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研究生: 崔鈺君
Tsui, Yu-Juin
論文名稱: 以新穎配位基合成錳-氧加成物及其對9,10-Dihydroanthracene的催化探討
Synthesis of Mn-O2 Adduct with a Novel Ligands and its Catalysis of 9,10-Dihydroanthracene
指導教授: 李位仁
Lee, Way-Zen
學位類別: 碩士
Master
系所名稱: 化學系
Department of Chemistry
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 71
中文關鍵詞: 含錳-氧合酶四價錳過氧錯合物(peroxo)三價錳過氧氫化物(hydroperoxo)DHA催化反應
英文關鍵詞: Mn enzymes, Mn(IV)-peroxo complex, Mn(III)-hydroperoxo complex, DHA catalyzed reaction
DOI URL: http://doi.org/10.6345/NTNU202000719
論文種類: 學術論文
相關次數: 點閱:106下載:0
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  • 第一章 緒論 1 1-1 光系統PSII中的錳金屬與氧反應 2 1-2 自然界中含錳金屬的蛋白及酶 4 1-3 錳金屬錯合物與氧氣反應 7 1-4 配位基的修飾與穩定反應機構中間體 13 1-5 研究方向 16 第二章 實驗部分 17 2-1 實驗藥品 17 2-2 實驗儀器及條件 18 2-3 錳系列錯合物之合成與鑑定 24 第三章 結果與討論 27 3-1 錳系列錯合物之合成 27 3-2 錯合物(1)氧化還原電位探討與比較 33 3-3 錯合物(1)、錯合物(2)和錯合物(3)EPR 光譜之探討 36 3-4 探究錯合物(1)與氧之反應性 39 3-5錯合物(2)和錯合物(3)之反應性探討 48 3-6錯合物(4)與HOTf反應 50 3-7錯合物(4)與TEMPOH氫原子轉移反應的探討 52 3-8錯合物(4)各別與2-PPA和DHA的反應性探討 56 第四章 結論與展望 65 參考文獻 67 附錄A X-ray單晶繞射解析結構及晶體常數 A-1

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