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研究生: 陳鴻文
Hong-Wen Chen
論文名稱: 含第16族元素(S、Se、Te)之過渡金屬(Mn、Fe、Ru)團簇化合物的合成與其化性、物性的研究
指導教授: 謝明惠
Shieh, Ming-Huey
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2004
畢業學年度: 92
語文別: 中文
論文頁數: 261
中文關鍵詞: 金屬團簇化合物
英文關鍵詞: Transition Metal
論文種類: 學術論文
相關次數: 點閱:153下載:9
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  • [Et4N]2[SeFe3(CO)9]與Cu+ 試劑的反應,不同的Cu+ 來源,可生成不同的產物:與[Cu(CH3CN)4]BF4的反應可生成{[SeFe3(CO)9]2
    -Cu}3-,與CuOAc反應可生成{[SeFe3(CO)9]2Cu2(μ-OAc)}3-。另外混合dppm與dppe於[SeFe3(CO)9]2-與[Cu(CH3CN)4]BF4的反應中,利用反應溶劑以及反應物比例的不同,可生成一系列含Cu片段的化合物(μ5-Se)Fe3(CO)9Cu2(μ-dppm)(L) (L = CH3CN, THF)、SeFe3(CO)9Cu2
    -(μ-dppe)、{[SeFe3(CO)9]2Cu2(μ-dppe)}2-和{[SeFe3(CO)8]Cu2(μ-dppm)
    -(μ-dppm)}。
    以Se powder和Mn2(CO)10於鹼性溶液中在室溫下反應,不同的濃度及反應時間,可得到不同的結果:於0.9 M KOH下以Se: Mn = 1: 1比例反應一小時,可得到[Se10Mn6(CO)18]4-;若將KOH濃度提高至4 M,則可得到[Se2Mn3(CO)9]2-。以Se: Mn = 10: 6比例,於0.9 M KOH和4 M KOH濃度下反應一小時,皆可得到[Se10Mn6(CO)18]4-;若延長反應時間至十天,於0.9 M KOH下可得[Se5Mn4(CO)12]2-,而於4 M KOH下可得到[Se6Mn6(CO)18]4-,二者皆為新型結構之化合物。

    The reactions of [Et4N]2[SeFe3(CO)9] with different Cu+ reagents resulted in different products. When [Et4N]2[SeFe3(CO)9] reacted with
    [Cu(CH3CN)4]BF4 and CuOAc, {[SeFe3(CO)9]2Cu}3- and {[SeFe3 -(CO)9]2Cu2(μ-OAc)}3- were obtained, respectively. On the other hand, if [SeFe3(CO)9]2- was treated with [Cu(CH3CN)4]BF4/dppm or dppe in varied ratios and different solvents, a series of copper-incorporated E-Fe clusters: (μ5-Se)Fe3(CO)9Cu2(μ-dppm)(L) (L = CH3CN, THF), SeFe3 -(CO)9Cu2(μ-dppe), {[SeFe3(CO)9]2Cu2(μ-dppe)}2-, and {[SeFe3(CO)8]
    -Cu2(μ-dppm)(μ-dppm)} were produced.
    The reactions of Se powder with Mn2(CO)10/KOH/MeOH solution in varied reaction condition were systematically studied. While Se powder reacted with 0.5 eq Mn2(CO)10 in 0.9 M KOH/MeOH solution for 1 hr to produce [Se10Mn6(CO)18]4-, the similar reaction in 4 M KOH/MeOH solution gave [Se2Mn3(CO)9]2-. In the case of Se: Mn in the ratio of 10: 6, the reaction of Se with Mn2(CO)10 in 0.9 M or 4 M of KOH/MeOH for 1 hr led to formation of the new complex [Se10Mn6(CO)18]4-. However, if the reactions proceeded for ten days in 0.9 M and 4 M of KOH/MeOH solutions for ten days, [Se5Mn4(CO)12]2- and [Se6Mn6(CO)18]4- were obtained, both of which represent novel types of complexes in the Se-Mn-CO system.

