簡易檢索 / 詳目顯示

研究生: 張滙婷
Chang, Hui-Ting
論文名稱: 以拉曼光譜技術鑑定東方繪畫顏料的實際與應用
Identification and Application of Oriental Painting Pigments by Raman Spectroscopy
指導教授: 林震煌
Lin, Cheng-Huang
口試委員: 林震煌
Lin, Cheng-Huang
呂家榮
Lu, Chia-Jung
丁望賢
Ding, Wang-Hsien
口試日期: 2021/06/11
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2021
畢業學年度: 109
語文別: 中文
論文頁數: 88
中文關鍵詞: 顏料拉曼光譜表面增強拉曼散射LabVIEW
英文關鍵詞: pigments, Raman spectroscopy, surface enhanced Raman scattering, LabVIEW
DOI URL: http://doi.org/10.6345/NTNU202100510
論文種類: 學術論文
相關次數: 點閱:145下載:0
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報
  • 本研究以拉曼散射光譜儀分析顏料的拉曼指紋圖譜,做為標準參考物質顏料,建立鑑定維護或修復畫作時所需的標準拉曼光譜圖。再使用本實驗室開發的LabVIEW程式擷取背景螢光的功能,擷取螢光背景光譜圖分析,另一方面也使用表面增強拉曼散射技術,藉著增強拉曼訊號並降低螢光背景的方法,解決螢光干擾的問題。
    利用上述方法技術,以螢光光譜區分方解末及胡粉兩種碳酸鈣顏料和辰砂及鉛丹兩種無機顏料;而LabVIEW程式無法解決的背景螢光問題,以表面增強拉曼散射技術,增強拉曼訊號並解決螢光干擾的問題,藉著添加奈米銀及使用拉曼光譜儀分析,解決紅色有機顏料強烈的背景螢光問題。
    本研究分析顏料標準品的拉曼光譜圖,實際將表面增強拉曼散射技術應用於東方畫作未知樣品上,成功降低拉曼光譜中的螢光干擾,並與顏料之標準拉曼光譜比較,分析出未知樣品1中之成分顏料為鉛丹,未知樣品2中之成分顏料為鉛丹和鉛白,透過分析未知樣品的例子,證明本研究方法能成功應用於東方畫作顏料的鑑定上。

    In this work, various color of pigments were selected, including inorganic and organic pigments, as standard reference material. These pigments were analyzed by Raman scattering spectrometer to establish the reference spectra for identification and restoration of paintings.
    Using the LabVIEW program to retrieve the Raman and fluorescence spectrum separately. On the other hand, utilizing the surface enhanced Raman scattering (SERS) to enhance the Raman signal and reduce the fluorescence background to solve the problem on fluorescent interference.
    By the LabVIEW program, distinguishing two of the calcium carbonate pigments and two of the red inorganic pigments. When fluorescence background couldn’t be solved with the LabVIEW program, the SERS was used for the identification of red organic pigments.
    Analyzing the fingerprint spectrum of the Raman spectroscopy to apply on the unknown samples of oriental paintings which used SERS to reduce the fluorescence interference. The results of unknown 1 and 2 have successfully confirmed. The composition of unknown 1 is red lead, and unknown 2 is red lead and white lead. Successfully proved that this work has been applied for the identification of oriental painting pigments.

    第一章 緒論 1 1-1 研究目的 1 1-2 分析物簡介 3 1-2-1 繪畫顏料介紹 3 1-2-2 東方繪畫之真實樣品介紹 11 第二章 分析原理及方法 13 2-1 LabVIEW程式減去背景螢光的原理及方法 13 2-2 XY-Graph減去背景螢光的原理及方法 16 2-3 表面增強拉曼散射(SERS)降低背景螢光的原理及方法 17 第三章 實驗介紹 18 3-1 實驗儀器設備 18 3-1-1 桌上型共軛焦拉曼顯微鏡光譜儀 19 3-2 試藥介紹 20 3-3 紅花素之萃取方法 21 3-4 茜根中茜素之萃取方法 21 3-5 奈米銀製備方法 23 第四章 結果與討論 24 4-1 無機顏料 24 4-1-1 白色無機顏料 27 4-1-2 黑色無機顏料 31 4-1-3 紅色無機顏料 33 4-1-4 褐色無機顏料 38 4-1-5 藍色與綠色無機顏料 39 4-1-6 黃色無機顏料 43 4-2 有機顏料 45 4-2-1 紅色有機顏料-茜素 47 4-2-2 紅色有機顏料-紅花素 49 4-2-3 紅色有機顏料-茜根中的茜素 51 4-2-4 藍色有機顏料 53 4-3 畫作分析 55 4-3-1 台師大文物保存維護研究發展中心提供之未知分析樣品1 55 4-3-2 台師大文物保存維護研究發展中心提供之未知分析樣品2 61 第五章 結論 69 參考文獻 70 附錄 76

    1. C. Anselmi, M. Vagnini, L. Cartechini, C. Grazia, R. Vivani, A. Romani, F. Rosi, A. Sgamellotti, C. Miliani, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 173 (2017) 439-444.
