研究生: |
楊顯皓 Yang, Hsien-Hao |
---|---|
論文名稱: |
奈米石墨烯機油基礎性質與實車應用之研究 The Study of Basic Properties and Motorcycle Application by Using Nano Graphene Lubricant Oil |
指導教授: |
呂有豐
Lue, Yeou-Feng |
口試委員: | 莫懷恩 鄧敦平 呂有豐 |
口試日期: | 2022/01/05 |
學位類別: |
碩士 Master |
系所名稱: |
工業教育學系 Department of Industrial Education |
論文出版年: | 2022 |
畢業學年度: | 110 |
語文別: | 中文 |
論文頁數: | 93 |
中文關鍵詞: | 奈米石墨烯機油 、奈米流體 、黏度 、磨潤 、粒狀汙染物 |
英文關鍵詞: | Nano Graphene Lubricant Oil, Nanofluid, Viscosity test, Tribology test, Particulate Matter |
研究方法: | 實驗設計法 |
DOI URL: | http://doi.org/10.6345/NTNU202200077 |
論文種類: | 學術論文 |
相關次數: | 點閱:169 下載:19 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究將奈米石墨烯添加到PGO SL 10W/40 原廠機油中,後續進行基礎性質及實車試驗。基礎性質實驗包括沉降試驗、磨潤試驗、黏度試驗、比熱試驗以及熱傳導試驗;實車試驗包含ECE-40、定速(50 km/h)、平路與爬坡試驗,同時觀察各測試項目數據,分別為引擎性能、廢氣排放、粒狀汙染物、實車溫度測試。在基礎性質試驗中,沉降試驗發現,在觀察沉澱現象的第30天之後,懸浮性最佳濃度為0.01 wt.%。磨潤試驗顯示,0.1 wt.%的磨潤效果最佳,其改善率為72.34 %。黏度試驗顯示,0.03 wt.%在高溫狀態下黏度平均下降了26.51 %。比熱試驗顯示,0.03 wt.%較原廠機油平均下降11.76 %。熱傳導試驗顯示,0.03 wt.%熱傳導係數平均提升10.43 %。最後,由綜合評比顯示,0.03 wt.%為最佳比例。實車試驗中, ECE-40與定速(50 km/h)之平均能源效率改善3.27 %,實車溫度表明,機油溫度的改善率能在5 %以內,高燃燒效率讓引擎室相關件構呈現高溫狀態。廢氣及粒狀污染物排放結果顯示,ECE–40 行車型態下奈米石墨烯機油之CO2的排放量大於原廠機油,小粒徑顆粒數比原廠機油還要多。在定速行車型態、平路以及爬坡行車型態下,結果顯示奈米石墨烯機油的CO2排放量與PM排放量都比原廠機油還要少。
In this research, nano graphene was added to the lubricant oil (PGO SL 10W / 40). Then, the basic properties and motorcycle application experiments were carried out. The experimental contents of basic properties included sedimentation, tribology, viscosity, specific heat and thermal conductivity tests. The experimental contents of motorcycle application included ECE-40, constant speed (50 km/h), flat road and climbing tests. Then, researcher observed the data from each experimental subjects of motorcycle application, including engine efficiency, exhaust emissions, particulate matter emissions, and the temperature of specific parts when the motorcycle was running. In the results of the basic properties experiments, the sedimentation test found that Nano Grephene Lubricant Oil was allowed to stand for 30 days, and the effect of 0.01 wt.% was very stable and had almost no precipitation. The tribology test found that 0.1 wt.% was the best, its tribology improvement rates was 72.34%. The results of the viscosity test showed that the viscosity of 0.03 wt.% at high temperature decreased by 26.51% on average. The specific heat test showed that the value of 0.03 wt.% was 11.76% lower than the original result on average. The thermal conductivity test showed that the thermal conductivity of 0.03 wt.% increased by 10.43% on average. According to the above experimental results, the Nano Grephene Lubricant Oil with 0.03 wt.% was selected to be the best concentration which had better comprehensive effects. In the motorcycle application experiments, under the condition of ECE-40 and constant speed (50 km/h) tests, the average energy efficiency is improved by 3.27%, and the motorcycle specific parts temperature is improved within 5%. The high combustion efficiency allowed the relative engine components to perform higher temperatures. Exhaust emissions and particulate matter emissions results showed that the CO2 emissions of Nano Grephene Lubricant Oil in the ECE-40 experiment was more than original lubricant oil, and the number of small particles was more than original one. During the conditions of constant speed, flat road and climbing tests, CO2 and PM emissions were all slightly lower than the original lubricant oil.
