研究生: |
高義倫 Kao,Yi-Lun |
---|---|
論文名稱: |
三原色鈣鈦礦量子點於垂直共振腔面射型雷射之光學特性研究 Study of Perovskite–based RGB Quantum Dots Vertical Cavity Emitting Lasers |
指導教授: |
李亞儒
Lee, Ya-Ju |
學位類別: |
碩士 Master |
系所名稱: |
光電工程研究所 Graduate Institute of Electro-Optical Engineering |
論文出版年: | 2018 |
畢業學年度: | 106 |
語文別: | 中文 |
論文頁數: | 44 |
中文關鍵詞: | 高溫注入合成法 、鈣鈦礦量子點 、帶通濾波片 、垂直面形雷射結構 |
英文關鍵詞: | hot injection, perovskite quantum dot, Bragg mirror, Vertical-Cavity Surface-Emitting Laser |
DOI URL: | http://doi.org/10.6345/THE.NTNU.EPST.012.2018.E08 |
論文種類: | 學術論文 |
相關次數: | 點閱:148 下載:0 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本論使用高溫注入法合成鈣鈦礦量子點(perovskite quantum),再與帶通濾波片作為垂直面形共振腔,做為結合。在這當中鈣鈦礦量子點作為發光增益介質,透過355 nm 脈衝雷射激發雷射。實驗分為三大類,實驗一:調控鈣鈦礦的反應物比例做出藍、綠、紅溶液,各別做材料分析以及光學分析,實驗二:將鈣鈦礦量子點旋塗至布拉格反射鏡上,再將另一片帶通濾波片蓋上,形成垂直腔面發雷射(Vertical-Cavity Surface-Emitting Laser)以355 nm 脈衝雷射激發雷射,實驗三:將藍、綠、紅色鈣太礦塗至於帶通濾波片試做出白光雷射
In this work, we uses hot injection to synthesize perovskite quantum dots, and then combines with high-reflection Bragg mirrors as vertical-surface resonant cavities. In this case, the perovskite quantum dot acting with gain medium and excites the laser through a 355 nm pulsed laser. The experiment is divided into three categories. Experiment 1: The proportion of reactants for controlling perovskite is made into blue, green and red solutions, and each material is analyzed and optically analyzed. Experiment 2: Spin perovskite quantum dots on Bragg mirrors. On the other hand, another Bragg mirror is covered to form a Vertical-Cavity Surface-Emitting Laser to excite the laser with a 355 nm pulsed laser. Experiment 3: By using blue, green and red perovskite quantum dot and the high-reflection Bragg mirror ,and try to make a white light laser
參考文獻
[1] VCSEL光纖網路之明日之星.
[2] VCSEL百科內文.
[3] 全球VCSEL產業發展現況.
[4] Shu-Wei Chang, “A White Random Laser, ” Scientific Reports DOI:10.1038/s41598-018-21228
[5] 楊寶賡, “雷射工程, ” 新文京開發, 第32-40頁
[6] http://www.lasertech.tw/index.php
[7] S. Gottardo, R. Sapienza, P. D. Garcia, A. Blanco, D. S. Wiersma, and C. Lopez, “Resonance-driven random lasing,” Nat. Photonics 2(7), 429–432 (2008).
[8] 郭家豪。2009。可雙光子調控隨機雷射於染料擦摻雜聚合物分散奈米液晶顆粒混合薄膜。成功大學物理研究所碩論。台南。
[9] Modeling of Low Power Multilayer Vertical Cavity Surface Emitting Laser
[10] Jinwen Shi, “ABO3-based photo catalysts for water splitting” Natural Science;22(6):592–615
[11] Wenk, Hans-Rodolf, Andrei Bulakh “Minerals:Their Constitution and Orign,” New York, NY: Cambridge University Press. ISBN 978-0-521-52958-7,(2004)
[12] Sai Bai, Zhong cheng Yuan and Feng Gao “Colloidal metal halide perovskite nanocrystals:synthesis, characterization, and applications ” Materials Chemistry C
DOI: 10.1039/c5tc04116c (2016)
[13] SIGMA-ALDRICH official web: http://www.sigmaaldrich.com
[14] L. E. Brus, “Chemistry and physics of semiconductor nanocrystals, ” (2007)
[15] Norris, D.J. (1995). “Measurement and Assignment of the Size-Dependent Optical Spectrum in Cadmium Selenide (CdSe) Quantum Dots, ” PhD thesis, MIT".
