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研究生: 胡翔皓
論文名稱: 水泥質材料中混合化學掺料不相容原因的探討
指導教授: 許貫中
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2010
畢業學年度: 98
語文別: 中文
論文頁數: 95
中文關鍵詞: 工作性強塑劑鹽析
英文關鍵詞: workability, superplasticizer, salting-out
論文種類: 學術論文
相關次數: 點閱:119下載:9
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  • 萘磺酸系強塑劑混合羧酸系強塑劑添加入混凝土後工作性有明顯的變差,找出原因並改善此現象是本篇研究重點。本研究首先使用三種不同比例混合強塑劑劑量,分別為1:3、1:1、3:1。實驗得到當萘磺酸系比上羧酸系強塑劑為3:1時,有最差的水泥漿流度。
    在3:1最差流度條件下,改變拌合水pH=4、7、10,研究結果顯示改變pH值對水泥漿的流度增加沒有明顯幫助。另外在一樣3:1條件下拌合水加入NaCl和CaCl2 結果發現有明顯的沉澱物質,而在相同鹽類濃度劑量下單一萘磺酸系強塑劑和羧酸系強塑劑的拌合水沒有任何沉澱,實驗結果證實混合強塑劑會受到鹽類濃度增加而發生鹽析現象,然而添加10mL的丙酮到已有沉澱物的拌合水就能有所減少因鹽析而變成混濁的水溶液濁度。
    為了減少混合強塑劑受到水泥溶出的鹽類而會鹽析然後失去強塑劑的效能,使用5mL丙酮取代5mL拌合水,結果發現水泥漿的流度有明顯的增加,這就表示混合強塑劑效能會受到鹽析而變差。

    Mixing the Naphthalene sulfonate-based superplasticizer and the carboxylic-based superplasticizer in concrete let the workability be obvious worse. How to resolve this phenomenon is an important topic to this research. In this research, the first to use three kinds of different combinative dosage of the mixed superplasticizer, respectively 1:3,1:1,3:1. The Naphthalene sulfonate-based superplasticizer compared to the carboxylic-based superplasticizer is 3:1,and then there are the worst cement paste’s fluidity.
    In the worst-flow condition(3:1), the research results show that changing the pH value of water of increase in the flow of cement paste and there is no apparent help. In the same conditions(3:1), the mixing superplasticizer in the water which have the visional precipitation when add NaCl and CaCl2 in the water. But while the same salt concentration add in the pure Naphthalene sulfonate-based superplasticizer and the carboxylic-based superplasticizer, there are no precipitation in both water solution. The experimental results show that mixed superplasticizer solution will be salting-out when there is more salt concentration in the solution. But adding 10mL acetone in the solution, the turbidity of solution will become decreasing which the turbidity result form the precipitation.
    To decreasing the salting-out result form the cement’s salt dissolving in the solution that can decrease cement workability.We replace 5mL water to 5mL acetone and the flow of cement paste is more increasing.This meaning that the workability of mixed superplasticizer is worse because of salting-out.

    摘 要 II Abstract III 目錄 IV 圖目錄 VI 表目錄 XI 第一章 緒論 1 第二章 文獻回顧 2 2-1 水泥 3 2-2 強塑劑 9 2-2-1 強塑劑之分散機制 12 2-2-2 水泥與強塑劑之間的吸附行為 15 2-3 混凝土 17 2-3-1 強塑劑混合應用 21 2-4 高分子鹽析現象 24 第三章 實驗部份 28 3-1 實驗流程 28 3-2 實驗計畫 28 3-3 實驗材料 29 3-4 實驗儀器 31 第四章 結果與討論 37 4-1 化學掺料基本性質分析 37 4-2 化學摻料之分子量 46 4-3單一掺料或混合掺料對水泥漿迷你坍度的影響 50 4-4 PH值對水泥漿迷你坍度的影響 57 4-5 金屬離子種類對水泥漿迷你坍度的影響 60 4-6 混合強塑劑的鹽析現象 62 4-6-1 四種強塑劑交叉混合的鹽析現象 68 4-6-2 水泥漿Pore solution對混合強塑劑鹽析影響 71 4-6-3 EA檢測鹽析沉澱量 76 4-7 使用不同溶劑改善混合強塑劑的鹽析現象 80 4-7-1 不同溶劑取代部分混合強塑劑的拌合水 82 第五章 結論與建議 89 5-1 結論 89 5-2 建議 90 第六章 參考資料 92

