研究生: |
郭昭克 Kuo,Chao-Ke |
---|---|
論文名稱: |
矽量子點太陽能電池 Silicon Quantum Dots Solar Cell |
指導教授: |
胡淑芬
Hu, Shu-Fen |
學位類別: |
碩士 Master |
系所名稱: |
物理學系 Department of Physics |
論文出版年: | 2010 |
畢業學年度: | 98 |
語文別: | 中文 |
論文頁數: | 102 |
中文關鍵詞: | 太陽能 、矽量子點 、低壓化學氣相沉積 |
英文關鍵詞: | solar cell, silicon quantum dot, lpcvd |
論文種類: | 學術論文 |
相關次數: | 點閱:149 下載:0 |
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本實驗利用低壓化學氣相沉積系統LPCVD (low pressure chemical vapor deposition)長成矽量子點,藉由調控NH3和Si2H2Cl2氣體流量與沉積時間,將量子點嵌入於氮化矽中(Si3N4)形成三明治結構。並探討是否需經由再退火(post-anneal)而形成量子點。此外,也藉由控制薄膜之厚度調變量子點大小,以及調變薄膜層積數量以達到所需之量子點層數,其大小及層數皆會應用在分析與太陽能元件上。之後利用原子力顯微鏡AFM(atomic force microscopy)掃描樣本表面,比較有無量子點之表面粗糙度差別。利用高解析穿透式電子顯微鏡HRTEM(high resolution transmission electron microscopy)觀測是否有量子點結晶現象,同時估算出量子點大小及其分佈密度。利用GIXRD (grazing incidence X-Ray diffraction)分析薄膜中是否有結晶現象,並利用Scherrer formula計算出量子點平均晶徑變化。最後利用光激螢光(photoluminescence)觀測量子點發放螢光現象,並進而推算出量子點大小及能階分裂狀態。
最後將矽量子點應用至太陽能電池中,並量測其效率(efficiency)與外部量子效應EQE(external quantum efficiency),並討論為何量子點太陽能電池效率未能提升。(量子點太陽能電池效率0.7%,無量子點則為6.9%)。
[1] http://emis.erl.itri.org.tw/,能源資訊網。
[2] http://www.nrel.gov/
[3] W. Shockley and H.J. Queisser J. Appl. Phys. 32 (1961), p. 510
[4] http://www.physorg.com/news104511242.html
[5] A. J. Nozik, Physica E-Low-Dimensional Systems & Nanostructures 14 (1-2),115-120 (2002).
[6] http://sotrc.cets.ncku.edu.tw/solar/,國立成功大學太陽光電科技研究中心。
[7] T. Markvart, “Solar Electricity,” John Wiley & Sons, New York,(1994)
[8] S.O. Kasap, International edition, Prentice-Hall, Inc.
[9] 雷永泉、萬群與石永康,“新能源材料”,新文京出版社。
[10] 林明獻,“太陽電池技術入門”,第二版,全華出版社。
[11] http://boya.xmu.edu.cn/photonics/chapt3/quantumpoint.htm
[12] http://www.wretch.cc/blog/KSChou/378198
[13] Y. K. Huang, C. P. Liu, Y. L. Lai, C. Y. Wang, Y. F. Lai and H. C.Chung, Applied Physics Letters 91 (9) (2007).
[14] M. Shalchian, J. Grisolia, G. Ben Assayag, H. Coffin, S. M. Atarodi and A. Claverie, Solid-State Electronics 49 (7), 1198-1205 (2005).
[15] J. P. Zhao, Y. Meng, D. X. Huang, W. K. Chu and J. W. Rabalais, Journal of Vacuum Science & Technology B 25 (3), 796-800 (2007).
[16] E. C. Cho, S. Park, X. J. Hao, D. Y. Song, G. Conibeer, S. C. Park and M. A. Green, Nanotechnology 19 (24) (2008).
[17] X. J. Hao, E. C. Cho, C. Flynn, Y. S. Shen, G. Conibeer and M. A.Green, Nanotechnology 19 (42) (2008).
[18] X. J. Hao, E. C. Cho, C. Flynn, Y. S. Shen, S. C. Park, G. Conibeer and M. A. Green, Solar Energy Materials and Solar Cells 93 (2), 273-279 (2009).
