研究生: |
杜柏翰 Tu, Po-Han |
---|---|
論文名稱: |
微波輔助法製成石墨烯於可撓式複合材料及其可穿戴式傳感器之研究與應用 Microwave assisted fabrication of graphene in flexible composites and applications on wearable strain sensor |
指導教授: | 李亞儒 |
學位類別: |
碩士 Master |
系所名稱: |
光電工程研究所 Graduate Institute of Electro-Optical Engineering |
論文出版年: | 2018 |
畢業學年度: | 106 |
語文別: | 中文 |
論文頁數: | 38 |
中文關鍵詞: | 微波輔助 、石墨烯 、應變 、感測器 |
英文關鍵詞: | microwave assist, graphene, Strain, Sensor |
DOI URL: | http://doi.org/10.6345/THE.NTNU.EPST.011.2018.E08 |
論文種類: | 學術論文 |
相關次數: | 點閱:96 下載:0 |
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我們提出一個在未來很有前景的方法,利用低成本來大量製成石墨烯,在本論文中我們主要在探討以微波輔助法製成石墨烯於可饒性基板PDMS傳感器之研究,實驗共分三部分,第一部分,以不同參數的溶劑插層後使用微波輔助還原法來製備出石墨烯。第二部分,並以拉曼光譜(Raman)進行分析I2D/IG訊號比來判定石墨烯品質,經過一系列的測試我們發現在硫酸:硝酸鈉:去離子水比為35毫升:0.7毫克:5毫升有最佳的條件,I2D/IG訊號比為0.63。第三部分,藉由拉伸測試來量測應變傳感器進一步得到應變係數(gauge factor),此係數可代表傳感器的靈敏度且應變量(strain)可達到30%,另外我們做了彎曲感測,使石墨烯在未來有更多更廣的應用可能性。傳感器基板我們選擇了聚二甲基矽氧烷(Polydimethylsiloxane,PDMS),此材料具有疏水性、無毒、有彈性、透光性佳等,讓未來石墨烯應變傳感器的應用端可以往生醫,作為人體的感測器。
In this study, we use a low cost prodecure to make a large amount of graphene. we mainly discuss the microwave-assisted method for the production of graphene on a PDMS sensor. The experiment is divided into third parts. In the first part, the microwave-assisted reduction method was used to prepare graphene after solvent intercalation with different parameters. In the second part, the I2D/IG signal ratio was analyzed by Raman spectroscopy to determine the quality of graphene. After a series of tests, we found that the ratio of sulfuric acid : sodium nitrate : deionized water was 35 ml : 0.7 mg : 5 ml. In the third part, By straining test, we can get the gauge factor. The coefficient can represent the sensitivity of the sensor and the strain can reach 30%. In addition, we have performed bending sensing to make Graphene has more and more application in the future. We chose Polydimethylsiloxane (PDMS) as a sensor’s substract. This material is hydrophobic, non-toxic, elastic, and high transmission. The application of the sensor can be used in the human body.
參考文獻
[1] Y.J. Lai, W.R. Liu “A Facile Approach to Synthesize Graphene Nanosheets Via Microwave Exfoliation for Heat Dissipation Applications” (2017)
[2] S. Saqib Shams , Ruoyu Zang, Jin Zhu “Graphene synthesis: a Review” Materials Science-Poland, 33(3), 566-578.(2015)
[3] A.K. Geim et al., Nat. Mater., 6,183 (2007)
[4] H Hibino, S Tanabe, S Mizuno , H Kageshima“Growth and electronic transport properties of epitaxial graphene on SiC” J. Phys. D: Appl. Phys. 45 154008.(2012)
[5] Eizenberg M, Blakely J M. “Carbon monolayer phase condensation on Ni(111) ” [ J]. Surface Science, 82 (1 ): 228236. (1979)
[6] Min Yi and Zhigang Shen “A review on mechanical exfoliation for the scalable production of graphene” Cite this: J. Mater. Chem. A, 3, 11700 (2015)
[7] Joseph I. Goldstein,Dale E. Newbury,Joseph R. Michael,Nicholas W.M. Ritchie,John Henry J. Scott,David C. Joy“Scanning Electron Microscopy and X-ray Microanalysis” (2017)
[8] Pimenta M A, Dresselhaus G, Dresselhaus M S, et al. Studying disorder in graphitebased systems by Raman spectroscopy [ J]. Physical Chemistry Chemical Physics, ( 11 ): 12761291. (2007)
[9] Thomsen C, Reich S. Double resonant Raman scattering in graphite[J]. Physical Review Letters, 85 (24): 5214 5217. (2000)
[10] Morteza Amjadi “Ultra-stretchable and skin-mountable strain sensors using carbon nanotubes–Ecoflex nanocomposites” (2015)
[11] A. C. Ferrari, J. C. Meyer, Scardaci, Casiraghi. Lazzeri,. Mauri, Piscanec, Jiang,. S. Novoselov. Roth, and A. K. Geim “Raman Spectrum of Graphene and Graphene Layers” (2006)
[12] Wikipedia “Boltzmann distribution” (1902)
[13] Shugar, G. J.; Shugar, R. A.; Bauman, L.; Bauman, R. S. Chemical Technicians’ Ready Reference Handbook; 2nd ed. McGraw-Hill Book Co. (1981)
[14] 羅聖全 “科學基礎研究之重要利器-掃描式電子顯微鏡(SEM)” 工業技術研究院奈米科技網 (2004) http://materialsnet.com.tw
[15] Zhao Jing “Review of graphene-based strain sensors” Chinese Phys. B 22 057701 (2013)
[16] PubMed “Scalable and Direct Growth of Graphene Micro Ribbons on Dielectric Substrates” (2013)
[17] Song Chen, Yong Wei, Xue Yuan, Yong Lin and Lan Liu “A highly stretchable strain sensor based on a graphene/silver nanoparticle synergic conductive network and a sandwich structure” (2016)
[18] Chaoyi Yan , Jiangxin Wang , Wenbin Kang , Mengqi Cui , Xu Wang , Ce Yao Foo , Kenji Jianzhi Chee , and Pooi See Lee “Highly Stretchable Piezoresistive Graphene–Nanocellulose Nanopaper for Strain Sensors” (2014)
[19] Morteza Amjadi “Ultra-stretchable and skin-mountable strain sensors using carbon nanotubes–Ecoflex nanocomposites” (2015)