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研究生: 張世安
Shih-An Chang
論文名稱: 台灣南部現生牡蠣殼體與水體之穩定同位素記錄及其應用
Stable isotope records of modern oyster shells and water from Southwest Taiwan and their implication
指導教授: 米泓生
Mii, Horng-Sheng
李匡悌
Li, Kuang-Ti
學位類別: 碩士
Master
系所名稱: 地球科學系
Department of Earth Sciences
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 105
中文關鍵詞: 長牡蠣穩定同位素大道公遺址水文環境
英文關鍵詞: Crassostrea gigas, stable isotope, Ta Tao Kung archaeological site, water environment
DOI URL: http://doi.org/10.6345/NTNU202001162
論文種類: 學術論文
相關次數: 點閱:188下載:25
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  • 本研究自2017年10月至2019年8月間,採集養殖於台南市七股地區現生牡蠣以及其所生長的水體標本,共採集101個殼體及208個水體標本,分析其穩定同位素成分,以了解現生牡蠣殼體同位素組成與其生活水文環境間之關係。
    本研究結果顯示養殖場水體氫同位數值主要介於-74.03‰ ~ 8.17‰間(平均值-2.59 ± 14.46‰,1σ;N=182;V-SMOW);氧同位數值主要介於-9.77‰ ~ 0.76‰之間(平均值-0.58 ± 1.90‰;V-SMOW),曾文溪近出海口水體氫同位數值主要介於-82.01‰ ~ -1.73‰間(平均值-19.27 ± 19.68‰,1σ;N=26;V-SMOW);氧同位數值主要介於-11.37‰ ~ -0.29‰之間(平均值-3.13 ± 2.90‰;V-SMOW)。養殖場與曾文溪近出海口水體氫、氧同位素有顯著的線性關係,與嘉南天水線之關係相似,可反映出淡水與海水混合環境的特性。養殖場水體氧同位素數值與雨量及鹽度數值亦呈現顯著負相關性,可反映出台灣西南部降水/蒸發之氣候特性。
    現生牡蠣殼體記錄的氧同位素數值介於-6.72‰~ 0.92‰之間(平均值為-3.38 ± 0.96‰,N=1091;V-PDB),碳同位素數值介於-4.67‰~0.92‰之間(平均值為 -1.67 ± 0.68‰;V-PDB)。而牡蠣殼體氧同位素數值與海溫及水體氧同位素記錄分別呈現負及正相關性的振盪變化。將海溫與水體氧同位素數據代入氧同位素溫度方程式計算出殼體氧同位素理論平衡值,牡蠣殼體氧同位素數值隨著生長週期的曲線變化與理論平衡值曲線大致符合。在牡犡殼體生長時間的不確定因素下,殼體氧同位素實際數值與理論數值約有67%相符,其他不一致的原因可能為雨季及冬季停止生長之生機效應所影響,因此在春、秋兩季溫度推算較為精確。
    本研究分析6個南科園區西拉雅文化之大道公遺址考古挖掘出土牡蠣,嘗試探討當時採集牡蠣的季節,及降雨強度與現今的差異。考古遺址牡蠣記錄的氧同位素數值介於-9.45‰~ -1.00‰之間(平均值-4.33 ± 1.50‰,N=86;1σ)。考古遺址殼體氧同位素記錄亦呈現如現生牡蠣殼體之季節性變化,春、夏、冬季皆有採收,考古遺址殼體與現今殼體比較,當時之夏季氧同位素較現今小1.08‰,冬季則小0.49‰。顯示600~500B.P.時期可能處於較現今溫暖及潮濕的氣候形態。