[19] G. Conibeer, M. Green, R. Corkish, Y. Cho, E. C. Cho, C. W. Jiang,
T. Fangsuwannarak, E. Pink, Y. D. Huang, T. Puzzer, T. Trupke, B. Richards, A. Shalav and K. L. Lin, Thin Solid Films 511, 654-662 (2006).
[20.] D. Das, D. Raha and K. Bhattacharya, Journal of Nanoscience and Nanotechnology 9 (9), 5614-5621 (2009).
[21] K. Ichikawa, P. Punchaipetch, H. Yano, T. Hatayama, Y. Uraoka, T.Fuyuki, E. Takahashi, T. Hayashi and K. Ogata, Japanese Journal of Applied Physics Part 2-Letters & Express Letters 44 (24-27), L836-L838 (2005).
[22] K. Ichikawa, P. Punchaipetch, H. Yano, T. Hatayama, Y. Uraoka, T.Fuyuki, A. Tomyo, E. Takahashi, T. Hayashi and K. Ogata, Journal of the Korean Physical Society 49 (2), 569-576 (2006).
[23] G. R. Lin, Y. H. Pai and C. T. Lin, Journal of Lightwave Technology 26 (9-12), 1486-1491 (2008).
[24] L. C. Wu, M. Dal, X. F. Huang, Y. J. Zhang, W. Ll, J. Xu and K. J. Chen, Journal of Non-Crystalline Solids 338, 318-321 (2004).
[25] B. H. Lai, C. H. Cheng, Y. H. Pai and G. R. Lin, Optics Express 18 (5), 4449-4456 (2010).
[26] T. Baron, F. Martin, P. Mur, C. Wyon and M. Dupuy, Journal of Crystal Growth 209 (4), 1004-1008 (2000).
[27] T. Baron, F. Martin, P. Mur, C. Wyon, M. Dupuy, C. Busseret, A.Souifi and G. Guillot, Applied Surface Science 164, 29-34 (2000).
[28] A. Beaumont and A. Souifi, Solid-State Electronics 53 (1), 42-48 (2009).
[29] I. Crupi, D. Corso, S. Lombardo, C. Gerardi, G. Ammendola, G. Nicotra, C. Spinella, E. Rimini and M. Melanotte, Materials Science & Engineering C-Biomimetic and Supramolecular Systems 23 (1-2), 33-36 (2003).
[30] K. Makihara, J. Xu, M. Ikeda, H. Murakami, S. Higashi and S. Miyazaki, Thin Solid Films 508 (1-2), 186-189 (2006).
[31] F. Mazen, T. Baron, G. Bremond, N. Buffet, N. Rochat, P. Mur and M. N. Semeria, Journal of the Electrochemical Society 150 (3), G203-G208 (2003).
[32] S. Miyazaki, Y. Hamamoto, E. Yoshida, M. Ikeda and M. Hirose, Thin Solid Films 369 (1-2), 55-59 (2000).
[33] A. Nakajima, Y. Sugita, K. Kawamura, H. Tomita and N. Yokoyama,Japanese Journal of Applied Physics Part 2-Letters 35 (2B), L189-L191 (1996).
[34] Y. C. Peng, M. Ikeda and S. Miyazaki, Acta Physica Sinica 52 (12), 3108-3113 (2003).
[35] http://www.ndl.org.tw,國研院奈米元件實驗室。
[36] http://www.materialsnet.com.tw,材料世界網。
[37] 楊茹媛、陳皇宇、翁敏航與戴寶通,” CdS量子點敏化太陽能電池”,奈米通訊,第十五卷。
[38] O. L. Lazarenkova and A. A. Balandin, Journal of Applied Physics 89 (10), 5509-5515 (2001).
[39] 張世育,”矽量子點鑲嵌在氮化矽薄膜之合成與光學性質研究”,中華大學電機工程研究所碩士學位論文,2006。
[40] L. T. Canham, Applied Physics Letters 57 1046 (1990).
