簡易檢索 / 詳目顯示
| 研究生： |
游若琳 Rouahlin You |
|---|---|
| 論文名稱： |
碳六十/聚合物石英壓電晶體偵測器之研製與應用 Preparation and Application of Piezoelectric Crystal Detector Based on C60/Polymer Coatings |
| 指導教授： |
施正雄
Shih, Jeng-Shong |
| 學位類別： |
碩士 Master |
| 系所名稱： |
化學系 Department of Chemistry |
| 畢業學年度： | 87 |
| 語文別： | 中文 |
| 論文頁數： | 150 |
| 中文關鍵詞： | 碳六十 、碳六十/聚合物 、石英壓電晶體偵測器 、石英微量天平 |
| 英文關鍵詞： | C60, buckminsterfullerene, piezoelectric crystal detector, quartz crystal microbalance, fullerene polymers |
| 論文種類： | 學術論文 |
| 相關次數： | 點閱：161 下載：0 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
碳六十/聚合物石英壓電晶體偵測器之研製與應用
摘 要
本實驗是利用Friedel-Craft反應合成C60/聚肉桂醛（C60/polycinnamaldehyde, C60/PCA）及C60/聚苯乙炔（C60/polyphenylacetylene, C60/PPA）兩種共聚合物來作為石英壓電晶體之塗佈物質。在C60/PCA石英壓電晶體偵測器中，利用自製微電腦介面中的頻率/電壓（F / V）轉換器，將頻率訊號轉為電壓訊號並以放大器（OPA）放大，再經類比 / 數位（A / D）介面卡轉換成數位訊號後，輸入電腦讀取記錄並繪圖。而在C60/PPA石英壓電晶體偵測器中，則利用含ALTERA及8255卡之介面來讀取振盪頻率及其變化，並以軟體控制介面、讀取數據及繪圖。
在C60/PCA塗佈膜之蛋白質壓電晶體偵測器中，發現血紅素（hemoglobin）及過氧化氫酵素（catalase）有較佳的感應頻率變化。其對血紅素有不錯的靈敏度（6530 Hz / (mg / mL)），良好的濃度線性關係及偵測下限（~ ppm level）。
而在C60/PPA塗佈膜之有機氣體壓電晶體偵測器中，其偵測訊號之大小分別為芳香烴＞炔＞烯＞烷。即使在加熱的情況下，其對甲苯仍有不錯的靈敏度，偵測下限（~ppm）及再現性（RSD = 6.4 ﹪）。此外，我們也發現在加熱的情況下，若以甲苯作為多環芳香烴（PAHs）之溶劑時，C60/PPA塗佈膜對PAHs也有不錯的感應效果。
Preparation and Application of Piezoelectric Crystal Detector Based on C60/Polymer Coatings
Abstract
The C60/polycinnamaldehyde ( C60/PCA ) and C60/polyphenylacetylene ( C60/PPA ) copolymers were synthesized by using the Friedel – Craft reaction and applized as the piezoelectric quartz crystal coating materials.
A C60/polycinnamaldehyde (PCA) coated piezoelectric quartz crystal membrane sensor with a home – made computer interface was prepared and applied as a PZ protein sensor. The adsorption of protein such as hemoglobin onto the C60/PCA coated crystal resulted in the decrease of oscillating frequency. The variations of crystal frequency were converted to voltage with a frequency to voltage converter, and followed by amplification with OPA and data acquisition with analog to digital converter. It was found that hemoglobin had the best signal shift among the testing proteins. The PZ protein sensor exhibited good sensitivity of 6530 Hz / ( mg / mL ) and with detection limit of ppm level for hemoglobin.
Furthermore, a C60/polyphenylacetylene (PPA) coated piezoelectric quartz crystal sensor with an Intell-8255 data processing system for various olefin vapors was also made. The aromatic hydrocarbons such as toluene seems to have greater adsorption onto C60/PPA membrane than alkynes, alkenes and alkanes. The absorption of ploycyclic aromatic hydrocarbons (PAHs) onto the C60/PPA membrane was also investigated. And we found that by using toluene as the solvent for PAHs, the C60/PPA membrane has a much larger frequency shift for naphthalene.