    2. H. Airi, A. Yoshinari, V.L. Annelies, D.K. Nouchka, N. Petria, V. Frederik, J. Koen, T. Kriengkamol, T. Kazuo, N. Izumi, Microchem J. 138 (2018) 266-272.
    3. P.O. Autran, C. Dejoie, P. Bordet, J.L. Hodeau, C. Dugand, M. Gervason, M. Anne, P. Martinetto, Anal. Chem. 93 (2021) 1135-1142.
    4. C. Vlachou-Mogire, P. Moretti, L. Monico, A. Chieli, M. Iwanicka, P. Targowski, V. Detalle, E. Bourguignon, K. Laclavetine, F. Mirambet, T. Tong, S. Pinchin, Microchem J. 156 (2020) 104797.
    5. A. Abdrabou, M. Abdallah, H.M. Kamal, Conservar Património 26 (2017) 51-63.
    6. T. Arlt, H. E. Mahnke, T. Siopi, E. Menei, C. Aibéo, R. R. Pausewein, I. Reiche, I. Manke, V. Lepper, J. Cult. Herit. 39 (2019) 13-20.
    7. F. Gabrieli, K.A. Dooley, M. Facini, J.K. Delaney, Sci. Adv. 5 (2019) eaaw7794.
    8. E. Pięta, J. Olszewska-Świetlik, C. Paluszkiewicz, A. Zając, W.M. Kwiatek, Vib. Spectrosc. 103 (2019)
    9. C. Pelosi, G. Capobianco, G. Agresti, G. Bonifazi, F. Morresi, S. Rossi, U. Santamaria, S. Serranti, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 198 (2018) 92-106.
    10. C. Biron, G. Le Bourdon, J. Perez-Arantegui, L. Servant, R. Chapoulie, F. Daniel, Anal. Bioanal. Chem. 410 (2018) 7043-7054.
    11. A. Daveri, M. Malagodi, M. Vagnini, J. Anal. Methods Chem. 2018 (2018) 6595643.
    12. L. Rampazzi, V. Brunello, F. P. Campione, C. Corti, L. Geminiani, S. Recchia, M. Luraschi, Microchem J. 157 (2020) 105017.
    13. L. Nodari and P. Ricciardi, Herit. Sci. 7 (2019)
    14. S.P. Best, R.J.H. Clark, R. Withnall, Endeavour 16 (1992) 66-73.
    15. A. Derbyshire and R. Withnall, J. Raman Spectrosc. 30 (1999) 185-188.
    16. F. Rosi, M. Paolantoni, C. Clementi, B. Doherty, C. Miliani, B.G. Brunetti, A. Sgamellotti, J. Raman Spectrosc. 41 (2009) 452-458.
    17. G. Marucci, A. Beeby, A.W. Parker, C.E. Nicholson, Anal. Methods 10 (2018) 1219-1236.
    18. T. Christiansen, D. Buti, K. N. Dalby, P. E. Lindelof, K. Ryholt, A. Vila, J. Archaeol. Sci. Rep. 14 (2017) 208-219.
    19. A. Botteon, C. Colombo, M. Realini, C. Castiglioni, A. Piccirillo, P. Matousek, C. Conti, J. Raman Spectrosc. 51 (2020) 2016-2021.
    20. N. Grechukha, K. Gorshkova, M. Panov, I. Tumkin, E. Kirillova, V. Lukianov, N. Kirillova, V. Kochemirovsky, Appl. Sci. 7 (2017) 991.