[41] N. M. Park, T. S. Kim, and S. J. Park, Applied Physics Letters 782575 (2001)
[42] N. M. Park, C. J. Choi, T. Y. Seong, and S. J. Park, Applied Physics Letters 86 1335 (2001)
[43] Y. Q. Wang, Y. G. Wang, L. Cao, and Z. X. Cao, Applied Physics Letters 83 3474 (2003)
[44] Y. Q. Wang, W. D. Chen, X. B. Liao, and Z. X. Cao, Nanotechnology 14, 1235 (2003)
[45] C. Liu, C. Li, A. Ji, L. Ma, Y. Wang, and Z. Cao, Nanotechnology 16, 940 (2005)
[46] C. Liu, C. Li, A. Ji, L. Ma, Y. Wang, and Z. Cao, Applied Physics Letters 86 223111 (2005)
[47] L. B. Ma, R. Song, Y. M. Miao, C. R. Li, Y. Q. Wang, and Z. X. Cao, Applied Physics Letters 88 093102 (2006)
[48] 莊達人,”VLSI製造技術第四版”,高立圖書,2000。
[49] L. EcKertova, and T. Ruzicka, “Diagnostics and Application of Thin Films” Ch.1 & 2, Institute of Physics Publishing (1993)
[50] Y. S. Jung and S. S. Lee, J. Crystal Growth, 259, 343-351 (2003)
[51] 羅聖全,”電子顯微鏡介紹-TEM”。
[52] C. Kittel, “Introduction to Solid State Physics”, Eight edition, John Wily & Sons, Inc.
[53] 謝嘉民、賴一凡、林永昌與枋志堯,”光激發螢光量測的原理、架構及應用”,奈米通訊,第十二卷。
[54] Joseph H. Simmons and Kelly S. Potter: Optical Materials. San Diego: Academic Press, 2000.
[55] A. H. Kitai: Solid State Luminescence. New York: Chapman & Hall, 1993.
[56] Klaus D. Mielenz: Optical Radiation Measurements. New York: Academic Press, 1982.
[57] 陳建志,”矽奈米晶體的光學特性研究”,中原大學應用物理研究所碩士學位論文,2006。
[58] M. C. Liu, T. Y. Chiang, P. Y. Kuo, M. H. Chou, Y. H. Wu, H. C. You, C. H. Cheng, S. H. Liu, W. L. Yang, T. F. Lei and T. S. Chao, Semiconductor Science and Technology 23 (7) (2008).
[59] P. Basa, Z. J. Horvath, T. Jaszi, A. E. Pap, L. Dobos, B. Pecz, L. Toth and P. Szollosi, Physica E-Low-Dimensional Systems & Nanostructures 38 (1-2), 71-75 (2007).
[60] T. Baron, F. Martin, P. Mur, C. Wyon, M. Dupuy, C. Busseret, A. Souifi and G. Guillot, Applied Surface Science 164, 29-34 (2000).
[61] R. Moriya, H. Kobayashi, K. Shibata, S. Masubuchi, K. Hirakawa, S. Ishida, Y. Arakawa and T. Machida, Applied Physics Express 3 (3) (2010).
[62] M. A. Salem, H. Mizuta, S. Oda, Y. Fu and M. Willander, Japanese Journal of Applied Physics Part 2-Letters & Express Letters 44 (1-7), L88-L91 (2005).
[63] H. Y. Xie, China Particuology 5 (3), 242-246 (2007).
[64] I. V. Antonova, M. Gulyaev, E. Savir, J. Jedrzejewski and I. Balberg, Physical Review B 77 (12) (2008).
[65] R. Huang, L. B. Ma, Y. Du, L. Gao, C. R. Li, C. L. Yu, J. P. Ye and Z. X. Cao, Nanotechnology 19 (25) (2008).
[66] A. Karim, G. V. Hansson, W. X. Ni, P. O. Holtz, M. Larsson and H. A. Atwater, Optical Materials 27 (5), 836-840 (2005).
[67] K. Kohno, Y. Osaka, F. Toyomura and H. Katayama, Japanese Journal of Applied Physics Part 1-Regular Papers Short Notes & Review Papers 33 (12A), 6616-6622 (1994).
[68] E. C. Cho, S. Park, X. J. Hao, D. Y. Song, G. Conibeer, S. C. Park and M. A. Green, Nanotechnology 19 (24) (2008).
[69] C. W. Jiang and M. A. Green, Journal of Applied Physics 99 (11) (2006).