參 考 資 料
1. Pederson, C. J. J. Am. Chem. Soc. 1967, 89, 7017.
2. Dietrich, B.; Lehn, J. M.; Sauvage, T. P. Tetrahedron Lett. 1969, 34, 2889.
3. Pederson, C. J. J. Am. Chem. Soc. 1970, 92, 386.
4. Christensen, J. J.; Eatough, D. J.; Izatt, R. M. Chem. Rev. 1974, 74, 351.
5. Mathias, L. J. J. Macromol. Sci. Chem. 1981, A15(5), 853.
6. Reger, S. L. J. Org. Chem. 1977, 42, 875.
7. Koto, H. W.; Hearth, J. R.; O’Brien, S. C.; Curl, R. F.; Smalley, R. E. Nature, 1985, 318, 162.
8. Kratschmer, W.; Lamb, L. D.; Fortiropoulos, K.; Huffman, D. R. Nature, 1990, 347, 354.
9. Withers, J. C.; Loutfy, R. O.; Lowe, T. P. Fullerene Science And Technology, 1997, 5(1), 1.
10. Scrirens, W. A.; Bedworth, P. V.; Tour, J. M. J. Am. Chem. Soc. 1992, 114, 7917.
11. Hawkins, J. M.; Meyer, A.; Lewis, T. A.; Loren, S.; Hollander, F. J. Science 1991, 252, 312.
12. Wanxi Chen; Zhude Xu Fullerene Science And Technology 1998, 6(4), 695.
13. Liu, T. Y.; Her, G. R. Chemistry(The Chinese Chem. Soc., Taiwan China) 1994, 52(1), 85.
14. Ajie, H.; Alvarez, M. M.; Anz, S. J.; Beck, R. D.; Diederich, F.; Fostiropoulos, K.; Huffman, D. R.; Kratschmer, W.; Rubin, Y.; Schriver, K. E.; Sensharma, K.; Whetten, R. L. J. Phys. Chem. 1990, 94, 8630.
15. Hare, T. P.; Koto, H. W.; Taylor, R. Chem. Phys. Lett. 1991, 177, 394.
16. Taylor, R.; Hare, J. P.; Abdul-Sada, A. K.; Kroto, H. W. J. Chem. Soc. Chem. Commun. 1990, 1423.
17. Kroto, H. W.; Allaf, A. W.; Balm, S. P. Chem. Rev. 1991, 91, 1213.
18. 鄧金培; 牟中原; 科學月刊, 1992, 20(9), 654.
19. Xie, Q.; Cordero, E. P.; Echegoyen, L. J. Am. Chem. Soc. 1992, 114, 3978.
20. Haufler, R. E.; Conceicas, J,; Chibante, L. P. F.; Byrne, N. E.; Flangan, S.; Haley, M. M.; O’Brien, S. C.; Pan, C.; Xiao, Z.; Billups, W. E.; Ciufolini, M. A.;Smalley, R. H.; J. Phys. Chem. 1990, 94, 8634.
21. Chiang, L. Y.; Upasani, R. B.; Swirczewski, J. W. J. Am. Chem. Soc. 1992, 114, 10154.
22. Chiang, L. Y.; Upasani, R. B.; Swirczewski, J. W.; Soled, S. J. Am. Chem. Soc. 1993, 115, 5453.
23. Li, J.; Takeuchi, A.; Wzawa, M.; Li, X.; Saigo, K.; Kitazawa, K. J. Chem. Soc. Chem. Commun. 1993, 1784.
24. Kampe, K. D.; Egger, N.; Vogel, M. Angew. Chem. Int. Ed. Engl. 1993, 32(8), 1174.
25. Davey, S. N.; Leigh, D. A.; Moody, A. E.; Tether, L. W.; Wade, F. A. J. Chem. Soc. Chem. Commun. 1994, 397.
26. Cox, D. M.; Creegan, K. M.; Robbins, J. L.; Robbins, W. K.; Millar, J. M.; Sherwood, R. D.; Tindall, D. J. J. Am. Chem. Soc. 1992, 114, 1103.