    To study the relationship between isotope compositions of modern oyster shells and those of water in which they lived, 101 modern oyster shells and 208 water samples were collected from Chi Ku area monthly from October, 2017 to August, 2019.
    The hydrogen isotope values of the aquafarm water samples are between -74.03‰ and 8.17‰ (-2.59 ± 14.46‰, 1σ; N = 182; V-SMOW), and the oxygen isotope values are between -9.77‰ and 0.76‰ (-0.58 ± 1.90‰; V-SMOW). The D and 18O values of Zengwen River are respectively between -82.01‰ and -1.73‰ (-19.27 ± 19.68‰, 1σ; N = 27) and between -11.37‰ and -0.29‰ (-3.13 ± 2.90‰). The significant linear relationship between oxygen and hydrogen isotopes values in these water samples shows the characteristics of mixing environment between freshwater and seawater. These water oxygen isotope values negatively and positively correlate with the amount of rainfall and the salinity observed, respectively. The relationfhip between D and 18O values observed is similar to that of the local meteoric water line of SW Taiwan published .
    The oxygen isotope values of living oyster shells range from -6.72‰ to 0.92‰(
    -3.38 ± 0.96‰, N = 1091; V-PDB) and the carbon isotope values range from -4.67‰ to 0.92‰ (-1.67 ± 0.68‰; V-PDB). Oxygen isotope fluctuation patterns of the oyster shells are similar to that of theoretical equilibrium pattern calculated using observed seawater temperature and water oxygen isotope values. With the uncertainty in the time correlation, the seasonal 18O values of shells are roughly 67% consistent with those of theoretical equilibrium values. Difference between the 18O values of oyster shells and those of equilibrium values might be caused by oyster stop growing during the time of higher precipitation events and lower winter temperature. Therefore, the temperature estimation is more accurate in the spring and autumn seasons.
    This study analyzes six archaeological oyster shells excavated from Ta Tao Kung archaeological site in the Southern Taiwan Science Park. The oxygen isotope values of these archaeological oysters are ranging from -9.45‰ to -1.00‰ (-4.33 ± 1.50‰, N = 86). Based on the 18O records, these shells were collected in spring, summer and winter. The average oxygen isotope values of the archaeological shells are 1.08‰ and 0.49‰ less than those of modern shells in summer and winter, respectively. Based on the 18O records, the overall climate in 600 to 500 B.P. may be warmer and wetter than present.

    中文摘要 i Abstract iii 致 謝 v 目 錄 vi 圖目錄 ix 表目錄 xiv 第一章、緒論 1 1.1前言 1 1.2穩定同位素的原理與古環境上的應用 2 1.2.1碳酸鹽類穩定碳、氧同位素 2 1.2.2水體穩定氫、氧同位素 3 1.3 前人研究 5 1.3.1 牡蠣相關研究與應用 5 1.3.2 南科考古遺址的研究 7 1.4 東亞地區500多年前至今氣候變化 10 1.5 研究目的 13 第二章、研究區域與材料 15 2.1研究地點 15 2.1.1 七股地區人文特色與自然環境演變 17 2.1.2 七股地區的牡蠣養殖情況 18 2.1.3 七股地區與將軍地區環境參數及海溫資料 20 2.2 長牡蠣(Crassostrea gigas)的生長史與生活習性 22 第三章、研究方法 25 3.1牡蠣殼體標本與水體標本之採樣 25 3.2牡蠣殼體標本實驗前處理 26 3.3 穩定同位素分析 26 3.3.1 牡蠣殼體標本 26 3.3.2 海水水體樣本 26 第四章、研究結果與討論 29 4.1牡蠣殼體標本構造與觀察 29 4.2牡蠣殼體取樣位置選擇 30 4.3水樣採集及分析結果 31 4.3.1水樣採集 31 4.3.2 七股區周遭水域資料 33 4.3.3 七股水樣分析 35 4.4牡蠣殼體碳、氧同位素分析 43 4.4.1 牡蠣殼體在不同養殖位置及深度的變化 46 4.4.2 單一牡蠣現生殼體探討季節性變化 50 4.4.3殼體最末端取樣點氧同位素數值變化 69 4.4.4大道公遺址出土牡蠣氧同位素探討 74 第五章、結論 77 參考文獻 78 附錄一、七股養殖場與曾文溪近出海口採樣記錄及氫、氧同位素分析 87 附錄二、七股現生牡蠣殼體碳、氧同位素數值(V-PDB) 91 附錄三、大道公遺址出土牡蠣殼體碳、氧同位素數值(V-PDB) 105

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