attar, M. Calin, L. Zhang, S. Scudino, J. Eckert, " Manufacture by selective laser melting and mechanical behavior of commercially pure titanium", Materials Science and Engineering: A, Vol. 593, 2014, pp. 170-177.
    [2] C. Veiga, J. Davim, A. Loureiro, " Properties and applications of titanium alloys: a brief review", Rev. Adv. Mater. Sci, Vol. 32(2), 2012, pp. 133-148.
    [3] D. Teker, F. Muhaffel, M. Menekse, N.G. Karaguler, M. Baydogan, H. Cimenoglu, " Characteristics of multi-layer coating formed on commercially pure titanium for biomedical applications", Materials Science and Engineering: C, Vol. 48, 2015, pp. 579-585.
    [4] M.S. Sai, V. Dhinakaran, K.M. Kumar, V. Rajkumar, B. Stalin, T. Sathish, " A systematic review of effect of different welding process on mechanical properties of grade 5 titanium alloy", Materials Today: Proceedings, Vol. 21, 2020, pp. 948-953.
    [5] 張文瀚, " 製程參數與攪拌棒凸銷形狀對純鈦摩擦攪拌銲接接合特性與抗蝕性影響之研究", National Taiwan Normal University (Taiwan), 2021,pp. 33-38。
    [6] Z. Yang, B. Qi, B. Cong, F. Liu, M. Yang, " Microstructure, tensile properties of Ti-6Al-4V by ultra high pulse frequency GTAW with low duty cycle", Journal of Materials Processing Technology, Vol. 216, 2015, pp. 37-47.
    [7] J. Xiong, S. Li, F. Gao, J. Zhang, " Microstructure and mechanical properties of Ti6321 alloy welded joint by GTAW", Materials Science and Engineering: A, Vol. 640, 2015, pp. 419-423.
    [8] K. Gangwar, M. Ramulu, " Friction stir welding of titanium alloys: A review", Materials & Design, Vol. 141, 2018, pp. 230-255.
    [9] M. Regev, B. Almoznino, S. Spigarelli, " A Study of the Metallurgical and Mechanical Properties of Friction-Stir-Welded Pure Titanium", Metals, Vol. 13(3), 2023, p. 524.
    [10] H. Moriyama, K. Shimada, N. Goto, " Morphometric analysis of neurons in ganglia: geniculate, submandibular, cervical spinal and superior cervical", Okajimas Folia Anatomica Japonica, Vol. 72(4), 1995, pp. 185-189.
    [11] W. Kroll, " The production of ductile titanium", Transactions of the Electrochemical Society, Vol. 78(1), 1940, p. 35.
    [12] O. Takeda, T. Ouchi, T.H. Okabe, " Recent progress in titanium extraction and recycling", Metallurgical and Materials Transactions B, Vol. 51, 2020, pp. 1315-1328.
    [13] S. Liu, Y.C. Shin, " Additive manufacturing of Ti6Al4V alloy: A review", Materials & Design, Vol. 164, 2019, p. 107552.
    [14] I. Inagaki, T. Takechi, Y. Shirai, N. Ariyasu, " Application and features of titanium for the aerospace industry", Nippon steel & sumitomo metal technical report, Vol. 106(106), 2014, pp. 22-27.
    [15] I. Gurrappa, " Characterization of titanium alloy Ti-6Al-4V for chemical, marine and industrial applications", Materials characterization, Vol. 51(2-3), 2003, pp. 131-139.
    [16] A.R. Prasad, K. Ramji, G. Datta, " An experimental study of wire EDM on Ti-6Al-4V alloy", Procedia materials science, Vol. 5, 2014, pp. 2567-2576.
    [17] R. Huang, M. Riddle, D. Graziano, J. Warren, S. Das, S. Nimbalkar, J. Cresko, E. Masanet, " Energy and emissions saving potential of additive manufacturing: the case of lightweight aircraft components", Journal of cleaner production, Vol. 135, 2016, pp. 1559-1570.
    [18] J.R.P. Jorge, V.A. Barao, J.A. Delben, L.P. Faverani, T.P. Queiroz, W.G. Assunçao, " Titanium in dentistry: historical development, state of the art and future perspectives", The Journal of Indian Prosthodontic Society, Vol. 13, 2013, pp. 71-77.