    21. X. Jiang, Y. Ma, Y. Chen, Y. Li, Q. Ma, Z. Zhang, C. Wang, Y. Yang, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 190 (2018) 61-67.
    22. O. Petrova, D. Pankin, A. Povolotckaia, E. Borisov, T. Krivul’ko, N. Kurganov, A. Kurochkin, J. Cult. Herit. 37 (2019) 233-237.
    23. P. Colomban, Y. Zhang, B. Zhao, Ceram. Int. 43 (2017) 12079-12088.
    24. S. Steger, H. Stege, S. Bretz, O. Hahn, J. Cult. Herit. 38 (2019) 20-28.
    25. C. Miliani, F. Rosi, B. G. Brunetti, A. Sgamellotti, Accounts Chem. Res. 43 (2010) 728-738.
    26. D. Mancini, A. Percot, L. Bellot-Gurlet, P. Colomban, P. Carnazza, Talanta 227 (2021) 122159.
    27. M. Leona, F. Casadio, M. Bacci, M. Picollo, J. Am. Inst. Conserv. 43 (2004) 39-54.
    28. M. Fleischmann, P.J. Hendra, A.J. McQuillan, Chem. Phys. Lett. 26 (1974) 163-166.
    29. E. Garcia-Rico, R.A. Alvarez-Puebla, L. Guerrini, Chem. Soc. Rev. 47 (2018) 4909-4923.
    30. W. Nam, X. Ren, S.A.S. Tali, P. Ghassemi, I. Kim, M. Agah, W. Zhou, Nano Lett. 19 (2019) 7273-7281.
    31. V. Moisoiu, A. Socaciu, A. Stefancu, S.D. Iancu, I. Boros, C.D. Alecsa, C. Rachieriu, A.R. Chiorean, D. Eniu, N. Leopold, C. Socaciu, D.T. Eniu, Appl. Sci. 9 (2019) 806.
    32. R. Pilot, J. Raman Spectrosc. 49 (2018) 954-981.
    33. J. Soto, E. Imbarack, I. López-Tocón, S. Sánchez-Cortés, J. C. Otero, P. Leyton, RSC Adv. 9 (2019) 14511-14519.
    34. Y. Jiang, J. Wang, L. Malfatti, D. Carboni, N. Senes, P. Innocenzi, Appl. Surf. Sci. 450 (2018) 451-460.
    35. A.M.C.A.N. 80, Anal. Methods 9 (2017) 4338-4340.
    36. \ V.M. Nardo, F. Aliotta, M.A. Mastelloni, R.C. Ponterio, F. Saija, S. Trusso, C.S. Vasi, Atti. Accad. Naz. Lin. 95 (2017) A5.
    37. F. Pozzi, J.R. Lombardi, M. Leona, Herit. Sci. 1 (2013) 23.
    38. E.V. Shabunya-Klyachkovskaya, O.S. Kulakovich, S.V. Gaponenko, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 222 (2019) 117235.
    39. A. Cesaratto, Y.B. Luo, H.D. Smith, M. Leona, Herit. Sci. 6 (2018)
    40. F. Pozzi, K.J. van den Berg, I. Fiedler, F. Casadio, J. Raman Spectrosc. 45 (2014) 1119-1126.
    41. E. Casanova‐González, A. García‐Bucio, J.L. Ruvalcaba‐Sil, V. Santos‐Vasquez, B. Esquivel, T. Falcón, E. Arroyo, S. Zetina, M.L. Roldán, C. Domingo, J. Raman Spectrosc. 43 (2012) 1551-1559.
    42. C. Sessa, R. Weiss, R. Niessner, N.P. Ivleva, H. Stege, Microchem J. 138 (2018) 209-225.
    43. S. Bruni, V. Guglielmi, F. Pozzi, J. Raman Spectrosc. 41 (2010) 175-180.
    44. M.L. de Souza and P. Corio, Vib. Spectrosc. 54 (2010) 137-141.
    45. W.C. Lin, S.H. Huang, C.L. Chen, C.C. Chen, D.P. Tsai, H.P.Chiang, Appl. Phys. A-Mater. Sci. Process. 101 (2010) 185-189.