[1] 維基百科,臺灣空氣汙染,取自:https://zh.wikipedia.org/zh-tw/%E8%87%BA%E7%81%A3%E7%A9%BA%E6%B0%A3%E6%B1%A1%E6%9F%93,2021年。
[2] 小世界百科,汽機車所排廢氣 PM 2.5 影響占三成,取自:http://shuj.shu.edu.tw/blog/2018/12/21/%E6%B1%BD%E6%A9%9F%E8%BB%8A%E6%89%80%E6%8E%92%E5%BB%A2%E6%B0%A3-pm2-5%E5%BD%B1%E9%9F%BF%E5%8D%A0%E4%B8%89%E6%88%90/,2018年。
[3] 全國法規資料庫, 固定污染源逸散性粒狀污染物空氣污染防制設施管理辦法,取自:https://law.moj.gov.tw/LawClass/LawAll.aspx?pcode= O0020078,2011年。
[4] 聯合新聞網,健康主題館/空汙拉警報 肺癌找上門,取自:https://udn.com/news/story/7266/5383580,2021年。
[5] 臺大醫院,細懸浮微粒影響你我健康,取自:https://epaper.ntuh.gov.tw/health/201705/project_2.html,2017年。
[6] M. K. A. Ali, X. Hou, and M. A. Abdelkareem, “Anti-wear properties evaluation of frictional sliding interfaces in automobile engines lubricated by copper/graphene nanolubricants,” Friction, vol. 8, no. 5, pp. 905-916, 2020.
[7] J. Xu, T. Luo, X. Chen, C. Zhang, and J. Luo, “Nanostructured tribolayer-dependent lubricity of graphene and modified graphene nanoflakes on sliding steel surfaces in humid air,” Tribology International, vol. 145, 106203, 2020.
[8] G. Lu, X. Shi, X. Liu, H. Zhou, and Y. Chen, “Effects of functionally gradient structure of Ni3Al metal matrix self-lubrication composites on friction-induced vibration and noise and wear behaviors,” Tribology International, vol. 135, pp. 75-88, 2019.
[9] L. Wang, P. Gong, W. Li, T. Luo, and B. Cao, “Mono-dispersed Ag/Graphene nanocomposite as lubricant additive to reduce friction and wear,” Tribology International, vol. 135, 106228, 2020.
[10] F. Leach, G. Kalghatgi, R. Stone, and P. Miles, “The scope for improving the efficiency and environmental impact of internal combustion engines,” Transportation Engineering, vol. 1, 100005, 2020.
[11] P. Soltic and T. Hilfiker, “Efficiency and raw emission benefits from hydrogen addition to methane in a Prechamber–Equipped engine,” International Journal of Hydrogen Energy, vol. 45, no. 43, pp. 23638-23652, 2020.
[12] S. Prakash, M. Prabhahar, O. P. Niyas, S. Faris, and C. Vyshnav, “Thermal barrier coating on IC engine piston to improve efficiency using dual fuel,” Materials Today: Proceedings, vol. 33, pp. 919-924, 2020.
[13] G. Paul, S. Shit, H. Hirani, T. Kuila, and N. C. Murmu, “Tribological behavior of dodecylamine functionalized graphene nanosheets dispersed engine oil nanolubricants,” Tribology International, vol. 131, pp. 605-619, 2019.
[14] W. Khalil, A. Mohamed, M. Bayoumi, and T. A. Osman, “Tribological properties of dispersed carbon nanotubes in lubricant,” Fullerenes Nanotubes and Carbon Nanostructures, vol. 24, no. 7, pp. 479-485, 2016.
[15] N. Arora and M. Gupta, “An updated review on application of nanofluids in flat tubes radiators for improving cooling performance,” Renewable and Sustainable Energy Reviews, vol. 134, 110242, 2020.