    1. Mindess, S., and Young, J. F., Concrete, Prentice-Hall, Inc.,Englewood Cliffs, New Jersy (1981).
    2. Damidot, Nonat, “Investigation of the C3S Hydration Process During the First Hours of Hydration,” in Hydration and Setting of Cements, Nonat, A., and Mutin, C., Edts., E & FN Spon,New York, (1992).
    3.郭文田, 添加強塑劑對水泥材料水化及其早期行為之影響, 國立中央大學土木工程研究所博士論文,(2000).
    4. M. Collepardi, “Admixtures used to enhance placing characteristics of concrete,” Cem. Concr. Comp., 20 (1998) 103.
    5. M. Pei, D. Wang, X. Hu, and D. Xu, “Synthesis of sodium sulfanilate phenol formaldehyde condensate and its application as a superplasticizer in concrtet,” Cem. Concr. Res., 30, (2000) 1841.
    6. Ramachandran, V. S., and Feldman, R.F., “Superplasticizers,” in Concrete Admixture Handbook, Ramachandran, V. S. Edt., Noyes,New Jersey (1984).
    7. K. Yamada, T. Takahashi, S. Hanehara and M. Matsuhisa, “Effects of the chemical structure on the properties of polycarboxylate-type superplasticizer,” Cem. Concr. Res., 30, (2000) 197
    8. 葉一賢, 新型聚羧酸系PMAMP強塑劑的合成與應用, 國立台 灣師範大學化學研究所碩士論文,(2002).
    9. K. C. Hsu, J. J. Chiu, S. D. Chen and Y. C.Tseng, “Effect of addition time of a superplasticizer on cement adsorption and on concrete workability,” Cem. Concr. Comp., 21, (1999) 425.
    10. B. G. Kim, S. Jiang, C. Jolicoeur and P. C. Aïtcin, “The adsorption behavior of PNS superplasticizer and its relation to fluidity of cement paste,” Cem. Concr. Res., 30, (2000) 887.
    11. H. Uchikawa, S. Hanehara, and D. Sawaki, “The role of steric repulsive force in the dispersion of cement particles in fresh paste paste prepared with organic admixture,” Cem. Concr. Res., 27,(1997) 37.
    12. S. Chandra and J. Björnström, “Influence of superplasticizer type and dosage on the slump loss of Portland cement mortars--Part II,” Cem. Concr. Res., 32, (2002) 1613.
    13. J. A. Lewis. and G. H. Kirby, “Comb polymer architecture effects on the rheological property evolution of concentrated cement suspensions,” J. Am. Ceram. Soc., 87, (2004) 1643.
    14. P. Anderson, D.Roy,., “The Effect of Adsorption of Superplasticizers on the Surface of Cement,” Cem. Concr. Res.,17, (1987) 805.
    15. J. Dransfield, R.Edmeades, “Superplasticizers,” in Cement Admixtures Use and Applications, Hewlett, P. C. Edt. Lougman Scientific and Technical, (1989).
    16. 沈進發,混凝土品質控制,大專工程用書,台北, 1981.
    17. S. Hanehara, K. Yamada, “Interaction between cement and chemical admixture from the point of cement hydration, absorption behaviour of admixture, and paste rheology,” Cem. Concr. Res., 29, (1999) 1159.
    18. M. Collepardi, “Admixtures used to enhance placing characteristics of concrete,” Cem. Concr. Comp., 20 (1998) 103.
    19. 黃宏隆,新型具羧酸系強塑劑對含飛灰水泥漿體流動行為之影響, 國立台灣師範大學化學研究所碩士論文,2003。
    20. S. Chandra and J. Björnström, “Influence of superplasticizer type and dosage on the slump loss of Portland cement mortars--Part II,” Cem. Concr. Res., 32, (2002) 1613.
    21. S. Hanehara, K. Yamada, “Interaction between cement and chemical admixture from the point of cement hydration, absorption behaviour of admixture, and paste rheology,” Cem. Concr. Res., 29, (1999) 1159.
    22. I. Soroka and D. Ravina, “Hot weather concreting with admixtures,” Cem. Concr. Composites, 20, (1998) 129.
    23. 黃兆龍, 混凝土性質與行為, 詹氏書局, 台北, 1997.
    24. K. Yoshioka, E. Tazawab, K. Kawaib and T. Enohatac ,“Adsorption characteristics of superplasticizers on cement component minerals”, Cem. Concr. Res., 32, (2002)1507.
    25. T. S. Liao, C. L. Hwang, Y. S. Ye, K. C. Hsu, “Effects of a carboxylic acid/sulfonic acid copolymer on the material properties of cementitious materials”, Cem. Concr. Res ., 36, (2006)650
    26. L. Coppola, E. Erali, R. Troli, M. Collepardi, “Blending of acrylic superplasticizer with napthalene, melamine or lignosulfonate based polymers,” in: V.M. Malhotra (Eds.), Proceedings of 5th International Conference on Superplasticizers and Other Chemical Admixtures in Concrete, Rome, (1997) .
    27. P. K. Grover and R. L. Ryall, “Critical appraisal of salting-out and its implications for chemical and biological sciences”, Chem. Rev.105 (2005) 1.
    28. F.Hofmeister Arch. Exp. Pathol. Pharmacol. 24, (1888) 247.
    29. O. Bailey and O. Koleske, Polyethylene Oxide, Academic Press, London, (1976), 98.
    30. A. Carlsson and B. Lindman, J. Phys. Chem., 94 (1990) 5005.
    31. 孫振平, 蔣正武, 王建東, 張冠倫, “聚羧酸系減水劑與其他減水劑複配性能之研究”, 建築材料學報, (2008).
    32. C. Gaoa, B. Chena, G. Möschner,“Thermosensitive poly(allylamine)-g-poly(N-isopropylacrylamide) copolymers: Salt-tuned phase separation, particle formation and their applicability on curved surface”, Colloids and Surfaces A: Physicochem. Eng. , 272 (2006) 203.
    33. C. L. Page, O. Vennesland, “Pore solution composition and chloride binding capacity of silica-fume cement pastes”, Cem. Concr. Res., 19,(1983)19

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