27. Beck, R. D.; Kappes Etal, M. M. J. Chem. Phys. 1994, 101, 3243.
28. Whetten, R. L.; Scott, K. Y. E.; Chimin Sheu, S.; Foote, C. S.; Alvarez, M. M. Angew. Chem. Int. Ed. Engl. 1992, 31, 351.
29. Selig, H.; Lifshitz, C.; Peres, T.; Fisher, J. E.; Mcghie, A. R.; Romanow, W. J.; McCauley, J. P.; Smith III, A. B. J Am. Chem. Soc. 1991, 113, 5475.
30. Kniaz, K.; Fischer, J. E.; Selig, H.; Vaughan, G. B. M.; Romanow, W. J.; Cox, D. M.; Chowdhury, S. K.; McCauley, J. P.; Strongin, R. M.; Smith III, A. B. J. Am. Chem. Soc. 1993,115,6060.
31. Birkett, P. R.; Hitchcock, P. B.; Kroto, H. W.; Taylor, R.; Walton, D. R. M. Nature, 1992, 357, 479.
32. Olah, G. A.; Bucsi, I.; Lambert, C.; Aniszfeld, R.; Triredi, N. J.; Sensharma, D. K.; Wasserman, E., Jr Young, R. J. J. Am. Chem. Soc. 1991, 113, 9385.
33. Caron, C.; Subramanian, R.; D’Souza, F.; Kim, J.; Kutner, W.; Jones, M. T.; Kadish, K. M. J. Am. Chem. Soc. 1993,115,8505.
34. Henderson, C. C.; Cahall, P. A. Science, 1993, 259, 1995.
35. Ballenweg, S.; Gleiter, R.; Kratchmer, W. Tetrahedro Lett. 1993, 34, 3737.
36. Skiebe, A.; Hirsch, A. J. Chem. Soc. Chem. Commun. 1994, 335.
37. Cooks, R. G.; Hoke II, S. H.; Dominique Dillettato, J. M.; Dean Carlson, M. J. J.; Bart Kahr, D. C. J. Org. Chem. 1992, 57,5069.
38. Wilson, S. R.; Kaprinindis, N.; Wu, Y.; Schuster, D. I.; Welch, C. J. J. Org. Chem. 1993, 58, 6548.
39. Shiu, L. L. Chemistry (The Chinese Chem. Soc., Taiwan China) 1994, 52(1), 43.
40. An, Y. Z.; Anderson, J. L.; Rubin, Y. J. Org. Chem. 1993, 58, 4779.
41. Fagan, P. J.; Calabrese, J. C.; Malone, B. Science 1991,252,1160.
42. Hirsch, A. Adv. Mater. 1993, 5(11), 859.
43. Loy, D. A.; Assink, R. A. J. Am. Chem. Soc. 1992, 114, 3977.
44. Bunker C. E.; Lawson, G. E.; Sun, Y. P. Macromolecules 1995, 28, 3744.
45. Patil, A. O.; Brois, S. J. Polymer 1997, 38(13), 3423.
46. Samulski, E. T.; Desimone, J. M.; Hunt, M. O.; Menceloglu, Y. Z.; Jaragin, R. C.; York, G. A.; Labat, K. B.; Wang, H. Chem. Mater. 1992, 4, 1153.
