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研究生: 柯棋澤
KO, Chi-Tse
論文名稱: 結合無線傳輸之布基摩擦起電元件的研製
Development of fabric-based triboelectric devices combined with wireless transmission
指導教授: 楊啓榮
Yang, Chii-Rong
學位類別: 碩士
Master
系所名稱: 機電工程學系
Department of Mechatronic Engineering
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 116
中文關鍵詞: 布料氧化石墨烯單極式摩擦起電器無線傳輸
英文關鍵詞: fabric, graphene oxide, single-electrode-mode triboelectric nanogenerators, wireless transmission
DOI URL: http://doi.org/10.6345/NTNU202001377
論文種類: 學術論文
相關次數: 點閱:115下載:0
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  • 摩擦起電器(Triboelectric generator, TEG)是藉由簡單的物理性接觸,將機械能轉換為電能輸出。然而,目前多數的摩擦起電器主要是使用金屬與ITO薄膜作為電極材料,這些材料的可撓性較差使得摩擦起電器的應用受到侷限,故本論文使用市售的導電布料當作電極,並使用平滑、粗糙、多孔與含有氧化石墨烯(Graphite oxide, GO)等四種PDMS作為摩擦層,實現製作簡單、低成本、高可撓性、高穩定性,且尺寸為70×50 mm2的單電極式布基摩擦起電元件。
    研究結果顯示使用含有GO之PDMS (GO@PDMS)作為摩擦層的元件,透過SF6電漿進行表面改質處理,具有最佳的開路電壓與短路電流輸出,分別為140.37 V與2.57 μA。此外,也發現加厚摩擦層會使接觸時之表面積有一定程度的增加,但是約到1.6 mm時能增加的接觸面積已趨近飽和,而在持續增加厚度的情況下,輸出性能反而會呈現降低的趨勢。此外,也針對元件的作動頻率與施力大小對輸出性能進行探討,發現作動頻率越高對於輸出電流有較明顯的提升,而作動元件之外力逐漸增加也能使輸出提升,但當施力達6 N以上輸出會趨近穩定。最後,本研究也評估負載電阻對輸出電壓與輸出電流的影響,並進一步得知當負載電阻為50 MΩ時,可得到的最大功率為130.5 μW。
    此外,經由耐久性與耐洗性的測試,證實本論文發展的元件之性能極為穩定,並藉由元件之柔軟與舒適的特點,將其整合至衣服、鞋子與褲子,以獲取運動過程中所產生的能量,藉由不同的動作獲取機械能,而得到相對應的輸出電壓與波形,並藉由波型的特徵來判斷動作形態,故可達到動作感測的應用。最後,用手拍打元件可將180顆串聯的綠光LED燈泡點亮,也使用橋式整流電路並聯電容器,再將其充電,透過按鍵開關將能量用來驅動LED燈,證明本研究之元件確實可以當作微型發電機來使用。另外,為了達成無線傳輸與感測的應用,也透過藍芽無線模組與兩個反向放大器,將布基摩擦起電元件所感測到的電壓訊號經過訊號處理後,可無線傳至電腦或手機APP中並顯示即時的波形,證明其未來可應用於具無線傳輸功能的感測領域。

    Triboelectric generators (TEGs) use simple physical contact to convert mechanical energy into electrical output. However, most of the TEGs mainly use metal and ITO films as electrode materials. These materials without high flexibility will limit the application of the TEGs. Therefore, this study uses commercially available conductive fabrics as electrodes, and uses four PDMS surfaces with smooth, rough, porous and graphene oxide (GO) as the friction layers, to achieve simple production, low cost, high flexibility, high stability single-electrode-mode fabric-based triboelectric devices with the size of 70 × 50 mm2.
