研究生: |
洪柏育 Po-Yu Hung |
---|---|
論文名稱: |
發光性二氧化鈦之特性分析與太陽能電池之應用 Investigation of Luminescent Titanium Dioxide and Application on Sensitized Solar Cells |
指導教授: |
胡淑芬
Hu, Shu-Fen |
學位類別: |
碩士 Master |
系所名稱: |
物理學系 Department of Physics |
論文出版年: | 2009 |
畢業學年度: | 97 |
語文別: | 中文 |
論文頁數: | 146 |
中文關鍵詞: | 二氧化鈦 、染料敏化太陽能電池 |
英文關鍵詞: | Titanium dioxide, solar cell |
論文種類: | 學術論文 |
相關次數: | 點閱:207 下載:8 |
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染料敏化太陽能電池 (Dye-Sensitized Solar Cell, DSSC) 目前於世界各國研究仍屬開發階段,其光電轉換效能與商用矽晶太陽能電池相較仍有差距,但因其具備製作簡單、成本低、可撓性 (flexible) 及易製成大面積之產品等商業化優勢,故將成為下階段太陽能新能源急切發展之技術。針對DSSC之研究,主要針對四項組成元件:工作電極、染料、電解質及反電極,探討不同材料對於效率之影響。其中工作電極多屬半導體奈米薄膜如:二氧化鈦 (TiO2) 或氧化鋅 (ZnO)等,已存在多數研究其形貌結構與塗佈方式對於電池效率之影響。而近年來TiO2 摻雜稀土金屬元素之研究,多數僅只探討其發光及觸媒特性,卻未有應用於敏化太陽能電池工作電極之研究。
本研究將以不同二氧化鈦前趨物及凝膠溶膠法、水熱法合成 TiO2 摻雜 Eu 粉體。主要內容探討 Eu 摻雜對於晶體成長及晶相生成之影響,並討論 Eu3+ 為發光中心引起之特殊發光特性及機制,且 Eu3+之摻雜對於 TiO2 吸收光譜及電子組態之影響也將於文中驗證。由於染料 Black dye 於紅光之特殊吸光特性,本研究將 TiO2: Eu3+ 應用於工作電池以增加染料對於太陽光之利用,且利用TiO2: Eu3+之特殊能階性質,設計雙層工作電極結構電池以增加光電流及電壓,進而提高電池效率,並以硒化鎘 (CdSe) 量子點取代染料 Black dye作為敏化物,觀察其光電特性。於本研究中針對 TiO2: Eu3+ 將進行材料結構鑑定及光譜特性分析,並針對敏化太陽能電池測量其光電特性及理論參數精算。
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