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研究生: 楊廷勛
Yang, Ting-Xun
論文名稱: 鈷/石墨烯的電化學與磁特性研究
Electrochemical and Magnetic Properties of Cobalt / Graphene
指導教授: 蔡志申
Tsay, Jyh-Shen
張丞勛
Chang, Cheng-Hsun
學位類別: 碩士
Master
系所名稱: 物理學系
Department of Physics
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 128
中文關鍵詞: 石墨烯電位誘導磁異向性循環伏安
DOI URL: http://doi.org/10.6345/NTNU202000414
論文種類: 學術論文
相關次數: 點閱:143下載:0
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  • 第一章 緒論 1 第二章 實驗基本原理 6 2-1 薄膜磊晶成長理論與物性介紹 6 2-1-1薄膜成長理論 6 2-1-2銅、鈷、石墨烯的物性介紹 7 2-2 電化學原理 9 2-2-1法拉第電解定律(Faraday’s law of electrolysis) 9 2-2-2電雙荷層(electrical double layer, EDL ) 10 2-2-3電化學反應和電子轉移 13 2-2-4能斯特方程 15 2-2-5陰離子特異性吸附(specific anion adsorption) 19 2-3 磁性理論 21 2-3-1磁性物質種類 22 2-3-2鐵磁性物質的特性 23 2-3-3磁異向性理論 25 第三章 實驗儀器介紹 31 3-1超高真空系統 31 3-1-2濺鍍 31 3-2電化學設備 33 3-2-1電化學電鍍槽 33 3-2-2電化學循環伏安儀 34 3-2-3磁光科爾效應器材與元件 40 3-2-4磁光科爾效應儀器架設 41 3-2-5磁光科爾效應理論(magneto-optic Kerr effect) 44 3-3貴重儀器 47 3-3-1原子力顯微鏡(Atomic Force Microscope) 47 3-3-2 科爾顯微鏡 47 3-4實驗方法 49 3-4-1 實驗藥品介紹 49 3-4-2 樣品製備 50 3-4-3 EC-MOKE實驗前處理及實驗步驟 50 第四章 實驗結果與討論 52 4-1 Co / Gra / Cu的大氣環境下測量之磁性與表面形貌 52 4-2 Gra / Cu與Co / Gra / Cu於1、10、100 mM KCl + 0.1mM HCl溶液中的氧化還原研究 65 4-2-1 確認Co在1、10、100 mM KCl + 0.1mM HCl的氧化還原研究 67 4-2-2 確認Cu與Co / Cu在1、10、100 mM KCl + 0.1mM HCl 的氧化還原研究 71 4-2-3 確認Gra / Cu在1、10、100 mM KCl + 0.1mM HCl 的氧化還原研究與Cu溶解厚度 83 4-2-4 確認Co/Gra / Cu在1、10、100 mM KCl + 0.1mM HCl 的氧化還原研究與Cu和Cu溶解厚度 89 4-3 Co / Gra / Cu在10、100 mM KCl + 0.1mM HCl 水溶液下的電位磁控制特性實驗 98 4-3-1 固定電位下,KCl濃度對於20、30 nm Co / Gra / Cu 在溶液下的變化 101 4-3-2固定KCl濃度下,電位對於20、30 nm Co / Gra / Cu 在溶液下的變化 110 4-3-3在 - 500 mV電位時,Cl吸附狀態對磁特性影響 120 4-3-4 未來展望 123 第五章 結論 124 第六章 參考資料與文獻 125

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