    The results show that the fabric-based triboelectric device using PDMS with GO (GO@PDMS) as the friction layer has the best open circuit voltage and short circuit current output after SF6 plasma surface modification treatment, which are 140.37 V and 2.57 μA respectively. In addition, it was also found that when the thickness of the friction layer increases, the surface area during contact will increase to a certain extent. But when it is about 1.6 mm, the contact area that can be increased and close to saturation, so it will only increase the thickness and reduce the output performance as the thickness is over 1.6 mm. We also discussed in terms of devices actuation frequency and applied force. It is found that the higher the actuation frequency, the output current increases significantly, and the gradual increase of the applied force can increase the output performance, but when the force reaches 6 N or more, the output will tend to be stable.
    Evaluated the effect of load resistance on the output voltage and current, and further learned that when the load resistance is 50 MΩ, the maximum power is 130.5 μW. Durability and washing resistance tests also confirmed that the performance of the device is extremely stable. We integrated the device into clothes, shoes and trousers to obtain the energy generated during exercise, and the different wave patterns collected can be used to determine the action form, so it can be used for motion sensing. On palm tapping the device, 180 green LEDs connected in series can be lit up, and also use a bridge rectifier circuit in parallel with capacitors, and then charge them. The energy can drive the LEDs through the switch key.
    The Bluetooth wireless module and two reverse amplifiers are also used to process the voltage signals sensed by the device, which can be wirelessly transmitted to a computer or mobile APP, proving that it can be applied to the sensing field with wireless transmission function in the future.

    第一章 緒論 1 1.1 前言 1 1.2 產生靜電的方式 3 1.3 摩擦起電器簡介 4 1.4 感測器 6 1.5 無線傳輸技術 9 1.6 研究動機與目的 10 1.7 論文架構 12 第二章 理論探討與文獻回顧 13 2.1 摩擦起電器的四種基本操作模式 13 2.2 摩擦起電器理論研究 17 2.3 摩擦起電器材料的選擇 19 2.4 基於紡織品的TENG (Textile-TENG, T-TENG)結構設計 29 2.5 溫度與濕度的影響 31 2.6 提升摩擦起電性能之方法 34 2.7 摩擦起電器作為自供電感測器之應用 40 2.8 摩擦起電器結合無線傳輸之應用 51 第三章 實驗設計與規劃 55 3.1 實驗程序規劃 55 3.1.1 提升摩擦層表面粗糙度 58 3.1.2 量測系統測試之架設 60 3.1.3 布基摩擦起電元件的製程與性能測試 61 3.1.4 布基摩擦起電元件作為自供電裝置之實務應用 64 3.1.5 布基摩擦起電元件作為感測器並結合無線傳輸之應用 64 3.2 實驗器材 65 第四章 結果與討論 71 4.1 導電布料的特性 71 4.1.1 電極導電性量測 72 4.2 摩擦層之微/奈米級結構的形貌分析 72 4.3 布基摩擦起電元件的組裝 79 4.4 布基摩擦起電元件的性能測試 81 4.4.1 布基摩擦起電元件的發電機制 81 4.4.2 摩擦層結構改良之輸出性能進行評估 84 4.4.3 電漿處理後與摩擦層厚度之輸出性能評估 89 4.4.4 電性輸出特性之量測 91 4.4.5 與其他摩擦起電器性能之比較以及可靠度之評估 96 4.5 布基摩擦起電元件的的實務應用 99 4.5.1 基礎人體活動感測與驅動LED燈泡 99 4.5.2 布基摩擦起電元件的結合無線傳輸之即時壓力感測器 106 4.5.3 性能表現與特性比較 107 第五章 結論與未來展望 108 5.1 結論 108 5.2 未來展望 111 參考文獻 112

    1. Z. L. Wang and J. Song, “Piezoelectric nanogenerators based on zinc oxide nanowire arrays”, Science, Vol. 312, pp. 242-246, 2006.
    2. S. Wang, L. Lin, and Z. L. Wang, “Triboelectric nanogenerators as self-powered active sensors”, Nano Energy, Vol. 11, pp. 436-462, 2015.