    1. 前言……………………………………………………… 1 1.1-1 背景……………………………………………………… 1 1.1-2 磁性……………………………………………………… 9 1.2 研究目標…………………………………………………13 2. 實驗……………………………………………………… 14 2.1 一般方法………………………………………………… 14 2.1-1 實驗過程………………………………………………… 14 2.1-2 光譜儀器………………………………………… 15 2.1-3 實驗溶劑…………………………………………………15 2.1-4 使用藥品………………………………………………… 16 2.1-5 縮寫表……………………………………………………16 2.2 Na2SO3和Ru3(CO)12與[Cu(CH3CN)4]BF4的反應………………… 18 2.3 [PPN]2[Te10Fe8(CO)20]和[Cu(CH3CN)4]BF4的反應……………… 18 2.4 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4的反應……………………19 2.4-1 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4以1: 1比例反應………19 2.4-2 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4以1: 2比例反應………20 2.5 [Et4N]2[SeFe3(CO)9]和CuOAc的反應........................ 20 2.6 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppe的反應…………… 21 2.6-1 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppe以1: 2: 1比例在THF下反應……………………………………………………21 2.6-2 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppe以1: 2: 1比例 在CH2Cl2下反應…22 2.6-3 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppe以1: 2: 1比例在CH3CN下反應………………………………………………………23 2.6-4 [SeFe3(CO)9]Cu2(μ-dppe)與{[SeFe3(CO)9]2Cu2(μ-dppe)} -[Cu(dppe)2]2的轉換反應……………………………………………24 2.7 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppm的反應……………25 2.7-1 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppm以1: 2: 1比例 在THF下反應………………………………………………………25 2.7-2 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppm以1: 2: 1比例 在CH2Cl2下反應……………………………………………………26 2.8 {[SeFe3(CO)8]Cu2(μ-dppm)(μ-dppm)}的合成………………………26 2.8-1 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppm以1: 2: 2比例反應……………………………………………………26 2.8-2 [SeFe3(CO)9]Cu2(μ-dppm)(THF)和dppm的反應…………………27 2.9 [PPh4]2[SeFe3(CO)9] 和[Cu(CH3CN)4]BF4/dppm以1: 2: 1比例 在長時間下反應………………………………………………………28 2.10 [PPh4]2[SeFe3(CO)9]和CuBr以1: 7比例反應………………………29 2.11 以強鹼(KOH~4 M)活化Mn2(CO)10後和Se powder反應………… 29 2.11-1 以Se: Mn = 1: 1的比例反應………………………………………29 2.11-2 以Se: Mn =10: 6的比例反應………………………………………31 2.12 以弱鹼(KOH~0.9 M)活化Mn2(CO)10後和Se powder反應…………34 2.12-1 以Se: Mn = 1: 1的比例反應……………………………………34 2.12-2 以Se: Mn = 10: 6的比例反應……………………………………36 2.13 [PPN]4[Se10Mn6(CO)18]與CH2Cl2的反應……………………………37 2.14 [Et4N]4[Se10Mn6(CO)18]與Mn2(CO)10/KOH的反應……… 38 2.15 [Et4N]4[Se6Mn6(CO)18]與Mn2(CO)10的反應……………… 40 2.16 [Et4N]4[Se6Mn6(CO)18]與Mn2(CO)10/KOH的反應………40 2.17 [Et4N]4[Se6Mn6(CO)18]與Se powder的反應………………41 2.18 [PPN]2[S2Ru3Cr(CO)10]之合成……………………………………42 2.19 [PPN]2[Se2Ru3Cr(CO)10]之合成……………………………………42 2.20 [PPN]2[Te2Mn2Fe (CO)9]之合成……………………………………43 2.21 [Et4N]2[Ru4Cu2Br2(CO)13]的晶體結構解析……………………45 2.22 Te2Fe3(CO)8(dppp)的晶體結構解析………………………49 2.23 [Et4N]3{[SeFe3(CO)9]2Cu}的晶體結構解析……………………52 2.24 [Et4N]3{[SeFe3(CO)9]2Cu2(OAc)}的晶體結構解析……………58 2.25 [SeFe3(CO)9]Cu2(dppe)的晶體結構解析………………………65 2.26 {[SeFe3(CO)9]2Cu2(dppe)}[Cu(dppe)2]2的晶體結構解析………69 2.27 [SeFe3(CO)9]Cu2(dppm)(THF)的晶體結構解析…………73 2.28 [SeFe3(CO)9]Cu2(dppm)(CH3CN)的晶體結構解析……………77 2.29 [SeFe3(CO)8]Cu2(dppm)(dppm)的晶體結構解析………………81 2.30 SeFe3(CO)6(dppm)2的晶體結構解析…………………………85 2.31 [PPh4]2{[SeFe3(CO)9]2Cu4Br2}的晶體結構解析……………… 89 2.32 [Et4N]4[Se6Mn6(CO)18]的晶體結構解析………………………93 2.33 [Et4N]2[Se8Mn4(CO)12(CH2)2]的晶體結構解析………………… 96 2.34 [Et4N]4[Se6Mn6(CO)18(CH2)]的晶體結構解析………………… 99 2.35 [Et4N]2[Se5Mn4(CO)12]的晶體結構解析………………………103 2.36 [PPN]2[S2Ru3Cr(CO)10]的磁性分析………………………………110 2.37 [PPN]2[Se2Ru3Cr(CO)10]的磁性分析………………………………111 2.38 [PPN]2[Te2Mn2Fe(CO)9]的磁性分析………………………………112 2.39 [Et4N]4[Se10Mn6(CO)18]的磁性分析………………………………113 2.40 [Et4N]4[Se6Mn6(CO)18]的磁性分析………………………………114 3. 結果…………………………………………………………………… 115 3.1 E-M-CO與Cu+ 試劑的反應………………………………………… 115 3.1-1 Na2SO3和Ru3(CO)12與[Cu(CH3CN)4]BF4的反應…………………115 3.1-2 [PPN]2[Te10Fe8(CO)20]和[Cu(CH3CN)4]BF4的反應……………116 3.1-3 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4的反應 ………………117 3.1-4 [Et4N]2[SeFe3(CO)9]和CuOAc的反應......................118 3.1-5 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppm or dppe的反應119 3.1-6 {[SeFe3(CO)8]Cu2(μ-dppm)(μ-dppm)}的合成…………………124 3.1-7 SeFe3(CO)6(dppm)2的合成…………………………………………126 3.2 Se-Mn系統…………………………………………………………… 127 3.2-1 以Se: Mn = 1: 1的比例反應………………………………………127 3.2-2 以Se: Mn = 10: 6的比例反應…………………………………… 130 3.3 Se-Mn系統產物間的轉換反應……………………………… 133 3.3-1 [PPN]4[Se10Mn6(CO)18]與CH2Cl2的反應....................133 3.3-2 [Et4N]4[Se10Mn6(CO)18]與Mn2(CO)10的反應……………….. 134 3.3-3 [Et4N]4[Se6Mn6(CO)18]與Se powder的反應………………… 136 3.3-4 [Et4N]4[Se6Mn6(CO)18]與Mn2(CO)10的反應………………… 137 3.4 [Et4N]2[Ru4Cu2Br2(CO)13]的晶體結構……………………………140 3.5 Te2Fe3(CO)8(dppp)的晶體結構…………………………………... 