    [19] P. Almeida, S. Williams, " Innovative process model of Ti-6Al-4V additive layer manufacturing using cold metal transfer (CMT)", 2010 International solid freeform fabrication symposium, University of Texas at Austin, 2010.
    [20] M. McCracken, " Dental implant materials: commercially pure titanium and titanium alloys", Journal of prosthodontics, Vol. 8(1), 1999, pp. 40-43.
    [21] K.M. Agarwal, R. Tyagi, A. Singhal, D. Bhatia, " Effect of ECAP on the mechanical properties of titanium and its alloys for biomedical applications", Materials Science for Energy Technologies, Vol. 3, 2020, pp. 921-927.
    [22] D.R. Askeland, P.P. Phulé, W.J. Wright, D. Bhattacharya, " The science and engineering of materials", 2003.
    [23] A.M. Handbook, " Properties and selection: stainless steels, tool materials and special-purpose metals, Met. Handbook, Vol. 3, 9th Edn, Ed. by D", Benjamin, CW Kirkpatrick (ASM Int. Met. Park, 1980.
    [24] W.D. Callister, " An introduction: material science and engineering", New York, Vol. 106, 2007, p. 139.
    [25] R.S. Mishra, Z. Ma, " Friction stir welding and processing", Materials science and engineering: R: reports, Vol. 50(1-2), 2005, pp. 1-78.
    [26] D.G. Mohan, C. Wu, " A review on friction stir welding of steels", Chinese Journal of Mechanical Engineering, Vol. 34, 2021, pp. 1-29.
    [27] E.T. Akinlabi, R.M. Mahamood, E.T. Akinlabi, R.M. Mahamood, " Introduction to friction welding, friction stir welding and friction stir processing", Solid-state welding: friction and friction stir welding processes, Vol., 2020, pp. 1-12.
    [28] Y. Li, L. Murr, J. McClure, " Flow visualization and residual microstructures associated with the friction-stir welding of 2024 aluminum to 6061 aluminum", Materials Science and Engineering: A, Vol. 271(1-2), 1999, pp. 213-223.
    [29] R. Nandan, T. DebRoy, H. Bhadeshia, " Recent advances in friction-stir welding–process, weldment structure and properties", Progress in materials science, Vol. 53(6), 2008, pp. 980-1023.
    [30] V. Firouzdor, S. Kou, " Al-to-Mg friction stir welding: effect of material position, travel speed, and rotation speed", Metallurgical and Materials Transactions A, Vol. 41, 2010, pp. 2914-2935.
    [31] F. Liu, H. Liu, K. Nakata, N. Yamamoto, J. Liao, " Investigation on friction stir welding parameter design for lap joining of pure titanium", Proceedings of the 1st International Joint Symposium on Joining and Welding, Elsevier, 2013, pp. 159-163.
    [32] Ø. Frigaard, Ø. Grong, O. Midling, " A process model for friction stir welding of age hardening aluminum alloys", Metallurgical and materials transactions A, Vol. 32, 2001, pp. 1189-1200.
    [33] C. Hamilton, S. Dymek, M. Kopyściański, A. Węglowska, A. Pietras, " Numerically based phase transformation maps for dissimilar aluminum alloys joined by friction stir-welding", Metals, Vol. 8(5), 2018, p. 324.
    [34] G. Bussu, P. Irving, " The role of residual stress and heat affected zone properties on fatigue crack propagation in friction stir welded 2024-T351 aluminium joints", International Journal of Fatigue, Vol. 25(1), 2003, pp. 77-88.
    [35] P. Omoniyi, R. Mahamood, N. Arthur, S. Pityana, S. Akinlabi, S. Hassan, Y. Okamoto, M. Maina, E. Akinlabi, " Investigation of the mechanical and microstructural properties of TIG welded Ti6Al4V alloy", Advances in Material Science and Engineering: Selected articles from ICMMPE 2020, Springer, 2021, pp. 111-118.
    [36] P.W. Muncaster, " A practical guide to TIG (GTA) welding", Elsevier1991.
    [37] W.-B. Lee, C.-Y. Lee, W.-S. Chang, Y.-M. Yeon, S.-B. Jung, " Microstructural investigation of friction stir welded pure titanium", Materials Letters, Vol. 59(26), 2005, pp. 3315-3318.
    [38] H. Fujii, Y. Sun, H. Kato, K. Nakata, " Investigation of welding parameter dependent microstructure and mechanical properties in friction stir welded pure Ti joints", Materials Science and Engineering: A, Vol. 527(15), 2010, pp. 3386-3391.