    3. Z. L. Wang, “Triboelectric nanogenerators as new energy technology for self-powered systems and as active mechanical and chemical sensors”, ACS Nano, Vol. 7, No. 11, pp. 9533-9557, 2013.
    4. W. Chen and X. Yan, “Progress in achieving high-performance piezoresistive and capacitive flexible pressure sensors: A review”, Journal of Materials Science & Technology, Vol. 43, pp. 175-188, 2020.
    5. M. L. Hammock, A. Chortos, B. C. K. Tee, J. B. H. Tok, and Z. Bao, “25th anniversary article: The evolution of electronic skin (E-Skin): A brief history, design considerations, and recent progress”, Advanced Materials, Vol. 25, pp. 5997-6038, 2013.
    6. J. He, Y. Zhang, R. Zhou, L. Meng, C. Pan, W. Mai, and T. Chen, “Recent advances of wearable and flexible piezoresistivity pressure sensor devices and its future prospects”, Journal of Materiomics, Vol. 6, pp. 86-101, 2020.
    7. J. Luo and Z. L. Wang, “Recent advances in triboelectric nanogenerator based self-charging power systems”, Energy Storage Materials, Vol. 23, pp. 617-628, 2019.
    8. G. Zhu, Z. H. Lin, Q. Jing, P. Bai, C. Pan, Y. Yang, Y. Zhou, and Z. L. Wang, “Toward large-scale energy harvesting by a nanoparticle-enhanced triboelectric nanogenerator”, Nano Letters, Vol. 13, pp. 847-853, 2013.
    9. S. Wang, L. Lin, Y. Xie, Q. Jing, S. Niu, and Z. L. Wang, “Sliding-triboelectric nanogenerators based on in-plane charge-separation mechanism”, Nano Letters, Vol. 13, pp. 2226-2233, 2013.
    10. Y. C. Lai, J. Deng, S. L. Zhang, S. Niu, H. Guo, and Z. L. Wang, “Single-thread-based wearable and highly stretchable triboelectric nanogenerators and their applications in cloth-based self-powered human-interactive and biomedical ensing”, Advanced Functional Materials, Vol. 27, pp. 1604462, 2016.
    11. S. Wang, Y. Xie, S. Niu, L. Lin, and Z. L. Wang, “Freestanding triboelectric-layer-based nanogenerators for harvesting energy from a moving object or human motion in contact and non-contact modes”, Advanced Materials, Vol. 26, pp. 2818-2824, 2014.
    12. S. Niu, S. Wang, L. Lin, Y. Liu, Y. S. Zhou, Y. Hu, and Z. L. Wang, “Theoretical study of contact-mode triboelectric nanogenerators as an effective power source”, Energy & Environmental Science, Vol. 6, pp. 3576, 2013.
    13. S. Niu, Y. Liu, S. Wang, L. Lin, Y. S. Zhou, Y. Hu, and Z. L. Wang, “Theory of sliding-mode triboelectric nanogenerators”, Advanced Materials, Vol. 25, pp. 6184-6193, 2013.
    14. D. K. Davies, “Charge generation on dielectric surfaces”, Journal of Physics D: Applied Physics, Vol. 2, pp.1533-1537, 1969.
    15. H. J. Kim, E. C. Yim, J. H. Kim, S. J. Kim, J. Y. Park, and I. K. Oh, “Bacterial nano‐cellulose triboelectric nanogenerator”, Nano Energy, Vol. 33, pp. 130-137, 2017.
    16. J. Shen, Z. Li, J. Yu, and B. Ding, “Humidity-resisting triboelectric nanogenerator for high performance biomechanical energy harvesting”, Nano Energy, Vol. 40, pp. 282-288, 2017.
    17. Y. Chi, K. Xia, Z. Zhu, J. Fu, H. Zhang, C. Du, and Z. Xu, “Rice paper-based biodegradable triboelectric nanogenerator”, Microelectronic Engineering, Vol. 216, pp. 111059, 2019.