142 3.6 [Et4N]3{[SeFe3(CO)9]2Cu}的晶體結構……………………………144 3.7 [Et4N]3{[SeFe3(CO)9]2Cu2(OAc)}的晶體結構……………………146 3.8 [SeFe3(CO)9]Cu2(dppe)的晶體結構…………………………………148 3.9 {[SeFe3(CO)9]2Cu2(dppe)}[Cu(dppe)2]2的晶體結構……………150 3.10 SeFe3(CO)9Cu2(μ-dppm)(THF)的晶體結構………………………152 3.11 [SeFe3(CO)9]Cu2(dppm)(CH3CN)的晶體結構………………………154 3.12 [SeFe3(CO)8]Cu2(dppm)(dppm)的晶體結構………………………156 3.13 SeFe3(CO)6(dppm)2的晶體結構……………………………………158 3.14 [PPh4]2{[SeFe3(CO)9]2Cu4Br2}的晶體結構………………………160 3.15 [Et4N]4[Se6Mn6(CO)18]的晶體結構………………………………162 3.16 [Et4N]2[Se8Mn4(CO)12(CH2)2]的晶體結構………………………165 3.17 [Et4N]4[Se6Mn6(CO)18(CH2)]的晶體結構…………………………168 3.18 [Et4N]2[Se5Mn4(CO)12]的晶體結構………………………………170 4. 討論…………………………………………………………………… 172 4.1 反應性探討…………………………………………………………… 172 4.1-1 [Et4N]2[SeFe3(CO)9]和Cu+ 試劑之反應性探討 172 4.1-2 [Et4N]2[SeFe3(CO)9]和[Cu(CH3CN)4]BF4/dppm or dppe之反應性探討………………………………………………………………………174 4.1-3 Se-Mn系統之反應性探討……………………………………………184 4.1-4 Se-Mn系統中產物的轉換反應之探討………………………………190 4.2 結構探討……………………………………………………………… 199 4.2-1 (μ5-Se)Fe3(CO)9Cu2(μ-dppm)(L) (L = THF, CH3CN)與(μ5-Se)Fe3(CO)8Cu2(μ-dppm)(μ-dppm)之結構探討......................199 4.2-2 {[SeFe3(CO)9]2Cu2(μ-dppe)}2-和{[SeFe3(CO)9]2Cu2(μ-OAc)}3-之結構探討…………202 4.2-3 [SeFe3(CO)9]Cu2(μ-dppe)、[{SeFe3(CO)9}2Cu4Br2]2-與SeFe3(CO)6(dppm)2之結構探討…………………………………………………204 4.2-4 {[SeFe3(CO)9]2Cu}3-之結構棎討…………………………………206 4.3 IR光譜分析…………………………………………………………...208 4.4 磁性探討……………………………………………………………… 212 4.4-1 E-M系統………………………………………………………………212 4.4-2 E-M-M’系統…………………………………………………………215 5. 結論…………………………………………………………………… 219 6. 參考文獻……………………………………………………………… 221 7. 附圖…………………………………………………………………… 229

    1. Haak, S.; Neels, A.; Stoeckli-Evans, H.; Suss-Fink, G.; Thomas, C. M. Chem. Commun. 1999, 1959.
    2. Fachinetti, G.; Fochi, C.; Funaioli, T. Inorg. Chem. 1994, 33, 1719.
    3. Knochenko, S. N.; Pushkarevsky, N. A.; Virovets, A. V.; Scheer, M. J. Chem. Soc., Dalton Trans. 2003, 581.
    4. (a) Reynolds, M. A.; Guzei, L. A.; Angelici, R. J. J. Am. Chem. Soc. 2002, 124, 1689. (b) Bianchini, C.; Meli, A. Acc. Chem. Res. 1998, 31, 109.
    5. Hidai, M.; Kuwata, S. Acc. Chem. Res. 2000, 33, 46.
    6. Guzman-Jimenez, I. Y.; van Hal, J. W.; Whitimire, K. H. Organometallics 2003, 22, 1914.
    7. (a) Happe, R. P.; Winfriend, R.; Pieriek A. J.; Albracht S. P. J.; Bagley, K. A. Science 1997, 385, 126. (b) Zhao, X.; Georgakaki, I. P.; Miller, M. L.; Yarbrough, J. C.; Darensbourg, M. Y. J. Am. Chem. Soc. 2001, 123, 9710.
