研究生: |
徐匯凱 Hsu Hui Kai |
---|---|
論文名稱: |
並五苯/駢苯衍生物(pentacene/PTCDI-C13H27)太陽能電池的電場調制光譜研究 |
指導教授: | 陸健榮 |
學位類別: |
碩士 Master |
系所名稱: |
物理學系 Department of Physics |
論文出版年: | 2008 |
畢業學年度: | 96 |
語文別: | 中文 |
論文頁數: | 142 |
中文關鍵詞: | 並五苯 、駢苯衍生物 、調制光譜 、太陽能電池 |
論文種類: | 學術論文 |
相關次數: | 點閱:183 下載:11 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本論文研究的主題為並五苯/駢苯衍生物(pentacene/PTCDI-C13)太陽能電池的電場調制光譜。對樣品施加電場產生斯塔克效應(Stark effect)後,將得到調制光譜進行擬合,可得到各個主要結構隨著調制電壓和和外加直流壓,對於不同溫度的變化趨勢。施加交流調制電壓時,躍遷能量1.85 eV、1.97 eV的譜形結構由高斯一次和二次微分譜形所組成,2.12 eV和2.17 eV的譜形結構由高斯一次微分譜形所組成。在外加直流偏壓調制光譜的部份中,當直流偏壓達到反相臨界偏壓時,譜形會有所顛倒,而躍遷能量1.85 eV、1.97 eV和2.17 eV的譜形結構,主要由高斯一次微分函數的譜形所組成,2.56 eV的譜形結構由高斯一次和二次微分譜形所組成。藉由電場調制光譜的譜圖分析,即可得知樣品內部的光學躍遷機制和載子傳輸等訊息。
[1] Wenge Guo, “Electroabsorption Spectroscopy of Quasi-One-dimensional Organic Molecular Crystals”, Dresden(2003)
[2] R.farchioni and G. Grosso(Eds.),“Organic Electronic Materials–Conjugated Polymers and Low Molecular Weight Organic Solids,Springer(2001)
[3] C. K. Chiang, C. R. Fincher, Y. W. Park, A. J. Heeger, H. Shirakawa,E. J. Louis, S. C. Gau, and Alan G. MacDiarmid, “Electrical Conductivity in Doped Polyacetylene”, Phys. Rev. Lett. 39, 1098(1997)
[4] R.E. Merrifield, “Ionized states in one-dimensional molecular crystal”, J.Chem. Phys. 34,1835(1961)
[
5] P. Petelenz, “Theoretical Models for Electroabsorption Spectroscopy of Organic Molecular Crystals”, Lecture Series on Computer and Computational Sciences Vol.6(2006)
[6] P. Petelenz,"Theoretical models for electro-absorption spectroscopy",Organic Electronics 5, 115-127(2004)
[7] P. Petelenz, Michal Slawik, Kohei Yokoi, and Marek Z. Zgierski,“Theoretical calculation of the electroabsorption spectra of polyacene crystals”, J. Chem. Phys. 105(11),15 September 1996
[8] Michal Slawik and P. Petelenz, “Theoretical interpretation of the electroabsorption spectra of polyacene crystal. . Ⅰ. Role of Frenkel states”,J. Chem. Phys. 107(18), 8 November 1997
[9] Michal Slawik and P. Petelenz, “Theoretical interpretation of the electroabsorption spectra of polyacene crystal. Ⅱ. Role of charge-transfer states”, J. Chem. Phys. 111(16), 22 October 1999
[10] Gerold U. Bublitz and Steven G. Boxer, “Stark Spectroscopy :Applications in Chemistry, Biology, and Materials Science”, Annu. Rev. Phys. Chem.
48:213-42(1997)
[11] Y.-Y. Lin, D.J. Gundlach, S.F. Nelson, T.N. Jackson, IEEE Trans.Electron.Device 44 (1997) 1325.
[12] T.W. Kelley, D. V. Muyres, P. F. Baude, T. P. Smith, and T. D. Jones, Mater.Res. Soc. Symp. Proc. 771, 169(2003)
[13] Rector Magnificns, and D. F. J. Bosscher(Dr.),
“polymorphism and electronic properties of pentacene”, Ph.D.(2002)
[14] Gerlinck, Gerwin H, Huitema, Edzer A, et al. “Flexible active-matrix displays and shift registers based on solution-processed organic transistors”,Nature Materials, 2004,3(2): 106-110
[15]. Katz, H.; Bao, Z.; Gilat, S. Adv. Mater. 2002, 14, 99.
[16] G. Horowitz, F. Kouki, P.Spearman, D. Fichou, C. Nogues, X. Pan, and F.Garnier,Adv.Mater.(Weinheim,Ger.)8,242(1996)
[17] Shuhei Tatemichi,Musubu Ichikawa,Toshiki Koyama,and Yoshio Taniguchi,Appl.Phys.Lett 89,112108(2006)
[18] P. R. L. Malenfant, C. D. Dimitrakopoulos, J. D. Gelorme, L.L.Kosbar,and T.O.Graham, Appl. Phys. Lett. 80, 2517 (2002)
[19] R. J. Chesterfield,J. C. McKeen, C. R. Newman,P.C.Ewbank,D. A.da Silva Filho, J.-L. Bredas, L. L. Miller, K. R. Mann, and C. D.Frisbie,J. Phys. Chem. B 108, 19281 (2004)
[20] Ajay. K. .Pandey, SylvieDabos-Seignon, and Jean-Michel
Nunzi,Appl.Phys.Lett 89,113506(2006)
[21] D. M. Chapin, C. S. Fuller, G. L. Pearson, A new silicon p-n junction photocell for con-verting solar radiation into electrical power, Journal of Applied Physics 25 (1954), 676.