[16] C. B. Murray and C. R. Kagan, "Synthesis and characterization of monodisperse nanocrystals and close-packed nanocrystal assemblies, ” Annual Review of Materials Research, Vol. 30Vol. 30 Vol. 30 , 545 -61 0, (2000 )
[17] M. A. Kastner, “Artificial Atoms, ” Physics Today, Vol. Vol. 46, 24 (1993)
[18] R. C.R. C. Ashoori , “Electrons in artificial atoms, ” Nature, 379, 413 - 419 (1996)
[19] C. P. Collier, T. Vossmeyer, and J. R. Heath, “Nanocrystal superlattices, ” Annual Review of Physical Chamistry, Vol. 49:371-404(1998)
[20] Xinzheng Lan, Silvia Masala and Edward H. Sargent “Charge-extraction strategies for colloidal quantum dot photovoltaics, ” nature, DOI: 10.1038/NMAT3816 (2014)
[21] Liuqi Zhang, Xiaolei Yang, Qi Jiang, Pengyang Wang“Ultra-bright and highly efficient inorganic based perovskite light-emitting diodes , ” NATURE COMMUNICATIONS , DOI: 10.1038/ncomms15640 (2017)
[22] Quantum Dots for Electronics and Energy Applications ,web: https://www.sigmaaldrich.com/technical-documents/articles/materials-science/quantum-dots-noncadmium.html
[23] Ting Zhang , Guopeng Li , Yajing Chang , Xiaoyan Wang “Full-spectra hyperfluorescence cesium lead halide perovskite nanocrystals obtained by efficient halogen anion exchange using zinc halogenide salts, ” CrystEngComm, DOI: 10.1039/c6ce02314b (2016)
[24] Dan Wang, Dan Wu,c Di Dong, Wei Chen, “Polarized emission from CsPbX3 perovskite quantum dots , ” Nanoscale , DOI: 10.1039/c6ce02314b (2016)
[25] Yue Wang, Xiaoming Li, Venkatram Nalla, “Solution-Processed Low Threshold Vertical Cavity Surface Emitting Lasers from All-Inorganic Perovskite Nanocrystals , ” Advanced Science , DOI: 10.1002/adfm.201605088 (2017)
[26] 謝嘉民, 賴一凡, 林永昌, 枋志堯, “光激發螢光量測的原理、架構及應用, ”奈米通訊, 第十二卷, 第二期, 第28-39頁 (2005)
[27] Sudipta Seth , Anunay Samanta , “A Facile Methodology for Engineering the Morphology of CsPbX3 Perovskite Nanocrystals under Ambient Condition , ” Scientific Reports , DOI: 10.1038/srep37693 (2016)
[28] Dan Wang , Dan Wu, Di Dong , Wei Chen, “Polarized emission from CsPbX3 perovskite quantum dots, ” Nanoscale , DOI: 10.1039/c6nr01915c(2016)
[29] A. Feldhoff , M. Arnold , J. Martynczuk ,“The solegel synthesis of perovskites by an EDTA/citrate complexing method involves nanoscale solid state reactions, ” Solid State Sciences, doi:10.1016/j (2008)
[30] R. M. PITICESCU , P. VILARNHO “Hydrothermal synthesis of perovskite based materials for microelectronic applications, ” Advanced materials ,Vol. 8, No. 2 (2006)
[31] Loredana Protesescu , Sergii Yakunin , Maryna I. Bodnarchuk, “Nanocrystals of Cesium Lead Halide Perovskites (CsPbX3, X = Cl, Br, and I): Novel Optoelectronic Materials Showing Bright Emission with Wide Color Gamut, ” Nano Let , DOI: 10.1021/nl5048779 (2015)
[32] Chun-Ying Huang, Chen Zou,“CsPbBr3 Perovskite Quantum Dot Vertical Cavity Lasers with Low Threshold and High Stability, ” ACS Photonics , DOI: 10.1021/acsphotonics.7b00520 (2017)