    8. (a) Linck, R. C.; Pafford, R. J.; Rauchfuss, T. B. J. Am. Chem. Soc. 2001, 123, 8856. (b) Ogata, H.; Mizoguchi, Y.; Mizuno, N.; Miki, K.; Adachi, S.-I.; Yasuoka, N.; Yagi, T.; Yamauchi, O.; Hirota, S.; Higuchi, Y. J. Am. Chem. Soc. 2002, 124, 11628. (c) Sellmann, D.; Geipel, F.; Lauderbach, F.; Heinemann, F. W. Angew. Chem., Int. Ed. Engl. 2002, 41, 632.
    9. Nyman, M. D.; Hampden-Smith, M. J.; Duesler, E. N. Inorg. Chem. 1996, 35, 802.
    10. Lazell, M.; O’Brien, P.; Otway, D. J.; Park, J.-H. J. Chem. Soc., Dalton Trans. 2000, 4479.
    11. Hieber, W.; Gruber, J. Z. Anorg. Allg. Chem. 1958, 296, 91.
    12. Shieh, M.; Huang, K.-C.; Tsai, Y.-C.; Lee, G.-H.; Peng, S.-M. Inorg. Chem. 1997, 36, 4421.
    13. 蔡易州,台灣師範大學碩士論文,1994.
    14. Shieh, M.; Shieh, M.-H.; Tsai, Y.-C.; Ueng, C.-H. Inorg. Chem. 1995, 34, 5088.
    15. O’Neal, S. C.; Pennington, W. T.; Kolis, J. W. Inorg. Chem. 1990, 29, 3134.
    16. Roof, L. C.; Pennington, W. T.; Kolis, J. W. Angew. Chem., Int. Ed. Engl. 1992, 31, 913.
    17. Hung, S.-P.; Kanatzids, M. G. Inorg. Chem. 1993, 32, 821.
    18. Huang, S. D.; Lai, C. P.; Barnes, C. L. Angew. Chem., Int. Ed. Engl. 1997, 36, 1854.
    19. (a) Dehnen, S.; Brandmayer, M. K. J. Am. Chem. Soc. 2003, 125, 6618. (b) Belletti, D.; Graiff, C.; Massera, C.; Pattacini, R.; Predieri, G.; Tiripicchio, A. Inorg. Chim. Acta. 2003, 356, 187. (c) O’Neal, S. C.; Pennington, W. T.; Kolis, J. W. Inorg. Chem. 1990, 29, 3134. (d) Seidel, R.; Schnautz, B.; Henkel, G. Angew. Chem., Int. Ed. Engl. 1996, 35, 1710.
    20. 吳美芬,台灣師範大學碩士論文,2001.
    21. (a) Limburg, J.; Vrettos, J. S.; Crabtree, R. H.; Brudvig, G. W.; Paula, J. C.; Hassan, A.; Barra, A. L.; Toia, C. D.; Collomb, M. N. Inorg. Chem. 2001, 40, 1698. (b) Atwood, C. G.; Geiger, W. E. J. Am. Chem. Soc. 2000, 122, 5477. (c) Tangoulis, V.; Malamatari, D. A.; Spyroulias, G. A.; Raptopoulou, C. P.; Terzis, A.; Kessissoglou, D. P. Inorg. Chem. 2000, 39, 2621.
    22. Soler, M.; Wernsdorfer, W.; Abboud, K. A.; Huffman, J. C.; Davidson, E. R.; Hendrickson, D. N.; Christou, G. J. Am. Chem. Soc. 2003, 125, 3576.
