研究生: |
陳柏勳 BO-XUN CHEN |
---|---|
論文名稱: |
雙晶片-多維度氣相層析模組開發與研製 The development of a multi-dimension gas chromatography module using dual chip |
指導教授: | 呂家榮 |
學位類別: |
碩士 Master |
系所名稱: |
化學系 Department of Chemistry |
論文出版年: | 2011 |
畢業學年度: | 99 |
語文別: | 中文 |
論文頁數: | 81 |
中文關鍵詞: | 微層析晶片 、二維氣相層析 、平行分離層析 |
論文種類: | 學術論文 |
相關次數: | 點閱:66 下載:2 |
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本研究藉由微機電製程技術(micro electro mechanical system ,MEMS)製作單管柱氣相微層析晶片與多管柱平行分離氣相微層析晶片(μ-column),微層析晶片大小為3 cm × 3 cm,選擇Stop-flow GC × GC為系統架構,配合多管柱微層析晶片為第二維分離管柱,且塗佈不同選擇性的靜相材料(DB-1、OV-225、OV-210)於各管柱中,建構Stop-flow GC × GCs系統,第一維微層析晶片無法分離的混合物,可利用第二維不同選擇性的三個分離管柱分離,且同步得三張不同結果的3D層析圖譜,此模組可以最短管柱分離複雜混合物,各層析圖譜流經的管柱長僅4公尺。
選擇14種沸點差距70 ℃揮發性有機氣體(VOCs)為待測氣體,其中有四組混合物無法被第一維(DB-1)微層析晶片分離,且每一組混合物僅含兩種化合物,利用第二維微層析晶片的三個管柱便能有效分離,更進一步挑戰17種沸點差距47 ℃的混合物進行分離測試,此組混合物有兩組訊號峰各含有7種與3種化合物,複雜度較14種化合物高,更能表現此膜組的分離效果。
任一化合物在固定實驗參數下進行實驗,3組3D層析圖譜可得3組座標(x,y),x與y座標為第一維與第二維微層析晶片滯留時間,3組座標可做為其身分證明並建立資料庫,配合3組3D層析圖譜可有效進行定性分析。
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