    46. M.H. Cho, Y.S. Paik, T.R. Hahn, J. Agric. Food Chem. 48 (2000) 3917-3921.
    47. L. Burgio, R.J.H. Clark, R.R. Hark, Proc. Natl. Acad. Sci. U.S.A. 107 (2010) 5726-5731.
    48. J.G. Shapter, M.H. Brooker, W.M. Skinner, Int. J. Miner. Process. 60 (2000) 199-211.
    49. M. Jeršek and S. Kramar, J. Raman Spectrosc. 45 (2014) 1000-1005.
    50. F. Casadio, A. Bezúr, I. Fiedler, K. Muir, T. Tradc, S. Maccagnola, J. Raman Spectrosc. 43 (2012) 1761-1771.
    51. W.J.B. Dufresne, C.J. Rufledt, C.P. Marshall, J. Raman Spectrosc. 49 (2018) 1999-2007.
    52. P. Vandenabeele, P.D. Paepe, L. Moens, J. Raman Spectrosc. 39 (2008) 1099-1103.
    53. N. Prieto-Taboada, O. Gomez-Laserna, I. Martinez-Arkarazo, M.A. Olazabal, J.M. Madariaga, Anal. Chem. 86 (2014) 10131-7.
    54. T. Schmid, R. Jungnickel, P. Dariz, Minerals 10 (2020)
    55. S.V. Gotoshia and L.V. Gotoshia, J. Phys. D-Appl. Phys. 41 (2008)
    56. L. Burgio, R.J.H. Clark, S. Firth, Analyst 126 (2001) 222-227.
    57. F.J. Owens and J. Orosz, Solid State Commun. 138 (2006) 95-98.
    58. D.L.A. de Faria and F.N. Lopes, Vib. Spectrosc. 45 (2007) 117-121.
    59. Y. Wang, Spectroc. Acta Pt. A-Molec. Biomolec. Spectr. 247 (2021) 119117.
    60. G.D. Ventura, F. Capitelli, M. Sbroscia, A. Sodo, J. Raman Spectrosc. 51 (2019) 1513-1521.
    61. R.L. Frost, W.N. Martens, L. Rintoul, E. Mahmutagic, J.T. Kloprogge, J. Raman Spectrosc. 33 (2002) 252-259.
    62. M. Vermeulen, S. Saverwyns, A. Coudray, K. Janssens, J. Sanyova, Dyes Pigment. 149 (2018) 290-297.
    63. C. Defeyt, P. Vandenabeele, B. Gilbert, J.V. Pevenage, R. Clootse, D. Strivay, J. Raman Spectrosc. 43 (2012) 1772-1780.
    64. S. Lin, (2015) Investigation into the Use of Surface-Enhanced Raman Spectroscopy (SERS) for Organic Dye Analysis. (Bachelor's degree, Massachusetts Institute of Technology) Retrieved from: http://hdl.handle.net/1721.1/98657.
    65. Y. Zhang, C. Zhao, G. Tian, C. Lu, Y. Li, L. He, H. Xiao, J. Zheng, Food Chem. 240 (2018) 743-750.
    66. T. Bayerová, Stud. Conserv. 63 (2017) 171-188.
    67. K. Retko, P. Ropret, R.C. Korošec, J. Raman Spectrosc. 45 (2014) 1140-1146.
    68. M.V. Cañamares, J.V. Garcia-Ramos, C. Domingo, S. Sanchez-Cortes, J. Raman Spectrosc. 35 (2004) 921-927.
    69. S. Bruni, V. Guglielmi, F. Pozzi, J. Raman Spectrosc. 42 (2011) 1267-1281.
    70. M.V. Cañamares, M.G. Mieites‐Alonso, M. Leona, J. Raman Spectrosc. 51 (2020) 903-909.
    71. A. Amat, F. Rosi, C. Miliani, A. Sgamellotti, S. Fantacci, J. Mol. Struct. 993 (2011) 43-51.
    72. A. Baran, A. Fiedler, H. Schulz, M. Baranska, Anal. Methods 2 (2010) 1372-1376.
    73. A.M. Hofmeister, T.C. Hoering, D. Virgo, Phys. Chem. Miner. 14 (1987) 205-224.

    無法下載圖示 本全文未授權公開
    QR CODE