    23. Mironov, V. S.; Chibotaru, L. F.; Ceulemans, A. J. Am. Chem. Soc. 2003, 125, 9750.
    24. Karasawa, S.; Zhou, G.; Morikawa, H.; Koga, N. J. Am. Chem. Soc. 2003, 125, 13676.
    25. Angaridis, P.; Berry, J. F. F.; Cotton, A.; Murillo, C. A.; Wang, X. J. Am. Chem. Soc. 2003, 125, 10327.
    26. Mukhopadhyay, S.; Armstrong,W. H. J. Am. Chem. Soc. 2003, 125, 13010.
    27. Boskovic, C.; Bircher, R.; Philip L. W. T.-P.; Hans U. G.; Paulsen, C.; Wernsdorfer, W.; Barra, A.-L.; Khatsko, E.; Neels, A.; Helen S.-E. J. Am. Chem. Soc. 2003, 125, 14046.
    28. Liu, T.-F.; Fu, D.; Gao, S.; Zhang, Y.-Z.; Sun, H.-L.; Su, G.; Liu, Y.-J. J. Am. Chem. Soc. 2003, 125, 13976.
    29. Tasiopoulos, A. J.; Wernsdorfer, W.; Moulton, B.; Zaworotko, M. J.; Christou, G. J. Am. Chem. Soc. 2003, 125, 15274.
    30. (a) Sessoli, R.; Ysai, H.-L.; Schake, A. R.; Wang, S.; Vincent, J. B.; Folting, K.; Gatteschi, D.; Christou, G.; Hendrickson, D. N. J. Am. Chem. Soc. 1993, 115, 1804. (b) Sessoli, R.; Gatteschi, D.; Caneschi, A.; Novak, M. A. Nature 1993, 356, 141. (c) Christou, G.; Gatteschi, D.; Hendrickson, D. N.; Sessoli, R. MRS Bull. 2000, 25, 66.
    31. Bai, J.; Virovets, A. V.; Scheer, M. Science 2003, 300, 781.
    32. Dehnen, S.; Eichhöfer, A.; Fenske, D. Eur. J. Inorg. Chem. 2002, 279.
    33. Shieh, M.; Liou, Y.; Hsu, M.-H.; Chen, R.-T.; Yeh, S.-J.; Peng, S.-M.; Lee, G.-H. Angew. Chem., Int. Ed. Engl. 2002, 41, 2384.
    34. (a) 陳秋炳,楊宗信,科儀新知,1983,4,78. (b) 余健治,科儀新知,1993,14,37.
    35. (a) Earnshaw, A. Introduction to Magnetochemistry; Academic Press: Lonton, 1968. (b) Van Vlenck, J. H. The Theory of Electronic and Magnetic Susceptibilities; Oxford University: Lonton, 1932.
    36. Kahn, O. J. of Magnetism and Magnetic Materials 1986, 54-57, 1459.
    37. Shriver, D. F.; Drezdzon, M. A.; The Manpulation of Air-Sensitive Compound; 1986.
    38. Simmons, M. G.; Merril, C. L.; Wilson, L. J.; Bottomley, L. A.; Kadish, K. M. J. Chem. Soc., Dalton Trans. 1980, 1827.
    39. Edwards, D. A.; Richards, R. J. Chem. Soc., Dalton Trans. 1973, 2463.
    40. Gordon, A. J.; Ford, A. The Chemist’s Compasion.; Wiely: New York, 1972, p445.
    41. 游宗憲,台灣師範大學碩士論文,2001.
    42. 洪昭宇,台灣師範大學碩士論文,2003.
    43. Boudreaux, E. A.; Mulay, L. N. Theory and Application of Molecular Paramagnetism; Wiley: New York, 1976.
    44. 賴韻文,未發表之成果.
    45. 李長儒,台灣師範大學碩士論文,2003.
    46. 黃國智,台灣師範大學博士論文,1998.
    47. Fuhr, O.; Meredith. A.; Fenske, D. J. Chem. Soc., Dalton Trans.
    2002, 4091.
    48. Liu, C. W.; Hung, C.-M.; Santra, B. K.; Chen, H.-C.; Hsueh, H.-H.;
    Wang, J.-C. Inorg. Chem. 2003, 42, 3216.