    18. Z. Zhao, Q. Huang, C. Yan, Y. Liu, X. Zeng, X. Wei, Y. Hu, and Z. Zheng, “Machine-washable and breathable pressure sensors based on triboelectric nanogenerators enabled by textile technologies”, Nano Energy, Vol. 70, pp. 104528, 2020.
    19. V. T. Bui, J. H. Oh, J. N. Kim, Q. Zhou, D. P. Huynh, and I. K. Oh, “Nest-inspired nanosponge-Cu woven mesh hybrid for ultrastable and high-power triboelectric nanogenerator”, Nano Energy, Vol. 71, pp. 104561, 2020.
    20. H. Guo, J. Chen, Q. Leng, Y. Xi, M. Wang, X. He, and C. Hu, “Spiral-interdigital-electrode-based multifunctional device: Dual-functional triboelectric generator and dual-functional self-powered sensor”, Nano Energy, Vol. 12, pp. 626-635, 2015.
    21. H. Chu, H. Jang, Y. Lee, Y. Chae, and J.-H. Ahn, “Conformal, graphene-based triboelectric nanogenerator for self-powered wearable electronics”, Nano Energy, Vol. 27, pp. 298-305, 2016.
    22. J. Chen, P. Ding, R. Pan, W. Xuan, D. Guo, Z. Ye, W. Yin, H. Jin, X. Wang, S. Dong, and J. Luo, “Self-powered transparent glass-based single electrode triboelectric motion tracking sensor array”, Nano Energy, Vol. 34, pp. 442-448, 2017.
    23. R. I. Haque, O. Chandran, S. Lani, and D. Briand, “Self-powered triboelectric touch sensor made of 3D printed materials”, Nano Energy, Vol. 52, pp. 54-62, 2018.
    24. W. Paosangthong, R. Torah, and S. Beeby, “Recent progress on textile-based triboelectric nanogenerators”, Nano Energy, Vol. 55, pp. 401-423, 2019.
    25. S. S. Kwak, H. Kim, W. Seung, J. Kim, R. Hinchet, and S. W. Kim, “Fully stretchable textile triboelectric nanogenerator with knitted fabric structures”, ACS Nano, Vol. 11, pp. 10733-10741, 2017.
    26. J. Chen, Y. Huang, N. Zhang, H. Zou, R. Liu, C. Tao, X. Fan, and Z. L. Wang, “Micro-cable structured textile for simultaneously harvesting solar and mechanical energy”, Nature Energy, Vol. 1, 2016.
    27. V. Nguyen and R. Yang, “Effect of humidity and pressure on the triboelectric nanogenerator”, Nano Energy, Vol. 2, pp. 604-608, 2013.
    28. X. Wen, Y. Su, Y. Yang, H. Zhang, and Z. L. Wang, “Applicability of triboelectric generator over a wide range of temperature”, Nano Energy, Vol. 4, pp. 150-156, 2014.
    29. Y. Su, J. Chen, Z. Wu, and Y. Jiang, “Low temperature dependence of triboelectric effect for energy harvesting and self-powered active sensing”, Applied Physics Letters, Vol. 106, pp. 013114, 2015.
    30. F.-R. Fan, L. Lin, G. Zhu, W. Wu, R. Zhang, and Z. L. Wang, “Transparent triboelectric nanogenerators and self-powered pressure sensors based on micropatterned plastic films”, Nano Letters, Vol. 12, pp. 3109-3114, 2012.
    31. G. Cheng, Z. H. Lin, L. Lin, Z. L. Du, and Z. L. Wang, “Pulsed nanogenerator with huge instantaneous output power density”, ACS Nano, Vol. 7, pp. 7383-7391, 2013.
    32. G. Wang, Y. Xi, H. Xuan, R. Liu, X. Chen, and L. Cheng, “Hybrid nanogenerators based on triboelectrification of a dielectric composite made of lead-free ZnSnO3 nanocubes”, Nano Energy, Vol. 18, pp. 28-36, 2015.
