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研究生：	呂沛儒 Lu, Pei-Ju
論文名稱：	鋁金屬有機骨架在酸鹼溶液處理下晶態轉變之研究 Research on revealing the crystalline state transformation of Al-based metal organic frameworks under treatments of acidic and basic solutions
指導教授：	林嘉和 Lin, Chia-Her
口試委員：	楊仲準 Yang, Chun-Chuen 蔡振彥 Tsai, Chen-Yen 蔡明剛 Tsai, Ming-Kang 林嘉和 Lin, Chia-Her
口試日期：	2024/06/03
學位類別：	碩士 Master
系所名稱：	化學系 Department of Chemistry
論文出版年：	2024
畢業學年度：	112
語文別：	中文
論文頁數：	143
中文關鍵詞：	金屬有機骨架、雙溶劑置換、加熱抽真空
英文關鍵詞：	Metal-Organic Framework, Two Solvent Exchange, Heat Under Vacuum
研究方法:	實驗設計法
DOI URL：	http://doi.org/10.6345/NTNU202400703
論文種類：	學術論文
相關次數：	點閱：149 下載：0
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謝辭 i
摘要 ii
Abstract iii
目次 v
表目次 vii
圖目次 ix
第一章 緒論 1
1-1 MOF介紹 1
1-2 MOF的自組裝 4
1-3 Al-MOF簡介 8
1-4 MOF缺陷、活化與結晶性 16
1-5 MOF在水相中的穩定度 23
1-6研究動機 25
第二章 實驗與儀器 27
2-1 實驗藥品 27
2-2 儀器設備 29
2-3 實驗合成方法 33
第三章 結果與討論 39
第一部分 MOF快速自組裝合成探討 39
3-1 MOF快速自組裝-粉末X光繞射(PXRD)鑑定 39
3-2 MOF快速自組裝-場發式掃描電子顯微鏡(FE-SEM)鑑定 44
3-3 MOF快速自組裝-比表面積及孔隙分析儀鑑定 47
3-4 MOF快速自組裝-熱穩定性(TGA)鑑定 63
第二部分 酸鹼水溶液下MOF的穩定度探討 67
3-5 浸泡酸鹼水溶液-粉末X光繞射(PXRD)鑑定 67
3-6 浸泡酸鹼水溶液-場發式掃描電子顯微鏡 (FE-SEM)鑑定 102
3-7 浸泡酸鹼水溶液-比表面積及孔隙分析儀鑑定 108
3-8 浸泡酸鹼水溶液-熱穩定性(TGA)鑑定 128
3-9 浸泡酸鹼水溶液-傅立葉轉換紅外線光譜儀(FTIR)鑑定 133
3-10 浸泡酸鹼水溶液-固態核磁共振光譜儀鑑定 134
第四章 結論 135
參考文獻 137
附錄 141
                                

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2026/06/30

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