    49. Crawford, N. R. M.; Hee, A. G., Long, J. R. J. Am. Chem. Soc. 2002, 124, 14842.
    50. Ahlrichs, R.; Anson, C. E.; Fenske, D.; Hampe, O.; Rothenberger, A.; Sierka, M. Angew. Chem., Int. Ed. Engl. 2003, 42, 4036.
    51. Liu, C. W.; Hung, C.-M.; Santra, B. K.; Wang, J.-C.; Kao, H.-M.; Lin, Z. Inorg. Chem. 2003, 42, 8551.
    52. Liu, C. W.; Hung, C.-M.; Wang, J.-C.; Keng, T.-C. J. Chem. Soc., Dalton Trans. 2002, 3482.
    53. Lobana, T. S.; Rimple; Castineiras, A.; Turner, P. Inorg. Chem. 2003, 42, 4731.
    54. Lobana, T. S.; Sharma, R.; Bermejo, E.; Castineiras, A. Inorg. Chem. 2003, 42, 7728.
    55. Shieh, M.; Tsai, Y.-C. Inorg. Chem. 1994, 33, 2303.
    56. Bai, J.; Virovets, A. V.; Scheer, M. Angew. Chem., Int. Ed. Engl. 2002, 41, 1737.
    57. Blue, E. D.; Gunnoe, T. B.; Brooks, N. R. Angew. Chem., Int. Ed. 2002, 41, 2571.
    58. Sun, D.; Cao, R.; Sun, Y.; Bi, W.; Yuan, D.; Shi, Q.; Li, X. Chem. Commun. 2003, 1528.
    59. Mironov, Y. V.; Efremova, O. A.; Naumov, D. Y.; Sheldrick, W. S.; Fedorov, V. E. Eur. J. Inorg. Chem. 2003, 16, 2591.
    60. Li, Y.-H.; Wang, X.-S.; Zhao, H.; Yuan, R.-X.; Zhang, J.; Xiong, R.-G.; You, X.-Z.; Ju, H.-X.; Xue. Z.-L. Inorg. Chem. 2004, 43, 712.
    61. Fournier, E.; Sicard, S.; Decken, A.; Harvey, P. D. Inorg. Chem. 2004, 43, 1491.
    62. Zhang, W.; Behrens, A.; Ga1tjens, J.; Ebel, M.; Wu, X.; Rehder, D. Inorg. Chem. 2004, 43, 3020.
    63. Yang, Y.; Abboud, K. A.; White, L. M. J. Chem. Soc., Dalton Trans. 2003, 4288.
    64. (a) Lorenz, A.; Fenske, D. Angew. Chem., Int. Ed. Engl. 2001, 40, 4402. (b) Langetepe, L.; Fenske, D. Z. Anorg. Allg. Chem. 2001, 627, 820.
    65. Shieh, M.; Chen, H.-S.; Yang, H.-Y.; Ueng, C.-H. Angew. Chem., Int. Ed. Engl. 1999, 38, 1252.
    66. Plecnik, C. E.; Liu, S.; Chen, X.; Meyers, E. A.; Shore, S. G. J. Am. Chem. Soc. 2004, 126, 204.
    67. Eichhöfer, A.; Deglmann, P. Eur. J. Inorg. Chem. 2004, 21, 349.
    68. Adams, R. D.; Captain, B.; Fu, W.; Pellechia, P. J.; Smith, M. D. Angew. Chem., Int. Ed. 2002, 114, 2031.
    69. Adams, R. D.; Miao, S. J. Organomet. Chem. 2003, 665, 43.
    70. Adams, R. D.; Kwon, O.-S.; Smith, M. D. Inorg. Chem. 2002, 41, 6281.
    71. Kullmer, V.; Rottinger, E.; Vahrenkamp, H. J. Chem. Soc., Chem. Comm. 1977, 782.
    72. Adams, R. D.; Kwon, O.-S.; Sanyal, S. J. Organomet. Chem. 2003,
    681, 258.
    73. Liaw, W.-F.; Ou, D.-S.; Li, Y.-S.; Lee, W.-Z.; Chuang, C.-Y.; Lee, Y.-P.; Lee, G.-H.; Pengs, S.-M. Inorg. Chem. 1995, 34, 3747.