    33. S. Wang, Y. Xie, S. Niu, L. Lin, C. Liu, Y. S. Zhou, and Z. L. Wang, “Maximum surface charge density for triboelectric nanogenerators achieved by ionized-air injection: methodology and theoretical understanding”, Advanced Materials, Vol. 26, pp. 6720-6728, 2014.
    34. S. H. Shin, Y. H. Kwon, Y. H. Kim, J. Y. Jung, M. H. Lee, and J. Nah, “Triboelectric charging sequence induced by surface functionalization as a method to fabricate high performance triboelectric generators”, ACS Nano, Vol. 9, pp. 4621-4627, 2015.
    35. W. Seung, M. K. Gupta, K. Y. Lee, K. S. Shin, J. H. Lee, T. Y. Kim, S Kim, J. Lin, J. H. Kim, and S.-W. Kim, “Nanopatterned textile-based wearable triboelectric nanogenerator”, ACS Nano, Vol. 9, pp. 3501-3509, 2015.
    36. J. Yang, J. Chen, Y. Su, Q. Jing, Z. Li, F. Yi, X. Wen, Z. Wang, and Z. L. Wang, “Eardrum-inspired active sensors for self-powered cardiovascular system characterization and throat-attached anti-interference voice recognition”, Advanced Materials, Vol. 27, pp. 1316-1326, 2015.
    37. G. H. Lim, S. S. Kwak, N. Kwon, T. Kim, H. Kim, S. M. Kim, S. W. Kim, B. Lim, “Fully stretchable and highly durable triboelectric nanogenerators based on gold-nanosheet electrodes for self-powered human-motion detection”, Nano Energy, Vol. 42, pp. 300-306, 2017.
    38. S. B. Jeon, S. J. Park, W. G. Kim, I. W. Tcho, I. W. Jin, J. K. Han, D. Kim, and Y. K. Choi, “Self-powered wearable keyboard with fabric based triboelectric nanogenerator”, Nano Energy, Vol. 53, pp. 596-603, 2018.
    39. Z. Zhang, K. Du, X. Chen, C. Xue, and K. Wang,, “An air-cushion triboelectric nanogenerator integrated with stretchable electrode for human-motion energy harvesting and monitoring”, Nano Energy, Vol. 53, pp. 108-115, 2018.
    40. C. Garcia, I. Trendafilova, and J. S. D. Rio, “Detection and measurement of impacts in composite structures using a self-powered triboelectric sensor”, Nano Energy, Vol. 56, pp. 443-453, 2019.
    41. M. T. Rahman, M. Salauddin, P. Maharjan, M. S. Rasel, H. Cho, and J. Y. Park, “Natural wind-driven ultra-compact and highly efficient hybridized nanogenerator for self-sustained wireless environmental monitoring system”, Nano Energy, Vol. 57, pp. 256-268, 2019.
    42. H.-J. Qiu, W. Z. Song, X.-X. Wang, J. Zhang, Z. Fan, M. Yu, S. Ramakrishna, and Y. Z. Long, “A calibration-free self-powered sensor for vital sign monitoring and finger tap communication based on wearable triboelectric nanogenerator”, Nano Energy, Vol. 58, pp. 536-542, 2019.
    43. T. He, Z. Sun, Q. Shi, M. Zhu, D. V. Anaya, M. Xu, T. Chen, M. R. Yuce, A. V. Y. Thean, and C. Lee, “Self-powered glove-based intuitive interface for diversified control applications in real/cyber space”, Nano Energy, Vol. 58, pp. 641-651, 2019.
    44. X. Zhao, G. Wei, X. Li, Y. Qin, D. Xu, W. Tang, H. Yin, X. Wei, and L. Jia, “Self-powered triboelectric nano vibration accelerometer based wireless sensor system for railway state health monitoring”, Nano Energy, Vol. 34, pp. 549-555, 2017.