    [39] M. Esmaily, S.N. Mortazavi, P. Todehfalah, M. Rashidi, " Microstructural characterization and formation of α′ martensite phase in Ti–6Al–4V alloy butt joints produced by friction stir and gas tungsten arc welding processes", Materials & Design, Vol. 47, 2013, pp. 143-150.
    [40] S. Mironov, Y. Sato, H. Kokawa, " Friction-stir welding and processing of Ti-6Al-4V titanium alloy: A review", Journal of Materials Science & Technology, Vol. 34(1), 2018, pp. 58-72.
    [41] G.J. Tchein, D. Jacquin, D. Coupard, E. Lacoste, F. Girot Mata, " Genesis of microstructures in friction stir welding of Ti-6Al-4V", Metallurgical and Materials Transactions A, Vol. 49, 2018, pp. 2113-2123.
    [42] D. Chicot, D. Mercier, F. Roudet, K. Silva, M. Staia, J. Lesage, " Comparison of instrumented Knoop and Vickers hardness measurements on various soft materials and hard ceramics", Journal of the European Ceramic Society, Vol. 27(4), 2007, pp. 1905-1911.
    [43] M. Atapour, A.L. Pilchak, G. Frankel, J.C. Williams, " Corrosion behavior of friction stir-processed and gas tungsten arc-welded Ti-6Al-4V", Metallurgical and Materials Transactions A, Vol. 41, 2010, pp. 2318-2327.
    [44] N. Xu, Q. Song, Y. Bao, Y. Jiang, J. Shen, X. Cao, " Twinning-induced mechanical properties’ modification of CP-Ti by friction stir welding associated with simultaneous backward cooling", Science and Technology of Welding and Joining, Vol. 22(7), 2017, pp. 610-616.
    [45] P.D. Edwards, M. Ramulu, " Material flow during friction stir welding of Ti-6Al-4V", Journal of Materials Processing Technology, Vol. 218, 2015, pp. 107-115.
    [46] J. Wang, J. Su, R.S. Mishra, R. Xu, J.A. Baumann, " Tool wear mechanisms in friction stir welding of Ti–6Al–4V alloy", Wear, Vol. 321, 2014, pp. 25-32.
    [47] M. Ramulu, P. Edwards, D.G. Sanders, A.P. Reynolds, T. Trapp, " Tensile properties of friction stir welded and friction stir welded-superplastically formed Ti–6Al–4V butt joints", Materials & Design, Vol. 31(6), 2010, pp. 3056-3061.
    [48] S. Lathabai, B. Jarvis, K. Barton, " Comparison of keyhole and conventional gas tungsten arc welds in commercially pure titanium", Materials Science and Engineering: A, Vol. 299(1-2), 2001, pp. 81-93.
    [49] V. Vaithiyanathan, V. Balasubramanian, S. Malarvizhi, P. Vijay, R.A. Gourav, " High temperature tensile properties and microstructural characterization of gas tungsten constricted arc welded Ti–6Al–4V alloy", Materials Research Express, Vol. 6(9), 2019, p. 0965d6.
    [50] A. Karpagaraj, K. Sankaranarayanasamy, " Some studies on mechanical properties and microstructural characterization of automated TIG welding of thin commercially pure titanium sheets", Materials Science and Engineering: A, Vol. 640, 2015, pp. 180-189.
    [51] T. Balasubramanian, V. Balasubramanian, M.M. Manickam, " Fatigue crack growth behaviour of gas tungsten arc, electron beam and laser beam welded Ti–6Al–4V alloy", Materials & Design, Vol. 32(8-9), 2011, pp. 4509-4520.
    [52] K. Ralston, N. Birbilis, " Effect of grain size on corrosion: a review", Corrosion, Vol. 66(7), 2010, pp. 075005-075005-13.
    [53] V. Fahimpour, S. Sadrnezhaad, F. Karimzadeh, " Corrosion behavior of aluminum 6061 alloy joined by friction stir welding and gas tungsten arc welding methods", Materials & Design, Vol. 39, 2012, pp. 329-333.
    [54] F. Karimzadeh, M. Heidarbeigy, A. Saatchi, " Effect of heat treatment on corrosion behavior of Ti–6Al–4V alloy weldments", Journal of materials processing technology, Vol. 206(1-3), 2008, pp. 388-394.

    下載圖示
    QR CODE