47. Bergbreiter D. E.; Gray, H. N. J. Chem. Soc. Chem. Commun. 1993, 645.
48. Geckeler, K. E.; Hirsch, A. J. Am. Chem. Soc. 1993, 115, 3850.
49. Weis, C.; Friedrich, C.; Mulhaupt, R.; Frey, H. Macromolecules 1995, 28, 403.
50. Hawker, C. J. Macromolecules 1994, 27, 4836.
51. Hawker, C. J.; Wooley, K. L.; Frechet, J. M. J. J. Chem. Soc. Chem. Commun. 1994, 925.
52. Cloutet, E,; Gnanou, Y.; Fillaut, J. L.;Astruc. D. Chem. Commun. 1996, 1565.
53. Guhr, K. I.; Greaves, M. D.; Rotello, V. M. J. Am. Chem. Soc 1994, 116, 5997.
54. Nie, B.; Rotello, V. J. Phys. Chem. Solids. 1997, 58(11), 1897.
55. Olah, G. A.; Bucsi, I.; Lambert, C.; Aniszfeld, R.; Trivedi, N. J.; Sensharma, D. K.; Prakash, G. K. S. J. Am. Chem. Soc. 1991,113,9387.
56. Olah, G. A.; Bucsi, I.; Ha, D. S.; Aniszfeld, R.; Lee, C. S.; Prakash, G. K. S. Fullerene Science And Technology 1997, 5(2), 389.
57. Liu, B.; Bunker, C. E.; Sun, Y. P. Chem. Commun. 1996, 1241.
58. Taki, M.; Takigami, S.; Watanabe, Y.; Nakamura, Y.; Nishimura, J. Polymer Journal 1997, 29(12), 1020.
59. Ederle, Y.; Reibel, D.; Mathis, C. Synthetic Metals 1996, 77, 139.
60. Dai, L.; Mau, A. W. H.; Zhang, X. J. Mater. Chem. 1998, 8(2), 325.
61. Muthu, S.; Maruthamuthu, P. Fullerene Science And Technology 1996, 4(3), 399.
62. Jinno, K.; Tanabe, K.; Saito, Y.; Nagashima, H. Analyst 1997, 122, 787.
63. Jinno, K.; Tanabe, K.; Saito, Y.; Nagashima, H.; Trengove, R. D. Analytical Communciations 1997, 34, 175.
64. Sauerbrey, G. Z. Z. Phys. 1959, 155, 206.
65. Halaray, J.; Gahbault, G. G. Anal. Chem. 1977, 49, 1890.
66. Thompson, M.; Kipling, A. L.; Duncan-Hewitt, W. C. Analyst 1991, 116, 881.
67. Konash, P. L.;Basiaans, G. J. Anal. Chem. 1980, 52, 1929.
68. Bruckenstein, S. Electrochemica Acta 1985, 80, 1295.
69. King, W. H. Anal. Chem. 1964, 36, 1735.
70. Dickert, F. L.; Zenkel, M. E.; Bulst, W. E.; Fischerauer, G.; Knauer, U. Fresenius J. Anal. Chem. 1997, 357, 27.
71. Sugimoto, I. Analyst 1998, 123, 1849.
72. Jarrett, M. R.; Finklea, H. O. Anal. Chem. 1999, 71, 353.
73. Schulz, W. W.; King, W. H. J. Chromatog. Sci. 1973, 11, 343.
74. Rickert, J.; Brecht, A.; Gopel, W. Anal. Chem. 1997, 69, 1441.
75. Caruso, F.; Rodda, E.; Furlong, D. N. Anal. Chem. 1997, 69, 2043.
76. Gizeli, E.; Liley, M.; Lowe, C. R.; Vogel, H. Anal. Chem. 1997, 69, 4808.
77. Li, W.; Su, X.; Guo, H.; Wei, W.; Yao, S. Analyst 1999, 124, 91.
78. Jane, Y. S.; Shih, J. S. Journal of Molecular Catalysis 1994, 89, 29.
79. Luo, S. Q.; Shih, J. S. J. Chin. Colloid and Interface Soc. 1995, 18(3), 143.
80. Chang, P.; Shih, J. S. Analytica Chimica Acta in press.
81. 凌永健, 陳秋雲, 黃依萍; 科儀新知, 1994, 16(1), 70.
82. Chao, Y. C.; Shih, J. S. Analytica Chimica Acta 1998, 374, 39.
83. 高文弘, 周孟儒譯著; “界面化學” 黎明書局, 1983.
84. Chang. P.; Shih. J. S. Analytica Chimica Acta 1998, 360, 61.