    45. K. Meng, J Chen, X. Li, Y. Wu, W. Fan, Z. Zhou, Q. He, X. Wang, X. Fan, Y. Zhang, J. Yang, and Z. L. Wang, “Flexible weaving constructed self‐powered pressure sensor enabling continuous diagnosis of cardiovascular disease and measurement of cuffless blood pressure”, Advanced Functional Materials, pp. 1806388, 2018.
    46. D. V. Anaya, T. He, C. Lee, and M. R. Yuce, “Self-powered eye motion sensor based on triboelectric interaction and near-field electrostatic induction for wearable assistive”, Nano Energy, Vol. 72, pp. 104675, 2020.
    47. L. Dhakar, P. Pitchappa, F. E. H. Tay, and C. Lee, “An intelligent skin based self-powered finger motion sensor integrated with triboelectric nanogenerator”, Nano Energy, Vol. 19, pp. 532-540, 2016.
    48. V. Harnchana, H. V. Ngoc, W. He, A. Rasheed, H. Park, V. Amornkitbamrung, and D. J. Kang, “Enhanced power output of a triboelectric nanogenerator using poly(dimethylsiloxane) modified with graphene oxide and sodium dodecyl sulfate”, ACS Applied Materials & Interfaces, Vol. 10, pp. 25263-25272, 2018.
    49. W. B. Ko, D. S. Choi, C. H. Lee, J. Y. Yang, G. S. Yoon, and J. P. Hong, “Hierarchically nanostructured 1d conductive bundle yarn-based triboelectric nanogenerators”, Advanced Materials, Vol. 29, pp. 1704434, 2017.
    50. Y. H. Ko, G. Nagaraju, and J. S. Yu, “Multi-stacked PDMS-based triboelectric generators with conductive textile for efficient energy harvesting”, RSC Advances, Vol. 5, pp. 6437-6442, 2015.
    51. W. Gong, C. Hou, Y. Guo, J. Zhou, J. Mu, Y. Li, Q. Zhang, and H. Wang, “A wearable, fibroid, self-powered active kinematic sensor based on stretchable sheath-core structural triboelectric fibers”, Nano Energy, Vol. 39, pp. 673-683, 2017.
    52. S. Jung, J. Lee, T. Hyeon, M. Lee, and D. H. Kim, “Fabric-based integrated energy devices for wearable activity monitors”, Advanced Materials, Vol. 26, pp. 6329-6334, 2014.
    53. P. S. Das, J. Y. Park, and D. H. Kim, “Vacuum filtered conductive nylon membrane-based flexible TENG for wearable electronics”, Micro & Nano Letters, Vol. 12, pp. 697-700, 2017.
    54. Z. Zhao, C. Yan, Z. Liu, X. Fu, L.-M. Peng, Y. Hu, and Z. Zheng, “Machine-washable textile triboelectric nanogenerators for effective human respiratory monitoring through loom weaving of metallic yarns”, Advanced Materials, Vol. 28, pp. 10267-10274, 2016.
    55. M. Shi, H. Wu, J. Zhang, M. Han, B. Meng, and H. Zhang, “Self-powered wireless smart patch for healthcare monitoring”, Nano Energy, Vol. 32, pp. 479-487, 2017.
    56. X. Li, Z.-H. Lin, G. Cheng, X. Wen, Y. Liu, S. Niu, and Z. L. Wang, “3D fiber-based hybrid nanogenerator for energy harvesting and as a self-powered pressure sensor”, ACS Nano, Vol. 8, pp. 10674-10681, 2014.
    57. S. Li, Q. Zhong, J. Zhong, X. Cheng, B. Wang, B. Hu, and J. Zhou, “Cloth-based power shirt for wearable energy harvesting and clothes ornamentation”, ACS Applied Materials & Interfaces, Vol. 7, pp. 14912-14916, 2015.

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