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研究生: 黃昱翔
Huang, Yu-Hsiang
論文名稱: 1T-MoS2催化劑結合矽光電陰極應用於氮氣還原反應
1T-MoS2 Catalyst for Nitrogen Reduction to Ammonia via Si-Heterojunction Photocathode
指導教授: 陳家俊
Chen, Chia-Chun
陳俊維
Chen, Chun-Wei
口試委員: 陳俊維
Chen, Chun-Wei
郭聰榮
Kuo, Tsung-Rong
王迪彥
Wang, Di-Yan
陳家俊
Chen, Chia-Chun
口試日期: 2022/06/28
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 57
中文關鍵詞: 產氨二維材料二硫化鉬光電化學
英文關鍵詞: Ammonia production, Two-dimensional materials (2D materials), Molybdenum disulfide (MoS2), Photoelectrochemical (PEC)
研究方法: 實驗設計法次級資料分析調查研究主題分析比較研究
DOI URL: http://doi.org/10.6345/NTNU202200821
論文種類: 學術論文
相關次數: 點閱:153下載:0
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  • 摘要 ii ABSTRACT iii 目錄 v 圖目錄 viii 表目錄 xii 第1章 緒論 1 1.1 前言 1 1.2 氮還原 1 1.2.1 哈伯法 1 1.2.2 電化學氮氣還原反應 2 1.3 氮還原觸媒 4 1.3.1 貴金屬 4 1.3.2 仿生觸媒 4 1.3.3 二維材料 5 1.4 光電化學 8 1.5 研究動機 9 第2章 文獻回顧與動機 10 2.1 電化學氮氣還原反應之過程 10 2.1.1 吸附機制 10 2.1.2 薩巴捷原則 11 2.2 電化學反應觸媒的抉擇 12 2.2.1 貴金屬 12 2.2.2 仿生觸媒 14 2.2.3 二維材料 ─ 二硫化鉬 15 2.3 光電化學反應 19 2.3.1 反應機制 19 2.3.2 反應元件的設計 21 第3章 實驗儀器設備 26 3.1 光電化學之實驗量測 26 3.1.1 太陽光模擬器 26 3.1.2 三極式光電化學反應系統 27 3.2 實驗材料與產物分析 30 3.2.1 掃描式電子顯微鏡 30 3.2.2 能量散射光譜儀 31 3.2.3 X射線繞射儀 32 3.2.4 拉曼光譜 33 3.2.5 紫外光/可見光吸收光譜儀 34 第4章 實驗藥品與步驟 36 4.1 實驗藥品 36 4.2 PEC基板的製作 37 4.3 1T-MoS2的合成 37 4.4 1T-MoS2電極的製作 38 4.5 產物NH3的檢測與分析 39 第5章 結果與討論 41 5.1 1T-MoS2的基本性質鑑定 41 5.2 PEC元件上1T-MoS2的形貌 43 5.3 1T-MoS2的電化學氮氣還原反應 45 5.4 1T-MoS2的光電化學氮氣還原反應 48 5.5 1T-MoS2的電化學與光電化學氮還原之比較 51 第6章 結論 53 參考文獻 54

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