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研究生： 吳卉馨
Hui-Hsin Wu
論文名稱： 氣相層析-哨式偵測器/加速度規感測器對無機氣體的分析與研究
Rapid Screening and Detection of Inorganic Gasses by Gas Chromatography/Whistle-Accelerometer Method
指導教授： 林震煌
Lin, Cheng-Huang
學位類別： 碩士
Master
系所名稱： 化學系
Department of Chemistry
論文出版年： 2013
畢業學年度： 101
語文別： 中文
論文頁數： 85
中文關鍵詞： 沖天炮 、氣相層析 、哨式偵測器 、加速度規感測器
英文關鍵詞： firework-rockets, gas chromatography, whistle, accelerometer
論文種類： 學術論文
相關次數： 點閱：133  下載：12 
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    • 　　本研究發展在氣相層析法中使用加速度規感測器來偵測無機氣體。將一迷你發音哨連接於氣相層析管柱的後端，取代傳統的氣相層析儀偵測器。當載流氣體與待測物氣體通過迷你發音哨時，產生聲音，造成振動變化，可以使用加速度規感測器來記錄。點燃傳統中國的沖天炮內的推進劑與爆炸劑，將會釋放高含量的二氧化硫、氮氣和二氧化碳無機氣體，並可以利用氣相層析/哨式偵測器-加速度規感測器系統做快速偵測。這裡描述的方法是安全的，儀器裝置亦是嚴謹，具有潛力被改良成為可攜式裝置。由於火焰離子偵測器對二氧化硫、氮氣、二氧化氮和二氧化碳難偵測，以及熱導偵測器需要使用氦氣，而此系統可以分別與火焰離子偵測器或是熱導偵測器結合來使用。

    The use of an accelerometer for detecting inorganic gases in gas chromatography (GC) is described. A milli-whistle was connected to the outlet of the GC capillary and was used instead of a classical GC detector. When the GC carrier gases and the sample gases pass through the milli-whistle, a sound is produced, leading to vibrational changes, which can be recorded using an accelerometer. Inorganic gases, including SO2, N2 and CO2, which are released from traditional Chinese firework-rockets at relatively high levels as the result of burning the propellant and explosive material inside could be rapidly determined using the GC/whistle-accelerometer system. The method described herein is safe, the instrumentation is compact and has potential to be modified so as to be portable for use in the field. It also can be used in conjunction with FID (flame ionization detector) or TCD (thermal conductivity detector), in which either no response for FID (CO2, N2, NO2, SO2, etc.) or helium gas is needed for TCD, respectively.

    摘要 I Abstract II 目錄 III 圖目錄 VI 表目錄 VIII 第一章 緒論 1 1-1 研究目的 1 1-2 分析物介紹 2 1-2-1 安全火柴 2 1-2-2 傳統沖天炮 3 1-3 哨式偵測器 4 1-4 聲波感測器 5 1-4-1 表面聲波特性 6 1-4-2 表面聲波感測器原理 7 第二章 研究方法及原理 8 2-1 哨式偵測器 8 2-1-1 哨式偵測器原理 10 2-1-2 哨式偵測器製作 12 2-2 加速度規感測器 13 2-2-1 加速度規感測器原理 13 2-2-2 壓電式加速度規 20 2-2-3 壓電效應 24 2-2-4 FleXense訊號分析軟體 27 2-3 加速度規感測器的應用 28 2-4 元素分析 30 2-4-1 元素分析儀 30 2-4-2 能量散佈分析儀 31 2-5 拉曼光譜分析 32 2-5-1 拉曼散射 32 2-5-2 拉曼散射原理 33 第三章 儀器裝置及藥品 35 3-1 實驗儀器 35 3-1-1 氣相層析儀 35 3-1-2 哨式偵測器 40 3-1-3 加速度規感測器 43 3-2 儀器及周邊設備列表 45 3-3 藥品及樣品 47 第四章 研究結果與討論 48 4-1 無機氣體 48 4-1-1 火柴氣體收集 48 4-1-2 沖天炮氣體收集 49 4-1-3 氣體收集裝置 50 4-2 哨式偵測器 52 4-2-1 哨式偵測器的規格與適用範圍 52 4-2-2 麥克風位置最佳化 53 4-2-3 載流及鞘流氣體種類的影響 54 4-2-4 標準氣體檢量線 57 4-3 真實樣品的測量 59 4-3-1 爆炸速度與溫度的關係 59 4-3-2 哨式偵測器結合加速度規感測器 63 4-3-4 顯微拉曼光譜 70 4-3-5 元素分析 73 4-3-6 能量散佈分析 74 第五章 結論 77 論文發表 78 研究發表 79 參考文獻 80

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