[16] C. Li, J. Huang, Y. Shang, and H. Huang, “Study on the flow and heat dissipation of water-based alumina nanofluids in microchannels,” Case Studies in Thermal Engineering, vol. 22, 100746, 2020.
[17] I. Carrillo-Berdugo, R. Grau-Crespo, D. Zorrilla, and J. Navas, “Interfacial molecular layering enhances specific heat of nanofluids: Evidence from molecular dynamics,” Journal of Molecular Liquids, vol. 325, 115217, 2021.
[18] S. Saedodin, M. Zaboli, and S. H. Rostamian, “Effect of twisted turbulator and various metal oxide nanofluids on the thermal performance of a straight tube: Numerical study based on experimental data,” Chemical Engineering and Processing - Process Intensification, vol. 158, 108106, 2020.
[19] H. Singh, V. S. Sharma, S. Singh, and M. Dogra, “Nanofluids assisted environmental friendly lubricating strategies for the surface grinding of titanium alloy: Ti6Al4V-ELI,” Journal of Manufacturing Processes, vol. 39, pp. 241-249, 2019.
[20] Mingshuai Huo, Hui Wu, Haibo Xie, Jingwei Zhao, Guanqiao Su, Fanghui Jia, Zhou Li, Fei Lin, Shengli Li, Hongmei Zhang , and Zhengyi Jiang, “Understanding the role of water-based nanolubricants in micro flexible rolling of aluminium,” Tribology International, vol. 151, 106378, 2020.
[21] K. S. Meenakshi, E. P. J. Sudhan, and P. G. Menon, “Analysis of sulphone based organic–inorganic hybrid epoxy nanocomposites for advanced engineering applications—Study of the mechanical, thermomechanical, XRD, EDS and physical properties,” Materials Science and Engineering: A, vol. 536, pp. 152-158, 2012.
[22] 洪偉修,“世界上最薄的材料--石墨烯”,98康熹化學報報,第 1 ~ 4 頁,980047,2009年11月。
[23] Nanowerk, Electrons can travel over 100 times faster in graphene than in silicon, 取自:https://www.nanowerk.com/news/newsid=5030.php, 2008.
[24] V. B. Mbayachi, E. Ndayiragije, T. Sammani, S. Taj, and E. R. Mbuta, “Graphene synthesis, characterization and its applications: A review,” Results in Chemistry, vol. 3, 100163, 2021.
[25] Ryuichi Kato, Masami Naya, Naoki Kasahata, RyosukeSenga, Chikara Sato, Masanori Koshino, Kazu Suenaga, and Masataka Hasegawa, “Thermal management function of graphene under cryogenic temperature,” Carbon, vol. 183, pp. 970-976, 2021.
[26] F. A. Yunusov, A. D. Breki, E. S. Vasilyeva, and O. V. Tolochko, “The influence of nano additives on tribological properties of lubricant oil,” Materials Today: Proceedings, vol. 30, pp. 632-634, 2020.
[27] Muhammad Khurram, Riaz Ahmad Mufti, Muhammad Usman Bhutta, Naqash Afzal, Muhammad Usman Abdullah, Sami ur Rahman, Saifur Rehman, Rehan Zahid, Khalid Mahmood, Mian Ashfaq, and Muhammad Umar, “Roller sliding in engine valve train: Effect of oil film thickness considering lubricant composition,” Tribology International, vol. 149, 105829, 2020.
[28] S. Perabathula, N. B. Teja, P. H. C. Prasad, M. S. C. Prasad, and S. Thomas, “Performance analysis of mineral oil based nano-lubricants with sulphur impregnated reduced graphene oxide nanosheets,” Materials Today: Proceedings, 2021.
[29] Selman Demirtas, Hakan Kaleli, Mahdi Khadem, and Dae Eun Kim, “Characterization of the friction and wear effects of graphene nanoparticles in oil on the ring/cylinder liner of internal combustion engine,” Industrial Lubrication and Tribology, 2019.
