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研究生: 吳宗賢
Wu, Chung-Xian
論文名稱: 結合電化學方法與電子顯微鏡探討鍍鋅鋼板表面塗層之抗蝕研究
A Study On Combining Electrochemical Methods And Electron Microscope To Explore Corrosion Resistance Of Coating On Zn-Coated Steel Sheet
指導教授: 呂家榮
Lu, Chia-Jung
口試委員: 劉茂煌
Liu, Mao-Huang
李君婷
Li, Chun-Ting
呂家榮
Lu, Chia-Jung
口試日期: 2023/06/16
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2023
畢業學年度: 111
語文別: 中文
論文頁數: 97
中文關鍵詞: 抗蝕性氧化矽奈米複合塗層鋯鈍化處理鍍鋅鋼板
英文關鍵詞: corrosion resistance, silicon dioxide nano-composite coating, zirconium passivation treatment, galvanized steel sheet
研究方法: 實驗設計法
DOI URL: http://doi.org/10.6345/NTNU202300941
論文種類: 學術論文
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  • 第一章 緒論 1 1.1研究動機 1 1.2 金屬的腐蝕和抗腐蝕 2 1.2.1 金屬材料的腐蝕 2 1.2.2 腐蝕的分類 3 1.2.3 抗腐蝕方法 7 1.3 鍍鋅鋼板表面處理 10 1.3.1 鈍化處理 12 1.3.2 塗油 13 1.3.3 抗指紋薄膜 13 1.4 溶膠–凝膠法 14 1.4.1 水解反應(Hydrosis) 14 1.4.2 縮合反應(Condensation) 15 1.5 塗層塗佈方式 17 1.5.1 沉浸塗佈法(Dip coating) 17 1.5.2 旋轉塗佈法(Spin coating) 17 1.5.3 噴霧塗佈法(Spray coating) 18 1.5.4 電泳塗佈法(Electrophoretic deposition) 18 1.5.5 滾輪塗佈法 19 1.6 鋼板表面塗層抗蝕性分析方法 20 1.6.1 塔弗曲線(Tafel) 20 1.6.2 電化學阻抗譜(Electrochemical impedance spectroscopy) 22 1.6.3 掃描式電子顯微鏡(Scanning electron microscope) 28 1.6.4 能量色散X射線譜 29 1.6.5 動態光散色粒徑分析儀(Dynamic Light Scattering) 31 1.6.6 鹽霧試驗(Salt-spray test) 32 第二章 實驗部分 33 2.1 實驗藥品與儀器 33 2.1.1 實驗藥品 33 2.1.2 器材與設備 34 2.1.3 分析儀器 35 2.2 配方之製備 40 2.2.1 製備E配方 40 2.2.2 製備DD配方 41 2.2.3 鋯鈍化液之製備 41 2.3 實驗方法 42 2.3.1 鋯鈍化鋼板處理 43 2.3.2 塗佈E配方與DD配方試片 44 2.3.3 掃描式電子顯微鏡試片前處理 45 2.3.4 Tafel曲線數據處理 46 第三章 結果與討論 47 3.1 環保型鋯鈍化塗層之研究 47 3.1.1 不同鈍化液濃度 47 3.1.2 鈍化液pH值對抗蝕性之影響 53 3.2 含矽封孔劑之研究 63 3.2.1 E配方討論 63 3.2.2 DD配方討論 66 3.2.3 不同含矽封孔劑對抗腐蝕性之差異 67 3.3 磷酸皮膜鈍化塗層之探討 73 3.3.1 表面結構與成分分析 73 3.3.2 電化學分析儀測量結果 76 3.4 鋅鎳層與電鍍鎳抗腐蝕之研究 79 3.4.1 表面結構與成分分析 79 3.4.2電化學分析儀量測結果 83 第四章 結論及未來展望 87 參考文獻 89

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