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研究生: 許志成
Syu, Jhih-Cheng
論文名稱: 局部表面電漿子共振提升發光材料轉換效率應用於白色發光二極體之研究
Enhancement of conversion efficiency of luminescent material by localized surface plasmon resonance used in white light emitting diode
指導教授: 李亞儒
Lee, Ya-Ju
學位類別: 碩士
Master
系所名稱: 光電工程研究所
Graduate Institute of Electro-Optical Engineering
論文出版年: 2018
畢業學年度: 106
語文別: 中文
論文頁數: 68
中文關鍵詞: 局部表面電漿子共振發光材料白光二極體
英文關鍵詞: localized surface plasmon resonance, luminescent material, white light emitting diode
DOI URL: http://doi.org/10.6345/THE.NTNU.EPST.006.2018.E08
論文種類: 學術論文
相關次數: 點閱:157下載:0
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  • 近年來電漿子光學已經成為新興研究領域,奈米級的金屬粒子獨特的光學特性被運用到各種光電元件上。由於藍光二極體的效率提升,螢光粉轉換(Phosphor-converted)白色發光二極體藉由藍光二極體激發無機發光材料(Inorganic luminescent materials)或稱為螢光粉(Phosphor)而形成白光,具有高效率、低能耗的優勢,所以被廣泛用於照明與背光的應用上。不過,由於螢光粉摻雜的稀土元素離子吸收藍光效率低,螢光粉轉換的白光二極體需要高比例的用量才能形成白光。

    因此,本研究探討不同型態和不同濃度的銀奈米粒子對螢光粉的發光強度的影響。從結果發現在不同型態的銀奈米粒子有一優化點的濃度,可以有效的增強發光強度。由於銀奈米粒子產生的極化效應,有效的吸收藍光並轉換成綠光,使得綠光的發光強度上升13.5%。同時,在相同的色度座標下,螢光粉的使用量可以減少30%,而色度座標也從(0.214, 0.202)偏移到(0.235, 0.253)。

    Plasmonics has been becoming emerged research topic area in recent years. Plasmonics is applicated in different kinds of electro-optic devices due to unique optical properties of metallic nanoparticles. As result of efficiency improvement of blue light emitting diode, phosphor-converted white light emitting diode is produced by blue light emitting diode pumping inorganic luminescent materials. Owing to phosphor-converted white light emitting diode with high efficiency and low energy consumption. It is widely applicated in solid state lighting and backlight applications. However, dopped rare earth ions of phosphor has low efficiency in blue light absorption, phosphor-converted white light emitting diode requires considerably high percentage usage to form white light.

    Therefore, this research is to investigate the influence of emission intensity on different types and different concentration of silver nanoparticles. From the results, the optimized point of concentration on different types of silver nanoparticles is found can efficiently enhance emission intensity. As result of polarizability produced by silver nanoparticles which can efficiently absorb blue light to convert green light, the emission intensity of green light enhanced by 13.5%. Meanwhile, in the same chromaticity coordinate, the usage of phosphor reduced by 30%, chromaticity coordinate also shifts from (0.214, 0.202) to (0.235, 0.253).

    致謝 i 中文摘要 ii Abstract iii 圖目錄 vii 第一章 導論 1 1.1 前言 1 1.2 電漿子共振效應用於發光二極體的應用 1 1.3 電漿子共振效應用於螢光材料與量子點材料相關應用 3 1.4 電漿子共振效應用於白色發光二極體 5 1.5 研究動機 5 第二章 發光材料發光原理 8 2.1 螢光粉之簡介(Introduction of phosphor) 8 2.2 激發光譜與發光光譜(Excitation and emission) 8 2.3 能量轉移機制(Energy transfer) 10 2.4 輻射躍遷機制(Radiative transition) 11 2.5 非輻射躍遷機制(Non-radiative transition) 12 2.6 多聲子鬆弛(Multiphonon relaxation) 14 2.7 交叉鬆弛(Cross relaxation) 14 2.8 光學中心的古典諧波振盪模型(Classical harmonic oscillator model of optical centers) 15 2.9 原子內電子躍遷(Electronic transition in an atom) 16 2.10 電偶極子躍遷的或然率(Electric dipole transition probability ) 18 2.11 光的發光和吸收的強度(Intensity of light emission and absorption) 19 2.12 螢光衰減(decay of fluorescence) 20 2.12 振盪器強度(Oscillator strength) 20 第三章 局部表面電漿子共振原理 22 3.1 馬克斯威爾方程式和電磁波的傳導原理(Maxwell's equations and propagation) 22 3.2 自由電子氣的介電函數(Dielectric function of the free electron gas) 24 3.3 局部表面電漿子共振(Localized surface plasmon resonance) 26 3.4 奈米級的金屬粒子的光散射效應(Light scattering by metallic nanoparticle ) 29 3.5 不同種類奈米級的金屬粒子的特性(Properties of different types of metallic nanoparticle) 30 第四章 實驗流程與儀器原理 32 4.1 樣品製備與流程(Sample building and procedures) 32 4.2 分光光譜儀原理(Double beam spectrophotometer) 35 4.3 光致激發光譜儀(Photoluminescence spectrometer) 36 4.4 人眼的色彩視覺(Color vision of human eye) 37 4.5 人眼的光譜感光度(Spectral sensitivity of human eye) 38 4.6 CIE比色系統(CIE colorimetric system) 39 第五章 結果與討論 43 5.1 銀奈米粒子的吸收光譜和螢光粉的發光光譜 43 5.2 不同濃度的銀奈米粒子對於PL發光光譜和激發光譜強度的影響 45 5.3 PL發光光譜和激發光譜強度增強和衰減效應 53 5.4 不同濃度的銀奈米粒子對藍光晶片的影響 55 5.5 不同濃度的銀奈米粒子混合單一螢光粉 57 5.6 不同濃度的銀奈米粒子混合兩種螢光粉 61 第五章 結論與未來展望 64 第六章 參考文獻 66

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