[30] B. Wu, H. Song, C. Li, R. Song, T. Zhang, and X. Hu, “Enhanced tribological properties of diesel engine oil with Nano-Lanthanum hydroxide/reduced graphene oxide composites,” Tribology International, vol. 141, 105951, 2020.
[31] S. S. Sanukrishna, A. V. Raju, A. Krishnan, G. H. Harikrishnan, A. Amal, T. K. Kumar, and M. J. Prakash, “Enhancing the thermophysical properties of PAG lubricant using graphene nano-sheets,” Journal of Physics: Conference Series, vol. 1355, no. 1, 012041, 2019.
[32] B. N. Vats and M. Singh, “Evaluation of tribological properties of graphene oxide dispersed paraffin oil,” Materials Today: Proceedings, vol. 25, pp. 557-562, 2020.
[33] 行政院經濟部標準檢驗局,標準總號:CNS3105,取自:https://www.cnsonline.com.tw/,2009年。
[34] 行政院經濟部能源局,車輛油耗指南,取自:https://auto.itri.org.tw/index.aspx,2019年。
[35] 行政院環境保護署,主管法規查詢系統—機車廢氣排放污染測試方法及程序,取自:https://oaout.epa.gov.tw/law/index.aspx,2019年。
[36] Vânia Martins, Carolina Correia, Inês Cunha-Lopes, Tiago Faria, Evangelia Diapouli, Manousos Ioannis Manousakas, Konstantinos Eleftheriadis, and Susana Marta Almeida, “Chemical characterisation of particulate matter in urban transport modes,” Journal of Environmental Sciences, vol. 100, pp. 51-61, 2021.
[37] Hugo Wihersaari, Liisa Pirjola, Panu Karjalainen, Erkka Saukko, Heino Kuuluvainen, Kari Kulmala, Jorma Keskinen, and Topi Rönkkö, “Particulate emissions of a modern diesel passenger car under laboratory and real-world transient driving conditions,” Environmental Pollution, vol. 265, 114948, 2020.
[38] Zhiyuan Hu, Zhangying Lum, Bo Song, and Yifeng Quan, “Impact of test cycle on mass, number and particle size distribution of particulates emitted from gasoline direct injection vehicles,” Science of The Total Environment, vol. 762, 143128, 2021.
[39] Yong Qian, Zilong Li, Liang Yu, Xiaole Wang, and Xingcai Lu, “Review of the state-of-the-art of particulate matter emissions from modern gasoline fueled engines,” Applied Energy, vol. 238, pp. 1269-1298, 2019.
[40] K. Choi, J. Kim, A. Ko, and C. Myung, “Evaluation of Time-Resolved Nano-Particle and THC Emissions of Wall-Guided GDI Engine,” SAE Technical, pp. 22, 2011.
[41] Kai Shen, Hong Chen, Zhendong Zhang, Bo Wang, and Yingjie Wang, “Experimental study on the effects of exhaust heat recovery system (EHRS) on vehicle fuel economy and emissions under cold start new European driving cycle (NEDC),” Energy Conversion and Management, vol. 197, 111893, 2019.
[42] Tandra Banerjee and R.A. Christian, “Effect of operating conditions and speed on nanoparticle emission from diesel and gasoline driven light duty vehicles,” Atmospheric Pollution Research, vol. 10, no. 6, pp. 1852-1865, 2019.
[43] Jianqin Fu, Banglin Deng, Xiaoqiang Liu, Jun Shu, Ying Xu, and Jingping Liu, “The experimental study on transient emissions and engine behaviors of a sporting motorcycle under World Motorcycle Test Cycle,” Energy, vol. 211, 118670, 2020.
[44] S. M. S. Ardebili, H. Solmaz, A. Calam, and D. İpci, “Modelling of performance, emission, and combustion of an HCCI engine fueled with fusel oil-diethylether fuel blends as a renewable fuel,” Fuel, vol. 290, 120017, 2021.
[45] M. A. Costagliola, F. Murena, and M. V. Prati, “Exhaust emissions of volatile organic compounds of powered two-wheelers: Effect of cold start and vehicle speed. Contribution to greenhouse effect and tropospheric ozone formation,” Science of The Total Environment, vol. 468, pp. 1043-1049, 2014.