    74. Shieh, M.; Chen, H.-S.; Yang, H.-Y.; Lin, S.-F.; Ueng, C.-H. Chem. Eur. J. 2001, 7, 3152.
    75. Pasynskii, A. A.; Skabitski, I. V.; Torubaev, Y.V.; Semenova, N. I.; Novotortsev, V. M.; Ellert, O. G.; Lyssenko, K. A. J. Organomet. Chem. 2003, 671, 91.
    76. Adams, R. D.; Captain, B.; Kwon, O.-S.; Pellechia, P. J.; Sanyal, S. J. Organomet. Chem. 2004, 689, 1370.
    77. Adams, R. D.; Kwon, O.-S. Inorg. Chem. 2003, 42, 6175.
    78. Adams, R. D.; Miao, S.; Smith, M. D.; Farach, H. Inorg. Chem. 2004, 43, 2515.
    79. Adams, R. D.; Kwon, O.-S.; Smith, M. D. Inorg. Chem. 2002, 41, 1658.
    80. Adams, R. D.; Kwon, O.-S.; Smith, M. D. Inorg. Chem. 2002, 41, 5525.
    81. Adams, R. D.; Captain, B.; Kwon, O.-S.; Miao, S. Inorg. Chem. 2003, 42, 3356.
    82. Adams, R. D.; Kwon, O.-S.; Smith, M. D. Organometallics 2002, 21, 1960.
    83. Adams, R. D.; Miao, S. Organometallics 2003, 22, 2492.
    84. Shibahara, T.; Nishiura, K.; Tsuboi, M.; Akashi, H.; Sakane, G. Chem. Lett. 2001, 1002.
    85. Sugiyama, H.; Lin, Y.-S.; Matsumoto, K. Angew. Chem., Int. Ed. 2000, 39, 4058.
    86. Sugiyama, H.; Moriya, Y.; Matsumoto, K. Organometallics 2001, 20, 5636.
    87. Yoshioka, K.; Kikuchi, H.; Mizutani, J.; Matsumoto, K. Inorg. Chem. 2001, 40, 2234.
    88. Bachman, R. E.; Whitmire, K. H. Inorg. Chem. 1994, 33, 2527.
    89. Bachman, R. E.; Whitmire, K. H.; Van Hal, J. W. Organometallics 1995, 14, 1792.
    90. Shieh, M.; Tsai, Y.-C.; Cherng, J.-J.; Shieh, M.-H.; Chen, H.-S.; Ueng,
    C.-H. Organometallics 1997, 16, 456.
    91. (a) Curtis, M. D.; Han, K. R.; Butler, W. M. Inorg. Chem. 1980, 19, 2096. (b) Klingler, R. J.; Butler, W. M.; Curtis, M. D. J. Am. Chem. Soc. 1978, 100, 5034.
    92. Doyle, G.; Eriksen, K. A.; Van Engen, D. J. Am. Chem. Soc. 1985, 107, 7914.
    93. Ferrer, M.; Reina, R.; Rossell, O.; Seco, M.; Solans, X. J. Chem. Soc., Dalton Trans. 1991, 347.
    94. Brown, S. S.; Hudson, S.; Saletr, I. D.; McParlin, M. J. Chem. Soc., Dalton Trans. 1987, 1967.
    95. Honvitz, C. P.; Holt, E. M.; Brock, C. P.; Shriver, D. F. J. Am. Chem. Soc. 1985, 107, 8136.
    96. 林淑芬,台灣師範大學碩士論文,2001.
    97. Harakas, G. N.; Whittlesey, B. R. J. Am. Chem. Soc. 1996, 118, 4210.
    98. Shieh, M.; Chung, R.-L.; Yu, C.-H.; Hsu, M.-H.; Ho, C.-H.; Peng, S.-M.; Liu, Y.-H. Inorg. Chem. 2003, 42, 5477.

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